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| A New Coordination Polymer Containing 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic Acid: Synthesis, Structure and Fluorescent Property |
| LUO Ya-Nan;XU Xian-Zhu;YU Xiao-Yang;ZHU Guang-Shan;ZHANG Xiao;QU Xiao-Shu;YU Li-Ying |
a (State Key Laboratory of Urban Water Resource and Environment (SKLUWRE), Harbin Institute of Technology, Harbin 150090, China)
b (College of Chemical and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin City, Jilin 132022, China)
c (State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130012, China) |
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Abstract A new coordination polymer, {[CdL(en)]·DMF}n (1, H2L = 4-[(8-hydroxy-5- quinolinyl)azo]-benzenesulfonic acid, en = ethylenediamine, DMF = N,N-dimethylformamide), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffrac- tion, infrared (IR) spectra, elemental analysis, powder X-ray diffractions (PXRD) and thermo- gravimetric analysis (TGA). Compound 1 crystallizes in monoclinic, space group P21/c with α = 14.6525(9), b = 13.3917(9), c = 11.8838(8) Å, β = 101.2290(10)°, V = 2287.2(3) Å3, Z = 4, C20H24CdN6O5S, Mr = 572.91, Dc = 1.664 mg·mm–3, F(000) = 1160, μ = 1.091 mm–1, R = 0.0232 and wR = 0.0587 for 3597 observed reflections (I > 2σ(I)). Compound 1 exhibits a one-dimensional (1D) double-chain structure which is further connected through hydrogen bonding and π-π interactions into a three-dimensional (3D) supramolecular network. In addition, it exhibits blue fluorescence at room temperature in the solid state.
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Received: 08 June 2013
Published: 12 September 2013
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| Fund:Supported by the National Basic Research Program of China (973 Program, No. 2012CB821700), Major International (Regional) Joint Research Project of National Natural Science Foundation (No. 21120102034), National Natural Science Foundation (No. 20831002; 51108122) and Education Department of Jilin Province (No. 2013-328) |
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Corresponding Authors:
许宪祝:xuxianzhuhb@163.com
E-mail: xuxianzhuhb@163.com
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| About author:: 许宪祝:xuxianzhuhb@163.com |
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2013, Vol. 32 
