A New Layer W/Cu/S Polymer with Heterobimetallic Nodes and Tridentate Trithiocyanuric Acid
李志华, 林建地, 田崇斌, 林 平, 杜少武
中科院福建物质结构研究所
A New Layer W/Cu/S Polymer with Heterobimetallic Nodes and Tridentate Trithiocyanuric Acid
LI Zhi-Hua ; LIN Jian-Di ;TIAN Chong-Bin; LIN Ping ; DU Shao-Wu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on theStructure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Solvothermal reaction of [WS4]2- with CuCN and trithiocyanuric acid (L1) in orga- nic solvents gave rise to a new W/Cu/S polymer with a 2D anionic network, namely [Et4N]2[WS4Cu3(C3N3S3H1.5)2] (1). The anionic layer of 1 is constructed by the T-shaped {WS4Cu3} subunits as nodes and L1 as linkers and features a (4, 4) topology. Both 1 and its isomorphous compound [Et4N]2[MoS4Cu3(C3N3S3H1.5)2] (2) have been fully characterized by X-ray crystal analysis, IR and microanalyses. Compounds 1 and 2 show optical transitions with band gaps of 2.17 and 1.84 eV, respectively.
Solvothermal reaction of [WS4]2- with CuCN and trithiocyanuric acid (L1) in orga- nic solvents gave rise to a new W/Cu/S polymer with a 2D anionic network, namely [Et4N]2[WS4Cu3(C3N3S3H1.5)2] (1). The anionic layer of 1 is constructed by the T-shaped {WS4Cu3} subunits as nodes and L1 as linkers and features a (4, 4) topology. Both 1 and its isomorphous compound [Et4N]2[MoS4Cu3(C3N3S3H1.5)2] (2) have been fully characterized by X-ray crystal analysis, IR and microanalyses. Compounds 1 and 2 show optical transitions with band gaps of 2.17 and 1.84 eV, respectively.
李志华;林建地;田崇斌;林 平;杜少武. A New Layer W/Cu/S Polymer with Heterobimetallic Nodes and Tridentate Trithiocyanuric Acid[J]. , 2010, 1(12): 1874-1878.
LI Zhi-Hua;LIN Jian-Di;TIAN Chong-Bin;LIN Ping;DU Shao-Wu. A New Layer W/Cu/S Polymer with Heterobimetallic Nodes and Tridentate Trithiocyanuric Acid. , 2010, 1(12): 1874-1878.
2010, Vol. 1 
