Facile Synthesis of Layered Sodium Manganese Oxide for Application in Asymmetric Supercapacitor

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Abstract Layered sodium manganese oxides (LSMOs), with two-dimensional channels for ion diffusion, have been regarded as the promising electrode materials in the application of asymmetric supercapacitors (ASCs). In this work, the layered Na0.5Mn2O4·1.5H2O was synthesized through a facile hydrothermal method by controlling the molar ratio of sodium and manganese. When the molar ratio of sodium to manganese is 3:1, Na0.5Mn2O4·1.5H2O has shown the best capacitance of 369 F/g with current density of 0.5 A/g, and maintained a capacitance of 265 F/g after 2000 cycles. The asymmetric supercapacitor consists of the sodium manages oxides as the positive electrode and active carbon (AC) as the negative electrode in 1 mol/L Na2SO4 solution. The voltage of the asymmetric supercapacitor has been expanded to 0～2 V with an energy density of 10.13 Wh/kg at a power density of 500 W/kg based on the total weight of both active electrode materials when the mass ratio of AC to Na0.5Mn2O4·1.5H2O was 3:1.

Key words： ayered sodium manganese oxides asymmetric supercapacitor electrochemical performance

Received: 12 June 2019 Published: 13 April 2020

Corresponding Authors: clz1977@sina.com E-mail: clz1977@sina.com

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	LIU Xu
	TENG Teng
	GU Lei-Xiang
	GE Li-Chao
	HE Wen
	LIAO Hui-Yong
	CHE Yi-Jun
	LIANG Chong-Yao
	DAN Yuan-Yuan
	CHEN Li-Zhuang

Cite this article:

LIU Xu,TENG Teng,GU Lei-Xiang, et al. Facile Synthesis of Layered Sodium Manganese Oxide for Application in Asymmetric Supercapacitor[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39(4): 756-764.

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http://manu30.magtech.com.cn/jghx/EN/ OR http://manu30.magtech.com.cn/jghx/EN/Y2020/V39/I4/756

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