Metal-induced Coordination Networks Using a C2v-based Hexacarboxylate Ligand:Syntheses, Structures and Properties

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Abstract

Metal-organic frameworks (MOFs), consisting of metal, anion and organic ligands, have attracted much attention. The structure of MOFs is affected by various factors. To explore the effects of metal ions, we synthesized six complexes, namely {[Me2NH2][Zn4(H2L)(L)]·2H2O·2DMF}n(1), {[Me2NH2]2[Cd2(L)]·2H2O}n (2), {[Me2NH2]2[Ca3(L)(μ-OH)2(DMF)2]·2H2O}n (3) and {[Me2NH2]2[M2(L)(μ-OH)]·2H2O·2DMF}n (M = Co, 4; Ni, 5; Mn, 6), from a C2v-based hexacar- boxylate ligand ([1,1΄;4΄,1΄΄]terphenyl-3,5,2΄,5΄,3΄΄,5΄΄-hexacarboxylic acid (H6L)) using metal-induced strategy. These MOFs were thoroughly characterized by single-crystal and X-ray diffraction, elemental analysis, Fourier-transform infrared spectra (FTIR) and photoluminescence.

Key words： metal-induced syntheses structures photoluminescence properties

Received: 26 November 2018 Published: 12 August 2019

Fund:Financially supported by the Natural Science Foundation of Shandong Province (ZR2017BB023), China Postdoctoral Science Foundation (2016M602180) and Innovative Training Project for graduate Students of Shandong Normal University

Corresponding Authors: glzhang@sdnu.edu.cn E-mail: glzhang@sdnu.edu.cn

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	Articles by authors
	WAN Xiu-Yan
	ZHANG Guang-Lu
	CHEN Lian
	JIANG Fei-Long
	HONG Mao-Chun

Cite this article:

WAN Xiu-Yan,ZHANG Guang-Lu,CHEN Lian, et al. Metal-induced Coordination Networks Using a C2v-based Hexacarboxylate Ligand:Syntheses, Structures and Properties[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38(8): 1370-1379.

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http://manu30.magtech.com.cn/jghx/EN/ OR http://manu30.magtech.com.cn/jghx/EN/Y2019/V38/I8/1370

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