Syntheses, Structures and Photocurrent Response Properties of Two Crystals Based on Tetrathiafulvalene Derivatives
肖宁;韩磊;温一航;王乐佳;肖勋文
a (School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, China)
b (Zhejiang Key Laboratory for Reactive Chemistry On Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China)
c (School of Material and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, China)
Syntheses, Structures and Photocurrent Response Properties of Two Crystals Based on Tetrathiafulvalene Derivatives
a (School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, China)
b (Zhejiang Key Laboratory for Reactive Chemistry On Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China)
c (School of Material and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, China)
摘要 In this paper, two compounds [Zn22+(2,6-bis(4΄-pyridyl)-TTF)(TPA)22-] (1) and [Cd2+(2,6(7)-bis(4΄-pyridyl)-TTF)(TPA)2-(H2O)2] (TTF = tetrathiafulvalene, TPA = terephthalic acid) (2) were synthesized by using solvothermal method and characterized by single-crystal X-ray. The purity of the two compounds was confirmed by their PXRD data. We also tested the photocurrent responses of these two compounds, and found they could generate photocurrent signal when exposed to light, but the photocurrent intensity of compound 2 is significantly greater than that of 1. From the crystal structure analysis, the possible reason for this phenomenon is that 2 has a more compact ligand arrangement than 1, leading to a higher carrier density and easier excitation.
In this paper, two compounds [Zn22+(2,6-bis(4΄-pyridyl)-TTF)(TPA)22-] (1) and [Cd2+(2,6(7)-bis(4΄-pyridyl)-TTF)(TPA)2-(H2O)2] (TTF = tetrathiafulvalene, TPA = terephthalic acid) (2) were synthesized by using solvothermal method and characterized by single-crystal X-ray. The purity of the two compounds was confirmed by their PXRD data. We also tested the photocurrent responses of these two compounds, and found they could generate photocurrent signal when exposed to light, but the photocurrent intensity of compound 2 is significantly greater than that of 1. From the crystal structure analysis, the possible reason for this phenomenon is that 2 has a more compact ligand arrangement than 1, leading to a higher carrier density and easier excitation.
基金资助:This work was supported by the Natural Science Foundation of Zhejiang Province (LY18B020016) and Ningbo Science and Technology Innovation 2025(2018B10033)
通讯作者:
wyh@zjnu.edu.cn
E-mail: wyh@zjnu.edu.cn
引用本文:
肖宁;韩磊;温一航;王乐佳;肖勋文. Syntheses, Structures and Photocurrent Response Properties of Two Crystals Based on Tetrathiafulvalene Derivatives[J]. 结构化学, 2021, 40(6): 759-767.
XIAO Ning;HAN Lei;WEN Yi-Hang;WANG Le-Jia;XIAO Xun-Wen. Syntheses, Structures and Photocurrent Response Properties of Two Crystals Based on Tetrathiafulvalene Derivatives. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40(6): 759-767.
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2021, Vol. 40 
