Synthesis, Characterization and Adsorption Properties for Al-based Metal-organic Framework

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摘要 Al-BTC MOFs were prepared in a facile manner via a solvothermal reaction and characterized using FT-IR, XRD, and SEM. The compound was then evaluated as an adsorbent to remove Congo red (CR) from an aqueous solution. The adsorption kinetics was evaluated using the pseudo-first-order and pseudo-second-order, and it was found that the adsorption of CR onto the MOFs was well described by the pseudo-second-order equation. The as-prepared MOFs adsorbent seems to be a promising material in practice for dyes removal from aqueous solution.

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	聂玉静
	邓严华
	郭鸿旭
	应少明

关键词 ： Al-based metal-organic framework, characterization, adsorption properties, Congo red

Abstract：Al-BTC MOFs were prepared in a facile manner via a solvothermal reaction and characterized using FT-IR, XRD, and SEM. The compound was then evaluated as an adsorbent to remove Congo red (CR) from an aqueous solution. The adsorption kinetics was evaluated using the pseudo-first-order and pseudo-second-order, and it was found that the adsorption of CR onto the MOFs was well described by the pseudo-second-order equation. The as-prepared MOFs adsorbent seems to be a promising material in practice for dyes removal from aqueous solution.

Key words： Al-based metal-organic framework characterization adsorption properties Congo red

收稿日期: 2019-08-21 出版日期: 2020-06-10

基金资助:This project was supported by the Natural Science Foundation of Fujian Province (No. 2017J01420 and 2018H0030), Education Bureau of Fujian Province (JZ160453) and Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry (FJKL_FBCM201902)

通讯作者: nieyujing@sina.com E-mail: nieyujing@sina.com

引用本文:

聂玉静;邓严华;郭鸿旭;应少明. Synthesis, Characterization and Adsorption Properties for Al-based Metal-organic Framework[J]. 结构化学, 2020, 39(6): 1029-1034.
NIE Yu-Jing;DENG Yan-Hua;GUO Hong-Xu;YING Shao-Ming. Synthesis, Characterization and Adsorption Properties for Al-based Metal-organic Framework. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39(6): 1029-1034.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2020/V39/I6/1029

REFERENCES
(1) Zhu, T.; Chen, J. S.; Lou, X. W. Highly efficient removal of organic dyes from waste water using hierarchical NiO spheres with high surface area.J.Phys. Chem. C 2012, 116, 68736878.
(2) Bulut, E.; Özacar, M.; Şengil, İ. A. Equilibrium and kinetic data and process design for adsorption of Congo red onto bentonite. J. Hazard. Mater. 2008,154, 613622.
(3) Khan, N. A.; Hasan, Z.; Jhung, S. H. Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review. J. Hazard. Mater.2013, 244–245, 444456.
(4) Guo, H. X.; Niu, B. T.; Wu, X. M.; Zhang, Y.; Ying, S. M. Effective removal of 2,4,6-trinitrophenol over hexagonal metal-organic framework NH2-MIL-88B(Fe). Appl. Organometal Chem. 2019, 33, 458011.
(5) Wu, Y. W.; Wu, X. M.; Niu, B. T.; Zeng, Y. P.; Zhu, M. H.; Guo, H. X. Facile fabrication of Ag2(bdc)@Ag nano-composites with strong green emission and their response to sulfide anion in aqueous medium. Sens. Actuators B 2018, 255, 31633169.
(6) Wang, D. F.; Ke, Y. C.; Guo, D.; Guo, H. X.; Chen, J. H.; Weng, W. Facile fabrication of cauliflower-like MIL-100 (Cr) and its simultaneous determination of Cd2+, Pb2+, Cu2+ and Hg2+ from aqueous solution. Sens. Actuators B 2015, 216, 504510.
(7) Guo, H. X.; Guo, D.; Zheng, Z. S.; Weng, W.; Chen, J. H. Visible-light photocatalytic activity of Ag@MIL-125 (Ti) microspheres. Appl. Organomet.Chem. 2015, 29, 618623.
(8) Haque, E.; Lee, J. E.; Jang, I. T.; Hwang, Y. K.; Chang, J. S.; Jegal, J.; Jhung, S. H. Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworks, porous chromium-benzenedicarboxylates. J. Hazard. Mater. 2010, 181, 535542.
(9) Haque, E.; Jun, J. W.; Jhung, S. H. Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235). J. Hazard. Mater. 2011, 185, 507511.
(10) Huo, S. H.; Yan, X. P. Metal-organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution. J. Mater. Chem. 2012, 22, 74497455.
(11) Patil, D. V.; Rallapalli, P. B. S.; Dangi, G. P.; Tayade, R. J.; Somani, R. S.; Bajaj, H. C. MIL-53(Al): an efficient adsorbent for the removal of nitrobenzene from aqueous solutions. Ind. Eng. Chem. Res. 2011, 50, 1051610524.
(12) Li, L.; Xiang, S. L.; Cao, S. Q.; Zhang, J. Y.; Ouyang, G. F.; Chen, L. P.; Su, C. Y. A synthetic route to ultralight hierarchically micro/mesoporous Al(III)-carboxylate metal-organic aerogels. Nat. Commun. 2013, 4, 17741782.
(13) Volkringer, C.; Popov, D.; Loiseau, T.; Ferey, G.; Burghammer, M.; Riekel, C.; Haouas, M.; Taulelle, F. Synthesis, single-crystal X-ray microdiffraction, and NMR characterizations of the giant pore metal-organic framework aluminum trimesate MIL-100. Chem. Mater. 2009, 21, 56955696.
(14) Loiseau, T.; Lecroq, L.; Volkringer, C.; Marrot, J.; Ferey, G.; Haouas, M.; Taulelle, F.; Bourrelly, S.; Llewellyn, P.; Latroche. M. MIL-96, a porous aluminum trimesate 3D structure constructed from a hexagonal network of 18-membered rings and μ3-oxo-centered trinuclear units. J. Am. Chem. Soc. 2006, 128, 1022310230.
(15) Wang, L.; Li, J.; Wang, Y.; Zhao, L.; Jiang, Q. Adsorption capability for Congo red on nanocrystalline MFe2O4 (M = Mn, Fe, Co, Ni) spinel ferrites. Chem. Eng. J. 2012, 72, 181182.
(16) Hameed, B. H.; Rahman, A. A. Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared from biomass material. J. Hazard. Mater. 2008, 160, 576581.
(17) Auta, M.; Hameed, B. H. Chitosan-clay composite as highly effective and low-cost adsorbent for batch and fixed-bed adsorption of methylene blue. Chem. Eng. J. 2014, 237, 352361.