Synthesis, Crystal Structure, and Photoluminescent Property of a 2-Fold Interpenetrating Znic(II) Coordination Polymer with 2,5-Dicarboxylic Acid-3,4-ethylene Dioxythiophene

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摘要

A three-dimensional coordination polymer, [Zn2(L)2(bpp)(H2O)2]n (H2L = 2,5-dicarboxylic acid- 3,4-ethylene dioxythiophene, bpp = 1,3-di(4-pyridyl)propane), was synthesized with high yield under solvothermal reaction conditions and structurally characterized by elemental analysis, infrared spectra, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction analysis. It crystallizes in orthorhombic space group Pnma with a = 16.6542(9), b = 18.0868(10), c = 10.7528(5) Å, V = 3239.0(3) Å3, Z = 4, Dc = 1.684 g/cm3, Mr = 821.38, Dc = 1.684 g/cm3, µ = 1.683 mm−1, F(000) = 1672, R = 0.0466, wR = 0.0933 and S = 1.066. The compound exhibits a three-dimensional structure, which can be simplified into a 2-fold interpenetrated pcu topological network. Moreover, it displays luminescence emission in the solid state at room temperature.

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	李召好
	周毓璇
	倪园园

关键词 ： coordination polymer, 2,5-dicarboxylic acid-3,4-ethylene dioxythiophene, 1,3-bis(4-pyridyl)propane, crystal structure, photoluminescent property

Abstract：

Key words： coordination polymer 2,5-dicarboxylic acid-3,4-ethylene dioxythiophene 1,3-bis(4-pyridyl)propane crystal structure, photoluminescent property

收稿日期: 2019-12-09 出版日期: 2020-09-11

基金资助:This work was supported by the NNSFC (No. 21671094)

通讯作者: lylizh@126.com E-mail: lylizh@126.com

引用本文:

李召好;周毓璇;倪园园. Synthesis, Crystal Structure, and Photoluminescent Property of a 2-Fold Interpenetrating Znic(II) Coordination Polymer with 2,5-Dicarboxylic Acid-3,4-ethylene Dioxythiophene[J]. 结构化学, 2020, 39(9): 1729-1734.
LI Zhao-Hao;ZHOU Yu-Xuan;NI Yuan-Yuan . Synthesis, Crystal Structure, and Photoluminescent Property of a 2-Fold Interpenetrating Znic(II) Coordination Polymer with 2,5-Dicarboxylic Acid-3,4-ethylene Dioxythiophene#br#. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39(9): 1729-1734.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2020/V39/I9/1729

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