A new one-dimensional aluminum fluorophosphate, AlP2O5(OH)3F·0.5[H2dien] (dien = diethylenetriamine), was solvothermally synthesized by using organic amine as the structure directing agent, and its structure was determined by single-crystal X-ray diffraction. The complex inorganic architecture consists of trans-corner-sharing AlO4F2 octahedra chain decorated by phosphate tetrahedra along both sides of the -F-Al-F-Al-F- backbone displaying a series of Al2P three-membered rings, which will represent a new fundamental structural type in metal phosphates.The results of CHN elemental analysis, EDS, and TGA are also presented. Crystal data: C4H18Al2F2N3O16P4, monoclinic, space group P21/c with a = 6.9107(14), b = 15.749(3), c = 8.9741(18) Å, β = 109.829(2)o, V = 918.8(3) Å3, Z = 2, Mr = 580.05, Dc = 2.097 g/cm3, μ = 0.618 mm-1, S = 1.022, F(000) = 590, the final R = 0.0510 and wR = 0.1284 for 1607 observed reflections (I > 2σ(I)).
Abstract：A new one-dimensional aluminum fluorophosphate, AlP2O5(OH)3F·0.5[H2dien] (dien = diethylenetriamine), was solvothermally synthesized by using organic amine as the structure directing agent, and its structure was determined by single-crystal X-ray diffraction. The complex inorganic architecture consists of trans-corner-sharing AlO4F2 octahedra chain decorated by phosphate tetrahedra along both sides of the -F-Al-F-Al-F- backbone displaying a series of Al2P three-membered rings, which will represent a new fundamental structural type in metal phosphates.The results of CHN elemental analysis, EDS, and TGA are also presented. Crystal data: C4H18Al2F2N3O16P4, monoclinic, space group P21/c with a = 6.9107(14), b = 15.749(3), c = 8.9741(18) Å, β = 109.829(2)o, V = 918.8(3) Å3, Z = 2, Mr = 580.05, Dc = 2.097 g/cm3, μ = 0.618 mm-1, S = 1.022, F(000) = 590, the final R = 0.0510 and wR = 0.1284 for 1607 observed reflections (I > 2σ(I)).
刘广臻;李晓玲;辛凌云;王利亚. A New One-dimensional Aluminium Fluorophosphate Templated by Organic Amine[J]. , 2011, 30(5): 660-665.
LIU Guang-Zhen;LI Xiao-Ling;WANG Li-Ya. A New One-dimensional Aluminium Fluorophosphate Templated by Organic Amine. , 2011, 30(5): 660-665.
2011, Vol. 30 
