Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-organic Coordination Polymer with Helical Chains Based on 5-(Imidazol-1-ylmethyl)isophthalic Acid

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Abstract

A novel 3D metal-organic coordination polymer with helical chains based on a flexible 5-(imidazol-1-ylmethyl)isophthalic acid (H2L) as a main ligand and 1,2-bis(4- pyridyl)ethane(bpa) as a N-containing ancillary ligand, [CdL(bpa)0.5]n (1), has been obtained under hydrothermal conditions and characterized by elemental analysis, powder X-ray diffraction (PXRD), IR, thermal gravimetric analyses (TGA) and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P21/c with a = 10.984(2), b = 10.1829(12), c = 17.782(3) Å, β = 123.156(11)º, V = 1665.1(5) Å3, Z = 4, Mr = 448.72, Dc = 1.790 g/cm3, Rint = 0.0871, F(000) = 892, the final R = 0.0687 and wR = 0.1294 for 2920 observed reflections (I  2σ(I)). In complex 1, the L2− anions connect Cd(II) ions to form two-dimensional metal-organic layers (Cd2L2)n, in which the 1D helical chains (Cd-L)n are alternately arranged in a right- and left-handed sequence. These layers are further linked to build a 3D network by the bpa ligand. In addtion, photo- luminescent properties for 1 are also investigated.

Key words： cadmium 5-(imidazol-1-ylmethyl)isophthalic acid PXRD luminescent properties

Received: 30 June 2015 Published: 11 March 2016

Fund:This project was supported by Education Chamber of Henan Province (No.15A150068)

Corresponding Authors: lifuanpds@163.com E-mail: lifuanpds@163.com

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	LI Fu-An
	YANG Wei-Chun
	MIAO Xu
	LI Song-Tian

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LI Fu-An,YANG Wei-Chun,MIAO Xu, et al. Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-organic Coordination Polymer with Helical Chains Based on 5-(Imidazol-1-ylmethyl)isophthalic Acid[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(3): 421-427.

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http://manu30.magtech.com.cn/jghx/EN/ OR http://manu30.magtech.com.cn/jghx/EN/Y2016/V35/I3/421

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