Scintillation Properties of Ce<sup>3+</sup>/Tb<sup>3+</sup> Co-doped Oxyfluoride Glass with the Exploration of Imaging Application

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摘要

Scintillator is a material that converts high-energy rays into visible light, and has great applications in high-energy physics, medical imaging, and security inspections. As a type of scintillator, scintillation glass has the advantages of low cost, high stability, controllable shape, and ability to be prepared on a large scale. In this paper, a traditional fusion quenching method was used to prepare a cerium-terbium co-doped glass. The green characteristic light of Tb ion was observed at 543 nm. Moreover, through the doping sensitization of Ce ions, the luminescence of Tb was successfully enhanced. The material has high X-ray response sensitivity, complete stability and strong X-ray emission intensity. We use a simple X-ray imaging platform for imaging, and the results show that our glass has a spatial resolution of 7.0 lp/mm.

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	陈达艺
	李艳
	吴以恒
	王志林
	王帅华
	苏檠
	张必胜
	曾庆有
	吴少凡

关键词 ： scintillators, light yield, glass, X-ray imaging, luminescence

Abstract：

Key words： scintillators light yield glass X-ray imaging luminescence

收稿日期: 2021-02-22 出版日期: 2021-10-11

基金资助:The work was supported by the National Natural Science Foundation of China (No. 22075284, 51872287 and U2030118), Equipment Pre-research Foundation Project of China (No. 61409220309), and the Financial Support of Fujian Province under Grant 2018Y024 and Grant 2019T3011, and supported by the Open-Foundation of Key Laboratory of Laser Device Technology, China North Industries Group Corporation Limited

通讯作者: shwang@fjirsm.ac.cn E-mail: shwang@fjirsm.ac.cn

引用本文:

陈达艺;李艳;吴以恒;王志林;王帅华;苏檠;张必胜;曾庆有;吴少凡. Scintillation Properties of Ce³⁺/Tb³⁺ Co-doped Oxyfluoride Glass with the Exploration of Imaging Application[J]. 结构化学, 2021, 40(10): 1337-1345.
CHEN Da-Yi;LI Yan;WU Yi-Heng;WANG Zhi-Lin;WANG Shuai-Hua;SU Qing;ZHANG Bi-Sheng;ZENG Qing-You;WU Shao-Fan. Scintillation Properties of Ce³⁺/Tb³⁺ Co-doped Oxyfluoride Glass with the Exploration of Imaging Application. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40(10): 1337-1345.

