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| Hydrothermal Synthesis, Crystal Structure and Proton Conductivity of a Pr–Ca Heterometal-organic Framework Generated by 1,2,4,5-Benzenetetracarboxylic Acid |
| LIANG Xiao-Qiang;LI Ren-Zhong;FAN Zeng-Lu |
a (College of Environmental and Chemical Engineering,Xi’an Polytechnic University, Xi’an 710048, China)
b (College of Textile & Material, Xi'an Polytechnic University, Xi'an 710048, China)
c (College of Electronics and Information, Xi’an Polytechnic University, Xi’an 710048, China)
d (State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China) |
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Abstract A heterometal-organic framework {[Pr2Ca(betc)2(H2O)7]H2O}n (1) was prepared by the hydrothermal reaction of 1,2,4,5-benzenetetracarboxylic acid (H4betc) with Pr(NO3)3 and CaCO3, and further characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Complex 1 crystallizes in triclinic, space group P1 with a = 7.3668(12), b = 10.1726(14), c = 11.2264(15) Å, = 100.404(2), = 106.113(3), = 109.158(3)º, V = 728.48(19) Å3, Mr = 966.26, Z = 1, F(000) = 470, Dc = 2.203 g/cm3, (MoKα) = 3.585 mm-1, the final R = 0.0195 and wR = 0.0470 (I > 2(I)). Complex 1 is a 3D network with pcu topology with 1D porosity and rich hydrogen-bonding interactions. The proton conductivity of complex 1 was also studied under ~97% relative humidity and the different temperature conditions.
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Received: 19 September 2016
Published: 12 June 2017
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| Fund:This work was supported by the National Natural Science Foundation of China (21401147 and 21301134), Basic Research Program of Natural Science from Shaanxi Provincial Government (2015JQ2032), Scientific Research Program from Education Department of Shaanxi Provincial Government (2013JK0654), Opening Foundation from State Key Laboratory of Coordination Chemistry in Nanjing University (201219),and the Program for Distinguished Young Scholars of Xi’an Polytechnic University (201403) |
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Corresponding Authors:
xqliang1980@qq.com;
E-mail: xqliang1980@qq.com
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2017, Vol. 36 
