Photophysical Performance and Energy Transfer Mechanism of a 1-D Chain-like Complex

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Abstract By means of solvothermal reactions, a novel lanthanide-mercury compound, {[Ho(IA)3(H3O)2]2n[2n(HgCl4)][n(HgCl5)]}·3nH3O·nH2O (1, HIA = isonicotinc acid) was prepared and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in the C2/c space group of monoclinic system with a = 24.2147(5), b = 20.8106(4), c = 15.3060(3) Å, β = 128.326(2)°, V = 6050.8(2) Å3, C36H45Cl13Hg3Ho2N6O20, Mr = 2274.26, Z = 4, Dc = 2.497 g/cm3, μ(MoKα) = 10.817 mm–1 and F(000) = 4232. It exhibits a one-dimensional (1-D) chain-like structure. Solid-state photoluminescence measurement shows that it displays brown light emission bands. These emission bands originate from the characteristic emissions of the 4f electrons intrashell transitions of 5S2 → 5I8 and 5F5 → 5I8 of the holmium(III) ions in 1. The photoluminescence emission energy transfer mechanism is elucidated by the energy level diagrams of the holmium(III) ions and isonicotinic acid ligand. Complex 1 has CIE chromaticity coordinates of (0.4361, 0.4992). Solid-state UV/Vis diffuse reflectance spectra reveal that it possesses wide optical band gap of 4.94 eV.

Key words： chromaticity coordinate energy transfer isonicotinc acid lanthanide Photoluminescence

Received: 03 June 2019 Published: 13 April 2020

Fund:Supported by the NNSFC (21361013, 31460488), NSF of Fujian (2018J01447), Jiangxi Provincial Department of Education’s Item of Science and Technology (GJJ170637), and the Open Foundation (20180008) of State Key Laboratory of Structural Chemistry

Corresponding Authors: hjg0468@163.com E-mail: hjg0468@163.com

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	Articles by authors
	LIN Wei-Sheng
	HUANG Jian-Gen
	WEN Yun-Xiang
	LUO Hui
	CHEN Wen-Tong

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LIN Wei-Sheng,HUANG Jian-Gen,WEN Yun-Xiang, et al. Photophysical Performance and Energy Transfer Mechanism of a 1-D Chain-like Complex[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39(4): 747-755.

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http://manu30.magtech.com.cn/jghx/EN/ OR http://manu30.magtech.com.cn/jghx/EN/Y2020/V39/I4/747

