Two NiII/CuII Coordination Polymers Based on Pyridyl-carboxylate Ligand: Synthesis, Crystal Structures and Magnetic Properties

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摘要

Under hydrothermal conditions, the reactions of NiII/CuII ions with 3-(6-aminpyri- dinium-3-yl) benzoate (HL) afford two compounds [NiL2]n (1) and [CuL2(H2O)]n (2). On the basis of X-ray diffraction analysis of the two compounds, the results show that compound 1 features one-dimensional (1D) double-strand coordination arrays, while 2 presents the 63-hcb layers. Both compounds are further constructed into a 3D supramolecular structure with the aid of weak secondary interactions. Thermal stabilities and magnetic properties of compounds 1 and 2 were also investigated.

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	叶骁
	董文文
	方义铭
	赵君
	李东升

关键词 ： coordination polymers, crystal structure, NiII/CuII compounds, magnetic property

Abstract：

Key words： coordination polymers crystal structure NiII/CuII compounds magnetic property

收稿日期: 2017-07-11 出版日期: 2018-02-07

基金资助:

This project was supported by the National Natural Science Foundation of China (Nos. 21671119, 21301106 and 21673127)

通讯作者: dongww1@126.com E-mail: dongww1@126.com

引用本文:

叶骁;董文文;方义铭;赵君;李东升. Two NiII/CuII Coordination Polymers Based on Pyridyl-carboxylate Ligand: Synthesis, Crystal Structures and Magnetic Properties[J]. 结构化学, 2018, 37(2): 322-328.
YE Xiao;DNOG Wen-Wen; FANG Yi-Ming;ZHAO Jun;LI Dong-Sheng. Two NiII/CuII Coordination Polymers Based on Pyridyl-carboxylate Ligand: Synthesis, Crystal Structures and Magnetic Properties. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37(2): 322-328.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2018/V37/I2/322

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