A Phenyl Sulfide Functionalized Luminescent Sensors for Efficient Fe3+ and Cr2O72- Ions Detection

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摘要 A new complex, {[Cd(BIDPT)(NBA)]}n (1), was synthesized from the self- assembly of BIDPT (BIDPT = 4,4΄-bis(imidazol-l-yl)diphenyl thioether) and H2NBA (H2NBA = 4,4΄-azanediyldibenzoic acid) ligands with Cd(II). 1 was characterized by infrared spectroscopy, powder X-ray diffraction, elemental analysis, and thermogravimetry measurement. 1 crystallizes in monoclinic system, space group P21/c with a = 8.8204(1), b = 29.835(3), c = 10.3813(1) Å, β = 96.180(2), V = 2730.7(5) Å3, Z = 4, C32H22CdN5O4S, Mr = 685.01, Dc = 1.666 g/cm3, μ = 0.926 mm-1, R = 0.0548 and wR = 0.1528. 1 features a parallel structure with 3-connected hcb network and the adjacent 2D networks are stacked together via C–H···π interaction to form a 3D network. Its application in detecting metal cations and inorganic anions was explored. 1 exhibits excellent photoluminescence sensing for Fe3+ and Cr2O72- ions. And the mechanism of quenching is also studied.

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	徐涵
	潘兆瑞

关键词 ： luminescent sensor, helical chain, quenching mechanism

Abstract：A new complex, {[Cd(BIDPT)(NBA)]}n (1), was synthesized from the self- assembly of BIDPT (BIDPT = 4,4΄-bis(imidazol-l-yl)diphenyl thioether) and H2NBA (H2NBA = 4,4΄-azanediyldibenzoic acid) ligands with Cd(II). 1 was characterized by infrared spectroscopy, powder X-ray diffraction, elemental analysis, and thermogravimetry measurement. 1 crystallizes in monoclinic system, space group P21/c with a = 8.8204(1), b = 29.835(3), c = 10.3813(1) Å, β = 96.180(2), V = 2730.7(5) Å3, Z = 4, C32H22CdN5O4S, Mr = 685.01, Dc = 1.666 g/cm3, μ = 0.926 mm-1, R = 0.0548 and wR = 0.1528. 1 features a parallel structure with 3-connected hcb network and the adjacent 2D networks are stacked together via C–H···π interaction to form a 3D network. Its application in detecting metal cations and inorganic anions was explored. 1 exhibits excellent photoluminescence sensing for Fe3+ and Cr2O72- ions. And the mechanism of quenching is also studied.

Key words： luminescent sensor helical chain quenching mechanism

收稿日期: 2019-04-08 出版日期: 2019-12-12

基金资助:The work was supported by Key Projects of Natural Science Research in Universities of Anhui Province (No. KJ2018A0409),National Undergraduate Training Programs for Innovation and Entrepreneurship (No. 201810375012, 201810375039)

通讯作者: pzr_2006@163.com E-mail: pzr_2006@163.com

引用本文:

徐涵;潘兆瑞. A Phenyl Sulfide Functionalized Luminescent Sensors for Efficient Fe³⁺ and Cr₂O₇^2-Ions Detection[J]. 结构化学, 2019, 38(12): 2121-2128.
XU Han;PAN Zhao-Rui. A Phenyl Sulfide Functionalized Luminescent Sensors for Efficient Fe³⁺ and Cr₂O₇^2- Ions Detection. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38(12): 2121-2128.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2019/V38/I12/2121