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REFERENCES
(1) Zanella, G.; Zannoni, R.; Dalligna, R. Nuclear instruments and methods in physics research section a: accelerators, spectrometers, detectors and associated equipment. Nucl. Instr. Meth. A 1994, 345, 198–201.
(2) Anderson, D. F. Properties of the high-density scintillator cerium fluoride. IEEE T. Nucl. Sci. 1989, 36, 137–140.
(3) Blasse, G. Scintillator materials. Chem. Mater. 1994, 6, 1465–1475.
(4) Murray, R. B.; Meyer, A. Scintillation response of activated inorganic crystals to various charged particles. Phys. Rev. 1961, 122, 815–826.
(5) Liu, S.; Zheng, S. P.; Tang, C. M. Photoluminescence and radio luminescence properties of Yb3+-doped silica glass. Mater. Lett. 2015, 144, 43–45.
(6) Nguyen, L. Q.; Gabella, G.; Goldblum, B. L.; Laplace, T. A.; Carlson, J. S.; Brubaker, E.; Feng, P. L. Boron-loaded organic glass scintillators. Nucl. Instrum. Meth. A 2021, 988, 164898–7.
(7) Ortega-Alfaro, M. C.; Hernández, N.; Cerna, I.; López-Cortés, J. G.; Gómez, E.; Toscano, R. A.; Alvarez-Toledano, C. Novel dinuclear iron (0) complexes from α,β-unsaturated ketones β-positioned with sulfide and sulfoxide groups. J. Organomet. Chem. 2004, 689, 885‒893.
(8) Lecoq, P. On the stabilization of Ce, Tb, and Eu ions with different oxidation states in silica based glasses. J. Alloy. Compd. 2016, 809, 130–139.
(9) Ronda, C.; Wieczorek, H.; Khanin, V.; Rodnyi, P. Review—scintillators for medical imaging: a tutorial overview. Ecs. J. Solid. State. Sc. 2016, 5, 3121–3125.
(10) Wantana, N.; Kaewnuam, E.; Kim, H. J. X-ray/proton and photoluminescence behaviors of Sm3+ doped high density tungsten gadolinium borate scintillating glass. J. Alloy. Compd. 2020, 849, 156574–8.
(11) Lecoq, P. Development of new scintillators for medical applications. Nucl. Instrum. Meth. A 2016, 809, 130–139.
(12) Lecoq, P.; Gektin, A.; Korzhik, M. Inorganic Scintillators for Detecting Systems. Springer International Publishing, Switzerland, 2017, p1–408.
(13) Kawano, N.; Kawaguchi, N.; Okada, G. Scintillation and dosimetric properties of Ce-doped strontium aluminoborate glasses. J. Non-Cryst. Solids 2017, 030, 0022–3093.
(14) Saidi, K.; Dammak, M. Crystal structure, optical spectroscopy and energy transfer properties in NaZnPO4:Ce3+, Tb3+ phosphors for UV-based LEDs. RSC Adv. 2020, 37, 21867–21875.
(15) Yi, Z.; Lu, W.; Qian, C.; Zeng, T.; Yin, L. Urchin-like Ce/Tb co-doped GdPO4 hollow spheres for in vivo luminescence/X-ray bioimaging and drug delivery. Biomater. Sci. 2014, 10, 1404–1411.
(16) Zhang, W.; Hua, R.; Qi, X.; Zhao, J.; Qin, L.; Liu, T. Photoluminescence properties and energy transfer of Ce3+–Tb3+ co-doped SrAlF5 nanorods by a hydrothermal method. CrystEngComm. 2017, 19, 5214–5222.
(17) Liang, C.; Gong, X. H.; Huang, J. H. Preparation and spectroscopic properties of Pr3+-doped transparent glass-ceramic containing LiYF4 nanocrystals. Chin. J. Struct. Chem. 2017, 36, 614–620.
(18) Zhang, H. D.; Wang, S. H.; Wu, S. F. A new copper coordination polymer with magnetic property based on 3-(1,2,4-traiazol-1-1-yl) benzoic acid. Chin. J. Struct. Chem. 2017, 036, 2011–1615.
(19) Chen, J.; Wang, S. H.; Zhang, H. D. Crystal structure and luminescence with relative principles calculation of a new one-dimensional Zn(II) coordination polymer. Chin. J. Struct. Chem. 2017, 36, 711–715.
(20) Liang, J. X.; Xin, S. L.; Qing, Q. H. Highly efficient eco-friendly X-ray scintillators based on an organic manganese halide. Nat. Commun. 2020, 11, 4329–7.
(21) Zhang, Y. H.; Sun, R. J.; Ou, X Y. Metal halide perovskite nanosheet for X-ray high-resolution scintillation-imaging screens. ACS Nano. 2019, 13, 2520–2525.
(22) Cao, J. T.; Guo, Z.; Zhu, S. Preparation of lead-free two-dimensional-layered (C8H17NH3)2SnBr4 perovskite scintillators and their application in X-ray imaging. ACS Appl. Mater. Inter. 2020, 12, 19797–19804.
(23) Qiu, Z. H.; Wang, S. H.; Wang, W. Q. Polymer composites entrapped Ce-doped LiYF4 microcrystals for high-sensitivity X-ray scintillation and imaging. ACS. Appl. Mater. Inter. 2020, 12, 29835–29843.
(24) Jin, H. H.; Dong, H. S. High-performance next-generation perovskite nanocrystal scintillator for nondestructive X-ray imaging. Adv. Mater. 2018, 1801743–6.