Auxiliary Ligands Mediated One- and Two-dimensional Cd(II) Coordination Polymers Incorporating Methyl-3- hydroxy-5-carboxy-2-Thiophenecarboxylate Ligand

摘要
图/表
参考文献
相关文章 (15)

全文: PDF (416 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要

Two N-donor ligands mediated Cd(II) coordination polymers, namely, [Cd(L)(dmpz)2]n (1) and {[Cd(L)(atr)0.5(H2O)](H2O)}n (2) (H2L = methyl-3-hydroxy-5-carboxy- 2-thiophenecarboxylate, dmpz = 3,5-dimethylpyrazole, and atr = 4-amino-1,2,4-triazole), have been produced. Their structures were characterized by single-crystal X-ray diffraction analysis, elemental analyses and infrared spectra. Compound 1 possesses a one-dimensional (1D) chain structure and is finally extended into a three-dimensional (3D) supramolecular architecture though hydrogen bonding interactions. Compound 2 features a two-dimensional (2D) network with 4-connected sql topology based on dinuclear Cd(II) clusters as nodes, which is also assembled into a 3D supramolecular architecture through hydrogen bonding interactions. Furthermore, compounds 1 and 2 exhibit high thermal stabilities and intense fluorescent emission in the solid, and can be explored as potential luminescent materials.

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	李召好
	李振元
	陈云
	路远远
	赵邦屯

关键词 ： coordination polymer, methyl-3-hydroxy-5-carboxy-2-thiophenecarboxylate, 3,5-dimethylpyrazole, 4-amino-1,2,4-triazole, photoluminescent properties

Abstract：

Key words： coordination polymer methyl-3-hydroxy-5-carboxy-2-thiophenecarboxylate 3,5-dimethylpyrazole 4-amino-1,2,4-triazole photoluminescent properties

收稿日期: 2017-09-05 出版日期: 2018-04-10

基金资助:

This work was supported by the National Natural Science of Foundation of China (No. 21671094)

通讯作者: lylizh@126.com E-mail: lylizh@126.com

引用本文:

李召好;李振元;陈云;路远远;赵邦屯. Auxiliary Ligands Mediated One- and Two-dimensional Cd(II) Coordination Polymers Incorporating Methyl-3- hydroxy-5-carboxy-2-Thiophenecarboxylate Ligand[J]. 结构化学, 2018, 37(4): 617-623.
LI Zhao-Hao; LI Zhen-Yuan;CHEN Yun;LU Yuan-Yuan;ZHAO Bang-Tun . Auxiliary Ligands Mediated One- and Two-dimensional Cd(II) Coordination Polymers Incorporating Methyl-3- hydroxy-5-carboxy-2-Thiophenecarboxylate Ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37(4): 617-623.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2018/V37/I4/617

