A Robust, Water-stable, and Multifunctional Praseodymium-organic Framework Showing Permanent Porosity, CO<sub>2 </sub>Adsorption Properties,and Selective Sensing of Fe<sup>3+</sup> Ion

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摘要 A robust microporous praseodymium-organic framework, {[Pr3(NTB)3(H2O)3]·(DMF)3(H2O)4}n (Pr-NTB, 1), was solvothermally synthesized based on 4,4΄,4΄΄-nitrilotribenzoic acid (H3NTB) and fully characterized. Single-crystal X-ray diffraction analysis reveals compound 1 possesses a three-dimensional porous coordination network, in which discrete cages are connected through microporous windows. 1 shows extraordinary thermal and water stability; in particular, it is stable in aqueous media from pH = 3 to 11, which is outstanding in benzyl-carboxylate based MOFs. Furthermore, 1 exhibits permanent porosity with the BET surface area of 156.2 m2·g-1 and can adsorb suitable CO2 (1.14 mmol·g-1 at 273 K/1 bar) with isosteric heat of adsorption (Qst) of 28.5 kJ·mol-1. These features suggest that the porous material 1 is a good candidate for CO2 capture in real-world application. Notably, the integration of fluorescent property, porosity and water stability in 1 promises it as a selective fluorescent sensor for Fe3+ cation in water.

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	姚清侠
	田苗苗
	王瑶
	孟玉洁
	王君
	姚青媛
	周新
	杨华
	王怀伟
	李允伍
	张杰

关键词 ： metal-organic framework, water stability, permanent porosity, CO2 capture, selective sensing

Abstract：

A robust microporous praseodymium-organic framework, {[Pr3(NTB)3(H2O)3]·(DMF)3(H2O)4}n (Pr-NTB, 1), was solvothermally synthesized based on 4,4΄,4΄΄-nitrilotribenzoic acid (H3NTB) and fully characterized. Single-crystal X-ray diffraction analysis reveals compound 1 possesses a three-dimensional porous coordination network, in which discrete cages are connected through microporous windows. 1 shows extraordinary thermal and water stability; in particular, it is stable in aqueous media from pH = 3 to 11, which is outstanding in benzyl-carboxylate based MOFs. Furthermore, 1 exhibits permanent porosity with the BET surface area of 156.2 m2·g-1 and can adsorb suitable CO2 (1.14 mmol·g-1 at 273 K/1 bar) with isosteric heat of adsorption (Qst) of 28.5 kJ·mol-1. These features suggest that the porous material 1 is a good candidate for CO2 capture in real-world application. Notably, the integration of fluorescent property, porosity and water stability in 1 promises it as a selective fluorescent sensor for Fe3+ cation in water.

Key words： metal-organic framework water stability permanent porosity CO2 capture selective sensing

收稿日期: 2020-06-29 出版日期: 2020-10-10

基金资助:Financially supported by the National Natural Science Foundation of China (21501086, 21701978, 21801108), the Shandong Provincial Natural Science Foundation (ZR2014BQ035), and the Youth Innovation Team of Shandong Colleges and Universities (2019KJC027). Yao Q. thanks the financial supports from Liaocheng University (318051401) and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry

通讯作者: yaoqxlcu@163.com E-mail: yaoqxlcu@163.com

引用本文:

姚清侠;田苗苗;王瑶;孟玉洁;王君;姚青媛;周新;杨华;王怀伟;李允伍;张杰;. A Robust, Water-stable, and Multifunctional Praseodymium-organic Framework Showing Permanent Porosity, CO₂Adsorption Properties,and Selective Sensing of Fe³⁺ Ion[J]. 结构化学, 2020, 39(10): 1862-1870.
YAO Qing-Xia;TIAN Miao-Miao;WANG Yao;MENG Yu-Jie;WANG Jun;YAO Qing-Yuan;ZHOU Xin;YANG Hua;WANG Huai-Wei;LI Yun-Wu;ZHANG Jie. A Robust, Water-stable, and Multifunctional Praseodymium-organic Framework Showing Permanent Porosity, CO₂ Adsorption Properties,and Selective Sensing of Fe³⁺ Ion. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39(10): 1862-1870.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2020/V39/I10/1862

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