REFERENCES
(1) Qiu, L. Y.; Yu, C. F.; Wang, X. L.; Xie, Y. B.; Kirillov, A. M.; Huang, W.; Li, J. P.; Gao, P.; Wu, T.; Gu, X. W.; Nie, Q.; Wu, D. Y. Tuning the solid-state white light emission of postsynthetic lanthanide-encapsulated double-layer MOFs for three-color luminescent thermometry applications. Inorg. Chem. 2019, 58, 4524–4533.
(2) Zhao, L. H.; Chen, H. M.; Yang, A. H.; Wu, D. F.; Gou, J.; Cui, J. Z.; Gao, H. L. Synthesis, characterization and properties of lanthanide complexes with different ancillary ligands. Inorg. Chim. Acta 2019, 490, 240–245.
(3) Yao, X.; An, G. H.; Li, Y. X.; Yan, P. F.; Li, W. Z.; Li, G. M. Effect of nuclearity and symmetry on the single-molecule magnets behavior of seven-coordinated β-diketonate Dy(III) complexes. J. Solid State Chem. 2019, 274, 295–302.
(4) Yu, L. H.; Li, G. W.; Liu, Y. S.; Jiang, F. L.; Hong, M. C. Lanthanide-doped KGd2F7 nanocrystals: controlled synthesis, optical properties, and spectroscopic identification of the optimum core/shell architecture for highly enhanced upconverting luminescence. Cryst. Growth Des. 2019, 19, 2340–2349.
(5) D'Vries, R. F.; Gomez, G. E.; Mondragon, L. P.; Onna, D.; Barja, B. C.; Soler-Illia, G. J. A. A.; Ellena, J. 1D lanthanide coordination polymers based on lanthanides and 4'-hydroxy-4-biphenylcarboxylic acid: synthesis, structures and luminescence properties. J. Solid State Chem. 2019, 274, 322–328.
(6) Xu, L.; Pu, N.; Li, Y. Z.; Wei, P. P.; Sun, T. X.; Xiao, C. L.; Chen, J.; Xu, C. Selective separation and complexation of trivalent actinide and lanthanide by a tetradentate soft-hard donor ligand: solvent extraction, spectroscopy, and DFT calculations. Inorg. Chem. 2019, 58, 4420–4430.
(7) Ren, K.; Wu, S. H.; Guo, X. F.; Wang, H. Lanthanide organic framework as a reversible luminescent sensor for sulfamethazine antibiotics. Inorg. Chem. 2019, 58, 4223–4229.
(8) Wang, K.; Zhang, J. Q.; Lu, J.; Jing, P.; Li, L. C. Slow magnetic relaxation in Cu–Ln heterometallic Schiff base complexes containing Ln(hfac)-4 as counterions magnetic relaxation in Cu–Ln heterometallic Schiff base complexes containing Ln(hfac)-4 as counterions. Inorg. Chim. Acta 2019, 490, 51–56.
(9) Martin-Caballero, J.; Artetxe, B.; Reinoso, S.; San Felices, L.; Vitoria, P.; Larranaga, A.; Vilas, J. L.; Gutierrez-Zorrilla, J. M. Thermostructural behavior in a series of lanthanide-containing polyoxotungstate hybrids with copper(II) complexes of the tetraazamacrocycle cyclam: a single-crystal-to-single-crystal transformation study. Inorg. Chem. 2019, 58, 4365–4375.
(10) Clementino, R. F. P.; de Souza Santos, A. B.; Marques, O. J. B. J.; Ratkovski, D. R.; Gatto, C. C.; Malvestiti, I.; de Araujo Machado, F. L.; Falcao, E. H. L. Structural description, luminescent and magnetic properties of novel 2-D coordination polymers containing thiazolo[5,4-d]thiazole rings and trivalent lanthanide ions. J. Solid State Chem. 2018, 268, 94–101.
(11) Cerfontaine, S.; Marcelis, L.; Laramee-Milette, B.; Hanan, G. S.; Loiseau, F.; De Winter, J.; Gerbaux, P.; Elias, B. Converging energy transfer in polynuclear Ru(II) multiterpyridine complexes: significant enhancement of luminescent properties. Inorg. Chem. 2018, 57, 2639–2653.
(12) Wang, W.; Peng, D. F.; Zhang, H. L.; Yang, X. H.; Pan, C. F. Mechanically induced strong red emission in samarium ions doped piezoelectric semiconductor CaZnOS for dynamic pressure sensing and imaging. Opt. Commun. 2017, 395, 24–28.
(13) Kuang, H. M.; Huang, J. G.; Lin, L. Z.; Zhong, Q. X.; Chen, W. T. Structure and luminescence of two new mercury-lanthanide complexes. Inorg. Chim. Acta 2019, 489, 48–53.
(14) Sheldrick, G. M. SHELXS, Program for X-ray Crystal Structure Solution. University of Göttingen, Germany 1997.
(15) Yi, X. G.; Zhang, Z. X.; Chen, W. T.; Lin, L. Z.; Chen, H. L. Photoluminescence and semiconductor properties of two novel lanthanide-mercury compounds with one-dimensional chain-like structures. J. Solid State Chem. 2018, 266, 16–22.
(16) Lin, L. Z.; Zhong, Q. X.; Hong, J. T.; Chen, H. L.; Chen, W. T. Syntheses, structures, photoluminescence and semiconductor properties of two novel mercury-lanthanide complexes with a three-dimensional open framework. Inorg. Chim. Acta 2018, 479, 30–35.
(17) Luo, Q. Y.; Luo, H.; Kuang, H. M.; Chen, W. T.; Wen, Y. X. A novel samarium material: synthesis, structure, photophysical properties and photoluminescence energy transfer mechanism. J. Solid State Chem. 2019, 270, 200–204.
