Synthesis of a Rare Doubly-interpenetrating Zinc(II) Coordination Polymer for Applications in Photocatalysis

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摘要 A rare doubly-interpenetrating Zn-MOF (complex 1), formulated as {[Zn(tci)- (bpy)(NO3)·DMF·0.5CH3CN}n (H3tci = tri(2-carboxyethyl) isocyanurate, bpy = 4,4-bipyridine), has been constructed under solvothermal conditions and characterized by single-crystal X-ray diffraction, infrared spectroscopy (IR) and powder X-ray diffraction (PXRD). 1 crystallizes in monoclinic system, space group C2/c with a = 21.5759(4), b = 12.87221(18), c = 26.4917(5) Å, β = 109.462(2)°, V = 6937.1(2) Å3, C50H56N14O27Zn4, Mr = 1546.56, Z = 4, Dc = 1.481 g·cm-3, μ = 2.325 mm-1 λ = 1.54178 Å, F(000) = 3160, S = 1.041, R = 0.0621 and wR = 0.1773. 1 features a two-fold interpenetrating 3D hms topology. Moreover, the thermal stabilities, fluorescent and CO2 adsorption properties were investigated. Complex 1 showed highly encoura- ging photocatalytic degradation of toxic dye molecules with a potential application in wastewater purification.

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	蔡紫薇
	孙杰
	潘业婷
	江婷婷
	李清
	崔培培
	张捷

关键词 ： Zn-MOF, solvothermal conditions, thermal stabilities, CO2 adsorption, fluorescent property, photocatalytic performance

Abstract：A rare doubly-interpenetrating Zn-MOF (complex 1), formulated as {[Zn(tci)- (bpy)(NO3)·DMF·0.5CH3CN}n (H3tci = tri(2-carboxyethyl) isocyanurate, bpy = 4,4-bipyridine), has been constructed under solvothermal conditions and characterized by single-crystal X-ray diffraction, infrared spectroscopy (IR) and powder X-ray diffraction (PXRD). 1 crystallizes in monoclinic system, space group C2/c with a = 21.5759(4), b = 12.87221(18), c = 26.4917(5) Å, β = 109.462(2)°, V = 6937.1(2) Å3, C50H56N14O27Zn4, Mr = 1546.56, Z = 4, Dc = 1.481 g·cm-3, μ = 2.325 mm-1 λ = 1.54178 Å, F(000) = 3160, S = 1.041, R = 0.0621 and wR = 0.1773. 1 features a two-fold interpenetrating 3D hms topology. Moreover, the thermal stabilities, fluorescent and CO2 adsorption properties were investigated. Complex 1 showed highly encoura- ging photocatalytic degradation of toxic dye molecules with a potential application in wastewater purification.

Key words： Zn-MOF solvothermal conditions thermal stabilities CO2 adsorption fluorescent property photocatalytic performance

收稿日期: 2019-09-24 出版日期: 2020-04-13

基金资助:This work was supported by the National Natural Science Foundation of China (Nos. 21401096 and 21701021)

通讯作者: jiesunld@163.com E-mail: jiesunld@163.com

引用本文:

蔡紫薇;孙杰;潘业婷;江婷婷;李清;崔培培;张捷. Synthesis of a Rare Doubly-interpenetrating Zinc(II) Coordination Polymer for Applications in Photocatalysis[J]. 结构化学, 2020, 39(4): 718-726.
CAI Zi-Wei;SUN Jie;PAN Ye-Ting;JIANG Ting-Ting;LI Qing;CUI Pei-Pei;ZHANG Jie. Synthesis of a Rare Doubly-interpenetrating Zinc(II) Coordination Polymer for Applications in Photocatalysis. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 39(4): 718-726.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2020/V39/I4/718

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