Heterometallic Trinuclear Ni2Zn and Ni2Mn Complexes of Macrocyclic Oxamide: Synthesis and Crystal Structurees
孙亚秋;刘尚远;王菁
天津师范大学化学学院
Heterometallic Trinuclear Ni2Zn and Ni2Mn Complexes of Macrocyclic Oxamide: Synthesis and Crystal Structurees
SUN Ya-Qiu;LIU Shang-Yuan;WANG Jing
Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry and Life Science, Tianjin Normal University, Tianjin 300387, China
摘要Two novel heterometallic trinuclear complexes of macrocyclic oxamide [Mn(NiL)2(HBTC)H2O] (1) and [Zn(NiL)2(HBTC)H2O] (2) (NiL, H2L = 2,3-dioxo-5,6,14,15- dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-dien, H3BTC = 1,3,5-benzenetricarboxylic acid) have been solvothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. For 1, the crystals crystallize in the monoclinic system, space groupP21/c with a = 11.3595(5), b = 23.1498(11), c = 17.2558(8) Å andb =101.2530(10)°. For 2, the crystals crystallize in the monoclinic system, space groupP21/c with a = 11.5214(8), b = 20.6566(14), c = 18.4126(13) Å and b =92.6770(10)°. The structures of 1 and 2 have oxamido-bridged trinuclear [NiII2MII] units and consist of two-dimensional supramolecular architectures formed by strong O–H···O intermolecular hydrogen bonds.
Abstract：Two novel heterometallic trinuclear complexes of macrocyclic oxamide [Mn(NiL)2(HBTC)H2O] (1) and [Zn(NiL)2(HBTC)H2O] (2) (NiL, H2L = 2,3-dioxo-5,6,14,15- dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-dien, H3BTC = 1,3,5-benzenetricarboxylic acid) have been solvothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. For 1, the crystals crystallize in the monoclinic system, space groupP21/c with a = 11.3595(5), b = 23.1498(11), c = 17.2558(8) Å andb =101.2530(10)°. For 2, the crystals crystallize in the monoclinic system, space groupP21/c with a = 11.5214(8), b = 20.6566(14), c = 18.4126(13) Å and b =92.6770(10)°. The structures of 1 and 2 have oxamido-bridged trinuclear [NiII2MII] units and consist of two-dimensional supramolecular architectures formed by strong O–H···O intermolecular hydrogen bonds.
2013, Vol. 32 