REFERENCES
(1) Huang, Y.; Liang, J.; Wang, X.; Cao, R. Multifunctional metal-organic framework catalysts: synergistic catalysis and tandem reactions. Chem. Soc. Rev. 2017, 46, 126–157.
(2) Zhao, D.; Timmons, D. J.; Yuan, D. Q.; Zhou, H. C. Tuning the topology and functionality of metal-organic frameworks by ligand design. Acc. Chem. Res. 2011, 44, 123–133.
(3) Wu, Z.; Tan, B.; Xie, Z.; Fu, J.; Huang, X. A photochromic dual-functional Mg-CP exhibits white-emission after modification with CuI. J. Mater. Chem. C 2016, 4, 2438–2441.
(4) Li, Y.; Lun, H.; Xiao, C.; Xu, Y.; Wu, L.; Yang, J.; Niu, J.; Xiang, S. A bilayer triangular lattice with crown-like Co7 spin cluster SBUs exhibiting high spin frustration. Chem. Commun. 2014, 50, 8558–8560.
(5) Xue, L.; Li, Z.; Li, S.; Wang, J. Synthesis, crystal structure and fluorescent property of a new one-dimensional cadmium(II) coordination polymer based on 3,4-thiophenedicarboxylic acid and 1,10-phenanthroline. Chin. J. Struct. Chem. 2013. 5, 704–708.
(6) Go, Y. B.; Wang, X.; Anokhina, E. V.; Jacobson A. J. Influence of the reaction temperature and pH on the coordination modes of the 1,4-benzenedicarboxylate (BDC) ligand: a case study of the NiII(BDC)/2,2΄-bipyridine system. Inorg. Chem. 2005, 44, 8265–8271.
(7) Noro, S.; Kitagawa, S.; Kondo, M.; Seki, K. A new, methane adsorbent, porous coordination polymer [{CuSiF6(4,4΄-bipyridine)2}n]. Angew. Chem. Int. Ed. 2000, 39, 2081–2084.
(8) Gole, B.; Bar, A. K.; Mukherjee, P. S. Modification of extended open frameworks with fluorescent tags for sensing explosives: competition between size selectivity and electron deficiency. Chem. Eur. J. 2014, 20, 2276–2291.
(9) Yang, Q.; Zhao, Q.; Tang, K.; Zhang, X.; Li, Y.; Chen, Z. A thermally stable and homochiral jsm-type metal-organic framework: syntheses, structure and properties. Polyhedron 2015, 90, 23–27.
(10) Jin, S.; Lin, Z.; Zhou, Y.; Wang, D.; Chen, G.; Ji, Z.; Huang, T. Syntheses, characterization and crystal structures of eight Cd (II) carboxylates containing 3,5-dimethylpyrazole. Polyhedron 2014, 74, 79–92.
(11) Appavoo, D.; Omondi, B.; Guzei, I. A.; Van Wyk, J. L.; Zinyemba, O.; Darkwa, J. Bis(3,5-dimethylpyrazole) copper(II) and zinc(II) complexes as efficient initiators for the ring opening polymerization of ε-caprolactone and D, L-lactide. Polyhedron 2014, 69, 55–60.
(12) Liu, K.; Shi, W.; Cheng, P. The coordination chemistry of Zn(II), Cd(II) and Hg(II) complexes with 1,2,4-triazole derivatives. Dalton Trans. 2011, 40, 8475–8490.
(13) Wang, S.; Yang, L.; Feng, J.; Wu, B.; Zhang, J.; Zhang, T.; Zhou, Z. Synthesis, crystal structure, thermal decomposition, and sensitive properties of two novel energetic cadmium(II) complexes based on 4-amino-1,2,4-triazole. Z. Anorg. Allg. Chem. 2011, 637, 2215–2222.
(14) Wu, X.; Kuang, X.; Zhao, Z.; Chen, S.; Xie, Y.; Yu, R.; Lu, C.A series of POM-based hybrid materials with different copper/aminotriazole motifs. Inorg. Chim. Acta 2010, 363, 1236–1242.
(15) Zheng, X.; Li, W.; Du, J.; Lu, X.; Liu, M.; Yu, Y.; Tian, L. Diverse structural assemblies of silver-thiophene-2,5-dicarboxylate coordination complexes contribute to different proton-conducting performances. CrystEngComm. 2016, 18, 7814–7822.
(16) Xue, L.; Li, Z.; Ma, L.; Wang, L. Crystal engineering of cadmium coordination polymers decorated with nitro-functionalized thiophene-2,5-dicarboxylate and structurally related bis(imidazole) ligands with varying flexibility. CrystEngComm. 2015, 17, 6441–6449.
(17) Xue, L. A dinuclear Cd(II) cluster-based coordination polymer: synthesis, structure and luminescence property. Chin. J. Struct. Chem. DOI:10.14102/j.cnki.0254-5861.2011-1666.
(18) Li, Z.; He, S.; Xue, L.; Wang, X.; Zhang, D.; Zhao B. Exploring methyl-3-hydroxy-5-carboxy-2-thiophenecarboxylate and varying flexible bis(imidazole)-based synthons as building blocks for the construction of diverse cadmium coordination polymers. Dyes and Pigments 2018, 149, 498–504.
(19) Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Cryst. 2009, 42, 339–341.
(20) Sheldrick, G. M. SHELXT-Integrated space-group and crystal-structure determination. Acta Cryst. 2015, A71, 3–8.
(21) Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Cryst. 2015, C71, 3–8.
(22) Zhai, Q.; Wu, X.; Chen, S.; Lu, C.; Yang, W. Construction of Cd/Zn(II)-1,2,4-triazolate coordination complexes via changing substituents and anions. Cryst. Growth Des. 2006, 6, 2126–2135.
(23) Li, J.; Zhou, J.; Li, Y.; Weng, L.; Chen, X.; Yu, Z.; Xue, Z. Synthesis and structures of two luminescent Zn(II) complexes with pyrazole and carboxylate ligands. Inorg. Chem. Commun. 2004, 7, 538–541.
(24) Chang, X.; Zhao, Y.; Han, M.; Ma, L.; Wang, L. Five Cd(II) coordination polymers based on 2,3′,5,5′-biphenyltetracarboxylic acid and N-donor coligands: syntheses, structures and fluorescent properties. CrystEngComm. 2014, 16, 6417–6424.