一个新颖4-结点umc拓扑Zn(II)配合物的合成、结构和荧光性能研究

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Abstract A novel complex, [Zn(L)]2•H2O (1, H2L = 4-aminophthalic acid), has been hydro- thermally prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and PXRD. Complex 1 crystallizes in monoclinic, space group C2/c with a = 12.4267(6), b = 7.7482(3), c = 18.6983(8) Å, β = 110.437(3)º, V = 1687.04(13) Å3, Z = 4, C16H12N2O9Zn2, Mr = 507.06, Dc = 1.996 g/cm3, μ = 2.903 mm-1, S = 0.989, F(000) = 1016, the final R = 0.0304 and wR = 0.0720 for 12618 observed reflections (I > 2σ(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional (3D) framework with 4-connected umc topology. Moreover, the thermogravimetric (TG) analysis and photoluminescent property of 1 were also discussed.

Key words： Zn(II) compound topology 3D framework luminescence

Received: 02 August 2016 Published: 11 May 2017

Fund:This work was supported by the National Natural Science Foundation of China (Nos. 21171040 and 21302019), excellent organic teaching and research project (No. 2013JCJS01) and National Undergraduates Innovation Project (201510371010)

Corresponding Authors: sscfync@163.com E-mail: sscfync@163.com

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	ZHANG Zi-You
	XIAO Li
	CHEN Shui-Sheng
	QIAO Rui
	YANG Song

Cite this article:

ZHANG Zi-You,XIAO Li,CHEN Shui-Sheng, et al. A Novel Zn(II) Complex with 4-Connected umc Topology: Synthesis, Crystal Structure and Luminescent Property[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(5): 819-824.

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http://manu30.magtech.com.cn/jghx/EN/ OR http://manu30.magtech.com.cn/jghx/EN/Y2017/V36/I5/819

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