Syntheses, Crystal Structures, Magnetic and Luminescent Properties of Ni(II), Cd(II) and Pb(II) Coordination Compounds Constructed from 5-Fluoronicotinic Acid

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Abstract

Five coordination compounds, namely [Ni2(5-Fnic)2(H2O)4] (1), [Ni(5-Fnic)(µ-5- Fnic) (H2biim)]n (2), {[Cd((µ-5-Fnic)2(H2O)2]4,4΄-bipy}n (3), [Pb2(µ-5-Fnic)2(µ3-5-Fnic)2(H2O)2]n (4), and [Pb(5-Fnic)2(4,4΄-bipy)(H2O)] (5), have been constructed hydrothermally using 5-FnicH (5-FnicH = 5-fluoronicotinic acid), H2biim (H2biim = 2,2΄-biimidazole), 4,4΄-bipy (4,4΄-bipy = 4,4΄-bipyridine), NiCl26H2O, CdCl2H2O and PbCl2. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses (TGA), and single-crystal X-ray diffraction analyses. Structures of 1～5 range from discrete 0D monomers (1 and 5) to 1D coordination polymers (2 and 4) and 2D metal-organic network (3). A broad structural diversity of 1～5 is guided by the type of the metal(II) node and the introduction of auxiliary ligands. The magnetic (for 2) and luminescent (for 3～5) properties were also investigated and discussed.

Key words： coordination compound 5-fluoronicotinic acid magnetic properties luminescent properties

Received: 03 September 2018 Published: 13 June 2019

Fund:This work was supported by Guangdong Province Higher Vocational Colleges & Schools Pearl River Scholar Funded Scheme (2015, 2018), the Natural Science Foundation of Guangdong Province (No. 2016A030313761), the Pearl River Scholar Foundation of Guangdong Industry Polytechnic (RC2015-001), the Opening Foundation of MOE Key Laboratory of MOE Key Laboratory of Bioinorganic and Synthetic Chemistry School of Chemistry Sun Yat-Sen University (2016) , Innovation Team Project on University of Guangdong Province (2017GKCXTD001, 2017GWCXTD002) and Outstanding youth fund project of Guangdong Industry Polytechnic (QN 2018-007)

Corresponding Authors: liyuletter@163.com and ggcxl@163.com E-mail: liyuletter@163.com and ggcxl@163.com

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	LI Yu
	ZOU Xun-Zhong
	QIU Wen-Da
	FENG An-Sheng
	CHEN Xiao-Ling

Cite this article:

LI Yu,ZOU Xun-Zhong,QIU Wen-Da, et al. Syntheses, Crystal Structures, Magnetic and Luminescent Properties of Ni(II), Cd(II) and Pb(II) Coordination Compounds Constructed from 5-Fluoronicotinic Acid[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38(6): 999-1011.

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http://manu30.magtech.com.cn/jghx/EN/ OR http://manu30.magtech.com.cn/jghx/EN/Y2019/V38/I6/999

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