Tuning the Photoluminescence of Zn(Ⅱ) Coordination Polymers by Changing the Coordinated Solvent
赵帅;郝学敏;刘家麟;王浩;伍一波;郭文莉
a (Beijing Key Lab of Special Elastomer Composite Materials, College of Materials Science and Engineering, Beijing Institute of Petrochemical Technology,Beijing 102617, China)
b (College of Materials Science and Engineering,Beijing University of Chemical Technology, Beijing 100029, China)
Tuning the Photoluminescence of Zn(Ⅱ) Coordination Polymers by Changing the Coordinated Solvent
a (Beijing Key Lab of Special Elastomer Composite Materials, College of Materials Science and Engineering, