Syntheses, Crystal Structures, and Electrochemical Properties of Dehydroabietic Acid-based Schiff Bases

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摘要 Two Schiff bases (DAMBA-Fc and DAA-Fc) derived from dehydroabietic acid have been successfully synthesized and characterized by means of FT-IR, elemental analysis, HRMS, and NMR spectroscopy. The crystal structure of DAA-Fc can be determined by single-crystal X-ray diffraction. The compound is of monoclinic system, space group P21 with a = 10.7379(6), b = 7.5004(4), c = 33.3294(18) Å, β = 97.996(3)º, Z = 4, V = 2658.2(3) Å3, Mr = 481.48, Dc = 1.203 g/cm3, S = 1.034, μ = 0.585 mm-1, F(000) = 1032, the final R = 0.0566 and wR = 0.0701 for 5645 observed reflections (I > 2σ(I)). In addition, cyclic and differential pulse voltammogram techniques have been applied to differentiate the redox properties of the aromatic- and aliphatic-connected Schiff bases DAMBA-Fc and DAA-Fc, respectively.

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	蔡旭敏
	陈新菲
	穆天齐
	蔺玉婷
	黄申林
	姚敏霞

关键词 ： dehydroabietic acid, ferrocene, Schiff base, crystal structure, electrochemical properties

Abstract： Two Schiff bases (DAMBA-Fc and DAA-Fc) derived from dehydroabietic acid have been successfully synthesized and characterized by means of FT-IR, elemental analysis, HRMS, and NMR spectroscopy. The crystal structure of DAA-Fc can be determined by single-crystal X-ray diffraction. The compound is of monoclinic system, space group P21 with a = 10.7379(6), b = 7.5004(4), c = 33.3294(18) Å, β = 97.996(3)º, Z = 4, V = 2658.2(3) Å3, Mr = 481.48, Dc = 1.203 g/cm3, S = 1.034, μ = 0.585 mm-1, F(000) = 1032, the final R = 0.0566 and wR = 0.0701 for 5645 observed reflections (I > 2σ(I)). In addition, cyclic and differential pulse voltammogram techniques have been applied to differentiate the redox properties of the aromatic- and aliphatic-connected Schiff bases DAMBA-Fc and DAA-Fc, respectively.

Key words： dehydroabietic acid ferrocene Schiff base crystal structure electrochemical properties

收稿日期: 2019-10-14 出版日期: 2020-09-11

基金资助:Supported by the National Natural Science Foundation of China (21601087 and 21401101), the Topnotch Academic Programs Project (TAPP), and the Priority Academic Program Development of Jiangsu Higher Education Institution (PAPD) The authors also acknowledge the Advanced Analysis & Testing Center of Nanjing Forestry University for testing services

通讯作者: xumin.cai@njfu.edu.cn E-mail: xumin.cai@njfu.edu.cn;

引用本文:

蔡旭敏;陈新菲;穆天齐;蔺玉婷;黄申林;姚敏霞. Syntheses, Crystal Structures, and Electrochemical Properties of Dehydroabietic Acid-based Schiff Bases[J]. 结构化学, 2020, 39(9): 1699-1706.
CAI Xu-Min;CHEN Xin-Fei;MU Tian-Qi;LIN Yu-Ting;HUANG Shen-Lin;YAO Min-Xia. Syntheses, Crystal Structures, and Electrochemical Properties of Dehydroabietic Acid-based Schiff Bases. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39(9): 1699-1706.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2020/V39/I9/1699

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