REFERENCES
(1) Wu, B.; Zhang, W. H.; Ren, Z. G.; Lang, J. P. A 1D anionic coordination polymer showing superior red sorption and its dye composite exhibiting remarkably enhanced photocurrent response. Chem. Commun. 2015, 51, 14893–14896.
(2) Gao, C. Y.; Tian, H. R.; A, J.; Li, L. J.; Dang, S.; Lan, Y. Q.; Sun, Z. M. A microporous Cu-MOF with optimized open metal sites and pore spaces for high gas storage and active chemical fixation of CO2. Chem. Commun. 2016, 52, 11147–11150.
(3) Zhu, X. Y.; Gu, J. L.; Wang, Y.; Li, B.; Li, Y. S.; Zhao, W. R.; Shi, J. L. Inherent anchorages in UiO-66 nanoparticles for efficient capture of alendronate and its mediated release. Chem. Commun. 2014, 50, 8779–8782.
(4) Ding, R.; Huang, C.; Lu, J. J.; Wang, J. N.; Song, C. J.; Wu, J.; Hou, H. W.; Fan, Y. T. Solvent templates induced porous metal-organic materials: conformational isomerism and catalytic activity. Inorg. Chem. 2015, 54, 1405–1413.
(5) Yang, Q.; Xu, Q.; Yu, S. H.; Jinag H. L. Pd nanocubes@ZIF-8: integration of plasmon-deriven photothermal conversion with a metal-organic framework for efficient and selective catalysis. Angew. Chem. Int. Ed. 2015, 55, 3685–3689.
(6) Zhou, S. Y.; Li, X.; Li, T.; Tian, L.; Liu, Z. Y.; Wang, X. G. A series of heterospin complexes based on lanthanides and pyridine biradicals: synthesis, structure and magnetic properties. RSC Adv. 2015, 5, 17131–17139.
(7) Zhao, J. P.; Han, S. D.; Jiang, X.; Xu, J.; Chang, Z.; Bu, X. H. A three dimensional magnetically frustrated metal-organic framework via the vertices augmentation of underlying net. Chem. Commun. 2015, 51, 4627–4630.
(8) Huang, Y. G.; Yuan, D. Q.; Pan, L.; Jinag, F. L.; Wu, M. Y.; Zhang, X. D.; Wei, W.; Lee, J.; Li, J. Y.; Hong, M. C. A 3D porous cobalt-organic framework exhibiting spin-canted antiferromagnetism and field-induced spin-flop transition. Inorg. Chem. 2007, 46, 9609–9615.
(9) Lu, Z. Z.; Zhang, R.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Solvatochromic behavior of a nanotubular metal-organic framework for sensing small molecules. J. Am. Chem. Soc. 2011, 133, 4172–4174.
(10) Ding, S. Y.; Dong, M.; Wang, Y. W.; Chen, Y. T.; Wang, H. Z.; Su, C. Y.; Wang, W. Thioether-based fluorescent covalent organic framework for selective detection and facile removal of mercury(II). J. Am. Chem. Soc. 2011, 133, 4172–4174.
(11) Ji, G. F.; Gao, X. C.; Zheng, T. X.; Guan, W. H; Liu, H. T.; Liu, Z. L. Postsynthetic metalation metal-organic framework as a fluorescent probe for the ultrasensitive and reversible detection of PO43- ions. Inorg. Chem. 2018, 57, 10525–10532.
(12) Xiao, Z. Z.; Han, L. J.; Wang, Z. J.; Zheng, H. G. Three Zn(II)-based MOFs for luminescence sensing of Fe3+ and Cr2O72- ions. Dalton Trans. 2018, 47, 3298–3302.
(13) Chen S. G.; Shi, Z. Z; Qin, L.; Jia, H. L.; Zheng, H. G. Two new luminescence Cd(II)-metal-organic frameworks as bifunctional chmosensors for detection of cations Fe3+, anions CrO42- and Cr2O72- in aqueous solution. Cryst. Growth Des. 2017, 17, 67–72.
(14) Han L. J.; Yan, W.; Chen, S. G.; Shi, Z. Z.; Zheng, H. G. Exploring the detection of metal ions by tailoring the coordination mode of V-Shaped thienylpyridyl ligand in three MOFs. Inorg. Chem. 2017, 56, 2936–2940.
