Three New Isostructural Metal-organic Coordination Polymers from Triangular Pyridinedicarboxylate Ligand:Syntheses, Structures and Properties

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摘要: Three new isostructural coordination polymers, namely, [Mg(cpna)(H2O)2]n (1), [Mn(cpna)(H2O)2]n (2) and [Co(cpna)(H2O)2]n (3) (H2cpna = 5-(3-carboxylphenyl)nicotic acid) are reported. They were synthesized by hydrothermal reactions of transition metal or alkaline earth metal chloride with 5-(3-carboxylphenyl)nicotic acid, respectively. Complexes 1～3 exhibit 2D layers with a 3,3-connected topology with Schläfli symbol {4.82}. Such layers including hexagonal rings and a quadrangular ring are further extended into an ordered 3D framework by hydrogen bonds between the cpna2- ligands and water molecules. The rare complex 1 has excellent luminescence and can be used as luminescent materials, while 2 and 3 possess prominent magnetism with potential applications in magnetic materials.

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	朱凌彬
	李斐
	孙明玲
	覃业燕
	姚元根

关键词: isostructural polymer, 2D layers, 3D framework, hydrogen bonds, luminescence, magnetism

Abstract:Three new isostructural coordination polymers, namely, [Mg(cpna)(H2O)2]n (1), [Mn(cpna)(H2O)2]n (2) and [Co(cpna)(H2O)2]n (3) (H2cpna = 5-(3-carboxylphenyl)nicotic acid) are reported. They were synthesized by hydrothermal reactions of transition metal or alkaline earth metal chloride with 5-(3-carboxylphenyl)nicotic acid, respectively. Complexes 1～3 exhibit 2D layers with a 3,3-connected topology with Schläfli symbol {4.82}. Such layers including hexagonal rings and a quadrangular ring are further extended into an ordered 3D framework by hydrogen bonds between the cpna2- ligands and water molecules. The rare complex 1 has excellent luminescence and can be used as luminescent materials, while 2 and 3 possess prominent magnetism with potential applications in magnetic materials.

Key words: isostructural polymer 2D layers 3D framework hydrogen bonds luminescence magnetism

收稿日期: 2020-12-25 出版日期: 2021-07-28

基金资助:This research was supported by the National Natural Science Foundation of China (21703247) and the Science Foundation of Fujian Province (2018J05029, 2019J05156, 2019H0053)

通讯作者: yyg@fjirsm.ac.cn E-mail: yyg@fjirsm.ac.cn

引用本文:

朱凌彬;李斐;孙明玲;覃业燕;姚元根. Three New Isostructural Metal-organic Coordination Polymers from Triangular Pyridinedicarboxylate Ligand:Syntheses, Structures and Properties[J]. 结构化学, 2021, 40(8): 1031-1038.
ZHU Ling-Bin;LI Fei;SUN Ming-Ling;QIN Ye-Yan;YAO Yuan-Gen. Three New Isostructural Metal-organic Coordination Polymers from Triangular Pyridinedicarboxylate Ligand:Syntheses, Structures and Properties. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40(8): 1031-1038.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2021/V40/I8/1031

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