Synthesis, Crystal Structure and Properties of A Triphenyltin Schiff Complex with Salicylidene-2-aminophenol
张复兴;吴倩;邝代治;庾江喜;蒋伍玖;朱小明
(Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Metal-organic Compounds of Hunan Province;Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang, Hunan 421008, China)
Synthesis, Crystal Structure and Properties of A Triphenyltin Schiff Complex with Salicylidene-2-aminophenol
(Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Metal-organic Compounds of Hunan Province;Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang, Hunan 421008, China)
The triphenyltin complex with salicylidene-2-aminophenol (C31H24NO2Sn, 1) has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic system, P21/c space group with a = 1.09515(8), b = 1.17739(8), c = 2.29075(14) nm, β = 117.070(4)°, V = 2.6302(3) nm3, Z = 4, Dc = 1.417 g/cm3, = 0.999 mm–1, F(000) = 1123, R = 0.0472 and wR = 0.1169. X-ray single-crystal diffraction showed that 1 demonstrates a one-dimensional chain structure. The quantum chemical calculation of 1 has been investigated. Complex 1 emits fluo- rescence at 558 nm and exhibits certain inhibitory activity against NCI-H460, A549 and MCF-7.
Abstract：The triphenyltin complex with salicylidene-2-aminophenol (C31H24NO2Sn, 1) has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic system, P21/c space group with a = 1.09515(8), b = 1.17739(8), c = 2.29075(14) nm, β = 117.070(4)°, V = 2.6302(3) nm3, Z = 4, Dc = 1.417 g/cm3, = 0.999 mm–1, F(000) = 1123, R = 0.0472 and wR = 0.1169. X-ray single-crystal diffraction showed that 1 demonstrates a one-dimensional chain structure. The quantum chemical calculation of 1 has been investigated. Complex 1 emits fluo- rescence at 558 nm and exhibits certain inhibitory activity against NCI-H460, A549 and MCF-7.
基金资助:Supported by the Open Fund Project of Key Laboratory of Functional Organometallic Materials of Hengyang Normal University (15K017, 14K014, 13K105), Natural Science Foundation of Hunan Province (No. 13JJ3112), Scientific & Technological Projects of Hunan Province (No. 2014NK3086), Aid programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province, the Key Discipline of Hunan Province and Project funding for research and innovation experiment of university students in Hunan Province
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引用本文:
张复兴;吴倩;邝代治;庾江喜;蒋伍玖;朱小明. Synthesis, Crystal Structure and Properties of A Triphenyltin Schiff Complex with Salicylidene-2-aminophenol[J]. 结构化学, 2018, 37(2): 270-276.
ZHANG Fu-Xing;WU Qian;KUANG Dai-Zhi;YU Jiang-Xi;JIANG Wu-Jiu;ZHU Xiao-Ming . Synthesis, Crystal Structure and Properties of A Triphenyltin Schiff Complex with Salicylidene-2-aminophenol. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37(2): 270-276.
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