(18) Gupta, S. K.; Langley, S. K.; Sharma, K.; Murray, K. S.; Murugavel, R. Pentanuclear lanthanide mono-organophosphates: synthesis, structure, and magnetism. Inorg. Chem. 2017, 56, 3946–3960.
(19) Zhang, L. Y.; Lu, L. P.; Zhu, M. L.; Feng, S. S. Self-assembly of lanthanide(III) coordination polymers from a bifunctional 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylate ligand with the assistance of oxalate: syntheses, structures, luminescence, and magnetic properties. CrystEngComm. 2017, 19, 1953–1964.
(20) Coban, M. B.; Amjad, A.; Aygun, M.; Kara, H. Sensitization of HoIII and SmIII luminescence by efficient energy transfer from antenna ligands: magnetic, visible and NIR photoluminescence properties of GdIII, HoIII and SmIII coordination polymers. Inorg. Chim. Acta 2017, 455, 25–33.
(21) Wu, J.; Li, X. L.; Zhao, L.; Guo, M.; Tang, J. Enhancement of magnetocaloric effect through fixation of carbon dioxide: molecular assembly from Ln4 to Ln4 cluster pairs. Inorg. Chem. 2017, 56, 4104–4111.
(22) An, L.; Zhou, J.; Zou, H. H.; Xiao, H.; Zhao, R.; Ding, Q. Syntheses, structures and properties of a series of new lanthanide chalcoarsenates(III) containing crown-shaped [As3Q6]3- (Q = S, Se) clusters. J. Alloy. Compd. 2017, 702, 594–600.
(23) Schmidt, S. F. M.; Koo, C.; Mereacre, V.; Park, J.; Heermann, D. W.; Kataev, V.; Anson, C. E.; Prodius, D.; Novitchi, G.; Klingeler, R.; Powell, A. K. A three-pronged attack to investigate the electronic structure of a family of ferromagnetic Fe4Ln2 cyclic coordination clusters: a combined magnetic susceptibility, high-field/high-frequency electron paramagnetic resonance, and 57Fe Mössbauer study. Inorg. Chem. 2017, 56, 4796–4806.
(24) Zhang, J. W.; Jiang, Y.; Xie, Y. R.; Chu, J.; Liu, B. Q. Syntheses, structures, photoluminescence, and magnetism of a series of discrete heavy lanthanide complexes based on a tricarboxylic acid. Inorg. Chim. Acta 2016, 453, 257–262.
(25) Ridenour, J. A.; Carter, K. P.; Butcher, R. J.; Cahill, C. L. RE-p-halobenzoic acid-terpyridine complexes, part II: structural diversity, supramolecular assembly, and luminescence properties in a series of p-bromobenzoic acid rare-earth hybrid materials. CrystEngComm. 2017, 19, 1172–1189.
(26) Botezat, O.; van Leusen, J.; Ch Kravtsov, V.; Kogerler, P.; Baca, S. G. Ultralarge 3d/4f coordination wheels: from carboxylate/amino alcohol-supported {Fe4Ln2} to {Fe18Ln6} rings. Inorg. Chem. 2017, 56, 1814–1822.
(27) Rojas-Hernandez, R. E.; Santos, L. F.; Almeida, R. M. Tb3+/Yb3+ doped aluminosilicate phosphors for near infrared emission and efficient down-conversion. J. Lumin. 2018, 197, 180–186.
(28) Gao, Y.; Sun, X. R.; Feng, Z. S.; Zhu, L. Y.; Zhang, J.; Gao, W. L.; Zhou, X. J.; Cong, R. H.; Yang, T. Tb3+ and Eu3+ co-doped Ba6Bi9B79O138: color-tunable phosphors by utilizing the host-sensitization effect of Bi3+ and enhancement of red emission upon heating. New J. Chem. 2017, 41, 2037–2045.
(29) Shi, H. W.; Zhu, Y. P.; Zhao, Y. M.; Liu, C.; Ren, X. Z.; Hao, J. G.; Li, W. Field-induced large strain and strong green photoluminescence in (Ho,Sb)-modified (Bi0. 5Na0. 5)0. 945Ba0. 065TiO3 multifunctional ferroelectric ceramics. J. Alloy. Compd. 2018, 767, 666–674.
(30) Krishnan, R.; Thirumalai, J. Up/down conversion luminescence properties of (Na0. 5Gd0. 5)MoO4:Ln3+ (Ln = Eu, Tb, Dy, Yb/Er, Yb/Tm, and Yb/Ho) microstructures: synthesis, morphology, structural and magnetic investigation. New J. Chem. 2014, 38, 3480–3491.
(31) Barrera, E. W.; Pujol, M. C.; Carvajal, J. J.; Mateos, X.; Sole, R.; Massons, J.; Speghini, A.; Bettinelli, M.; Cascales, C.; Aguilo, M.; Diaz, F. White light upconversion in Yb-sensitized (Tm, Ho)-doped KLu(WO4)2 nanocrystals: the effect of Eu incorporation. Phys. Chem. Chem. Phys. 2014, 16, 1679–1686.
(32) Dexter, D. L. A theory of sensitized luminescence in solids. J. Chem. Phys. 1953, 21, 836–850.
(33) Sato, S.; Wada, M. Relations between intramolecular energy transfer efficiencies and triplet state energies in rare earth β-diketone chelates. Bull. Chem. Soc. Jpn. 1970, 43, 1955–1962.
(34) Xu, B.; Yan, B. Photophysical properties of novel lanthanide (Tb3+, Dy3+, Eu3+) complexes with long chain para-carboxyphenol ester p-L-benzoate (L = dodecanoyloxy, myristoyloxy, palmitoyloxy and stearoyloxy). Spectrochim. Acta A 2007, 66, 236–242.
(35) Huang, F. Q.; Mitchell, K.; Ibers, J. A. New layered materials: syntheses, structures, and optical and magnetic properties of CsGdZnSe3, CsZrCuSe3, CsUCuSe3, and BaGdCuSe3. Inorg. Chem. 2001, 40, 5123–5126.