(15) Zhao, J.; Wang, Y. N.; Dong, W. W.; Wu. Y. P.; Li, D. S.; Zhang, Q. C. A robust luminescent Tb(III)-MOF with lewis basic pyridyl sites for the highly sensitive detection of metal ions and small molecules. Inorg. Chem. 2016, 55, 3265–3271.
(16) Hu, J. S.; Shang, Y. J.; Yao X. Q.; Qin, L.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G.; Xue, Z. L. Syntheses, structures, and photochemical properties of six new metal-organic frameworks based on aromatic dicarboxylate acids and V-shaped imidazoles ligands. Cryst. Growth Des. 2010, 10, 4135–4142.
(17) Sheldrick, G. M. SHELXL-97, Program for X-ray Crystal Structure Refinement. University of Göttingen, Germany 1997.
(18) Gong, Y. Q.; Mi, T. Q.; Liang, W. T. Synthesis, crystal structure and properties of a 3-fold interpenetrating 3D Cd(Ⅱ) complex derived from 4-(2-methyl-1H-imidazol-1-yl) benzoic acid. Chin. J. Struct. Chem. 2016, 10, 1600–1605.
(19) Wang, X. Y.; Li, G. T.; Sun, Y. D.; Zhang, Y.; liu, D. X.; Xu, Z. L. A new luminescent Cd(Ⅱ) coordination polymer constructed with 2-(carboxymethoxy) benzoic acid. Chin. J. Struct. Chem. 2018, 37, 1939–1944.
(20) Zhu, E. W.; Sun, J. J.; Jia, Y.; Qiao, Y.; Zhu, Y.; Che, G. B. Two Cd(Ⅱ) coordination polymers based on a flexible tricarboxylate ligand: syntheses, structures, and photoluminescence and catalytic properties. Chin. J. Struct. Chem. 2018, 37, 2003–2010.
(21) Ji, N. N.; Shi, Z. Q.; Hu, H. L.; Zheng, H. G. A triphenylamine-functionalized luminescent sensor for efficient p-nitroaniline detection. Dalton Trans. 2018, 47, 7222–7228.
(22) Wang, B.; Lv, X. L.; Feng, D. W.; Xie, L. H.; Zhang, J.; Li, M.; Xie, Y. B.; Li, J. R.; Zhou, H. C. Highly stable Zr(IV)-based metal-organic frameworks for the detection and removal of antibiotics and organic explosives in water. J. Am. Chem. Soc. 2016, 138, 6204–46216.
(23) Li, H. H.; Han, Y. B.; Shao, Z. C.; Li, N.; Huang, C.; Hou, H. W. Water-stable Eu-MOF fluorescent sensors for trivalent metal ions and nitrobenzene. Dalton Trans. 2017, 46, 12201–12208.
(24) Hu, X. L.; Qin, C.; Wang, X. L.; Shao, K. Z.; Su, M. Z. A luminescent dye@MOF as a dual-emitting platform for sensing explosives. Chem. Commun. 2015, 51, 17521–417524.
(25) He, G.; Peng, H. N.; Liu, T. L.; Yang, M. N.; Zhang, Y.; Fang, Y. A novel picric acid film sensor via combination of the surface enrichment effect of chitosan films and the aggregation-induced emission effect of siloles. J. Mater. Chem. 2009, 19, 7347–7353.
(26) Rao, P. C.; Mandal, S. Europium-based metal-organic framework as a dual luminescence sensor for the selective detection of the phosphate anion and Fe3+ ion in aqueous media. Inorg. Chem. 2018, 57, 11855–11858.
(27) Wang, Z. J.; Ge, F. Y.; Sun, G. H.; Zheng, H. G. Two MOFs as dual-responsive photoluminescence sensors for metal and inorganic ion detection. Dalton Trans. 2018, 47, 8257–8263.
(28) Samanta, P.; Desai, A. V.; Sharma, S.; Chandra, P.; Ghosh, S. K. Selective recognition of Hg2+ ion in water by a functionalized metal-organic framework (MOF) based chemodosimeter. Inorg. Chem. 2018, 54, 2360–2364.
(29) Wang, B.; Lv, X. L.; Feng, D.; Xie, L. H.; Zhanf, J.; Li, M.; Xie, Y.; Li, J. R.; Zhou, H. C. Highly stable Zr(IV)-based metal-organic frameworks for the detection and removal of antibiotics and organic explosives in water. J. Am. Chem. Soc. 2016, 138, 6204–6216.