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| Temperature-dependent Syntheses of Two Manganese(II) Coordination Compounds Based on an Ether-bridged Tetracarbolylic Acid |
| LI Yu;WU Jiang;GU Jin-Zhong;QIU Wen-Da;FENG An-Sheng |
a (Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China)
b (Key Laboratory for Tibet Plateau Phytochemistry of Qinghai Province,School of Pharmacy, Qinghai University for Nationalities, Xining 810007, China)
c (College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China)
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Abstract 0D dinuclear manganese(II) coordination compound and 1D chain manganese(II) coordination polymer, namely [Mn2(μ-L)(phen)4]·4H2O (1) and {[Mn2(μ5-L)(phen)2]·H2O}n (2), have been constructed hydrothermally using H4L (H4L = 2,3,3΄,4΄-diphenyl ether tetracarboxylic acid), phen (phen = 1,10-phenanthroline), and manganese chloride at 120 and 160 °C, respectively. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses (TGA), and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that two compounds crystallize in the triclinic or monoclinic system, space group P or P21/c. Compound 1 discloses a discrete dimeric structure, which is assembled into a 3D supramolecular framework through O–H∙∙∙O hydrogen bond. Compound 2 has a chain structure. Structural differences between compounds 1 and 2 are attributed to the different reaction temperature. Magnetic studies for compound 2 demonstrate an antiferromagnetic coupling between the adjacent Mn(II) centers.
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Received: 03 June 2019
Published: 13 April 2020
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| Fund:This work was supported by Guangdong Province Higher Vocational Colleges & Schools Pearl River Scholar Funded Scheme (2015, 2018), the Natural Science Foundation of Guangdong Province (No. 2016A030313761), the Pearl River Scholar Foundation of Guangdong Industry Polytechnic (RC2015-001), the Opening Foundation of MOE Key Laboratory of MOE Key Laboratory of Bioinorganic and Synthetic Chemistry School of Chemistry Sun Yat-Sen University (2016), Innovation Team Project on University of Guangdong Province (2017GKCXTD001), Science and Technology Planning Project of Guangzhou (201904010381) and the Science and Technology Plan of Qinghai Province (2018-ZJ-919) |
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Corresponding Authors:
gujzh@lzu.edu.cn
E-mail: gujzh@lzu.edu.cn
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2020, Vol. 39 
