The title compound, a mixed (phthalocyaninato)(porphyrinato) yttrium double-decker complex 1,has been synthesized and structurally characterized by X-ray single-crystal diffraction method. Crystal data: monoclinic, space group C2/c, Z = 8, C79H52Cl10N12O4Y, Mr= 1676.74, a =38.217(3), b = 18.9867(13), c = 26.200(3) Å, β = 128.0190(10)o,V = 14977(2) Å3, Dc= 1.487 g/cm3, μ(MoKα) = 1.196 mm−1, F(000) = 6808, R= 0.0745 and wR = 0.2208 for observed reflections with I > 2σ(I). X-ray analysis reveals that the coordination polyhedron adopts a slightly distorted square-antiprismatic structure around the metal center. Both phthalocyanine and porphyrin ligands are saucer-shaped, with the skew angle of the two ligand planes approximately 45o.
Abstract:The title compound, a mixed (phthalocyaninato)(porphyrinato) yttrium double-decker complex 1,has been synthesized and structurally characterized by X-ray single-crystal diffraction method. Crystal data: monoclinic, space group C2/c, Z = 8, C79H52Cl10N12O4Y, Mr= 1676.74, a =38.217(3), b = 18.9867(13), c = 26.200(3) Å, β = 128.0190(10)o,V = 14977(2) Å3, Dc= 1.487 g/cm3, μ(MoKα) = 1.196 mm−1, F(000) = 6808, R= 0.0745 and wR = 0.2208 for observed reflections with I > 2σ(I). X-ray analysis reveals that the coordination polyhedron adopts a slightly distorted square-antiprismatic structure around the metal center. Both phthalocyanine and porphyrin ligands are saucer-shaped, with the skew angle of the two ligand planes approximately 45o.