Two New Coordination Polymers Based on H<sub>4</sub>BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe<sup>3+</sup> Ion

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Abstract Based on the solvothermal reaction of 5,5΄-(1,3,6,8-tetraoxobenzo[lmn][3,8] phenanthrolin-2-7-diyl)bis-1,3-benzenedicarboxylic acid (H4L) linker and Zn(II)/Cd(II), two new 2D coordination polymers (CPs), namely {[ZnH2L(4,4΄-bibp)]·H2O}n (1) and {[CdL0.5(1,4- bimb)0.5(H2O)]·EtOH}n (2) (L = BIPA-TC), have been successfully constructed and characterized by EA, PXRD and IR with the aid of 4,4΄-bis(benzoimidazo-1-yl)biphenyl(4,4΄-bbib)/1,4- bis(imidazol-1-ylmethyl)benzene (1,4-bimb). The structural analysis showed that complex 1 exhibits a 3D supramolecular structure with the topology of sql, and complex 2 possesses a 2-nodal (4,6)-c framework with the topology of (32·42·52)(34·44·54·63)-4,6T26. Fluorescent experiments showed that 1 and 2 have high selectivity and sensitivity for the sensing of nitroaromatic compounds and Fe3+ in aqueous solutions.

Key words： fluorescence sensing crystal structure coordination polymers

Received: 06 August 2019 Published: 13 April 2020

Fund:Supported by the NSFC (No. 21676258) and the International Scientific and Technological Cooperation Projects of Shanxi Province (No. 201803D421080)

Corresponding Authors: hutuoping@nuc.edu.cn E-mail: hutuopingsx@126.com

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	ZHAI Li-Jun
	JIAO Chen-Xu
	LIANG Jin-Fang
	ZHANG Jie
	NIU Xiao-Yan
	HU Tuo-Ping
	NIU Yu-Lan

Cite this article:

ZHAI Li-Jun,JIAO Chen-Xu,LIANG Jin-Fang, et al. Two New Coordination Polymers Based on H₄BIPA-TC: Syntheses and Fluorescence Sensing for Nitroaromatic Compounds and Fe³⁺ Ion[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39(4): 772-782.

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http://manu30.magtech.com.cn/jghx/EN/ OR http://manu30.magtech.com.cn/jghx/EN/Y2020/V39/I4/772

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