Synthesis and Crystal Structures of Two New Ag(I) Complexes with Betaine Derivative: Structure Changes via Metal-to-Ligand Ratio

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摘要 Two new Ag(I) complexes {Ag₂(L)(NO₃)(H₂O)}_n (1) and {Ag(L)}_n·nH₂O (2) have been synthesized via the reaction of silver nitrate and betaine derivative 1-carboxyme- thylpyridinium-3-carboxylate (L) by only changing the metal-to-ligand ratio. The results of X-ray crystallographic analysis indicate that complexes 1 and 2 both crystallize in the monoclinic space group P2₁/c with α = 5.0809(14), b = 17.390(5), c = 13.399(4)Å, β = 91.677(5)°, V = 1183.4(6) Å³, Z = 4, M_r = 475.90, D_c = 2.671 g/cm³, F(000) = 912, μ= 3.352 mm^-1, S = 1.259, the final R = 0.0320 and wR = 0.0831 for 2036 observed reflections with I > 2σ(I) for 1 and α = 12.180(2), b = 5.0283(10), c = 14.396(3)Å, β = 94.87(3)º, V = 878.5(3) Å³, Z = 4, M_r = 306.02, D_c = 2.314 g/cm³, F(000) = 600, μ= 2.294 mm^-1, S = 1.053, the final R = 0.0283 and wR = 0.0684 for 2011 observed reflections with I > 2σ(I) for 2. Complexes 1 and 2 both feature a unique 2D structure. For 1, the 2D undulated network consists of 1D infinite helical chains running parallel to the b axis, while for 2, the 2D network is made up of 1D tubes along the b axis. Moreover, the Ag×××Ag interactions in complexes 1 and 2 are also discussed.

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	黄永清
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关键词 ： silver(I), coordination polymer, crystal structure, betaine derivative

Abstract：Two new Ag(I) complexes {Ag₂(L)(NO₃)(H₂O)}_n (1) and {Ag(L)}_n·nH₂O (2) have been synthesized via the reaction of silver nitrate and betaine derivative 1-carboxyme- thylpyridinium-3-carboxylate (L) by only changing the metal-to-ligand ratio. The results of X-ray crystallographic analysis indicate that complexes 1 and 2 both crystallize in the monoclinic space group P2₁/c with α = 5.0809(14), b = 17.390(5), c = 13.399(4)Å, β = 91.677(5)°, V = 1183.4(6) Å³, Z = 4, M_r = 475.90, D_c = 2.671 g/cm³, F(000) = 912, μ= 3.352 mm^-1, S = 1.259, the final R = 0.0320 and wR = 0.0831 for 2036 observed reflections with I > 2σ(I) for 1 and α = 12.180(2), b = 5.0283(10), c = 14.396(3)Å, β = 94.87(3)º, V = 878.5(3) Å³, Z = 4, M_r = 306.02, D_c = 2.314 g/cm³, F(000) = 600, μ= 2.294 mm^-1, S = 1.053, the final R = 0.0283 and wR = 0.0684 for 2011 observed reflections with I > 2σ(I) for 2. Complexes 1 and 2 both feature a unique 2D structure. For 1, the 2D undulated network consists of 1D infinite helical chains running parallel to the b axis, while for 2, the 2D network is made up of 1D tubes along the b axis. Moreover, the Ag×××Ag interactions in complexes 1 and 2 are also discussed.

Key words： silver(I) coordination polymer crystal structure betaine derivative

收稿日期: 2013-11-11 出版日期: 2014-03-05

基金资助:This work was financially supported by the National Natural Science Foundation of China (No. 21201111) and the

通讯作者: 黄永清: yqhuangskd@163.com E-mail: yqhuangskd@163.com

作者简介: 黄永清: yqhuangskd@163.com

引用本文:

黄永清;万毅;程海蒂;赵越. Synthesis and Crystal Structures of Two New Ag(I) Complexes with Betaine Derivative: Structure Changes via Metal-to-Ligand Ratio[J]. 结构化学, 2014, 33(6): 928-934.
HUANG Yong-Qing;WAN Yi;CHENG Hai-Di;ZHAO Yue. Synthesis and Crystal Structures of Two New Ag(I) Complexes with Betaine Derivative: Structure Changes via Metal-to-Ligand Ratio. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33(6): 928-934.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2014/V33/I6/928

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