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| Structural Characterization of ((S)-2΄-Hydroxy-1,1΄- binaphthalen-2-yl)-(SP)-vinylphosphonate Synthesized by the Chiral Induced Diastereoselective Reaction |
| JIANG Jie;LIU Feng-Jiao;ZHU Zhong-Xiang;WU Ming-Shu |
| (Key Laboratory of Tropical Medicinal Plant Chemistry of the Ministry of Education, College of Chemistry & Chemical Engineering, Hainan Normal University, Haikou 571158, China) |
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Abstract Ethyl((S)-2΄-hydroxy-1,1΄-binaphthalen-2-yl)-(SP)-vinylphosphonate (SBINOL-SP) was synthesized by diastereoselective reaction and characterized by means of NMR spectroscopy, H RMS and X-ray diffraction. The single crystal belongs to the monoclinic system, space group P21/c with a = 7.4983(13), b = 12.065(2), c = 21.805(4) Å, β = 90.094(6)°, Mr = 404.38, V = 1972.6(6) Å3, Z = 4, Dc = 1.362 g/cm3, F(000) = 848, μ = 0.168 mm-1, R = 0.0280 and wR = 0.0743. The title compound shows good activities against E. coli, S. albus, B. subtilis and M. tetragenus.
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Received: 30 September 2016
Published: 10 July 2017
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Corresponding Authors:
wmsh@hainnu.edu.cn
E-mail: wmsh@hainnu.edu.cn
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2017, Vol. 36 
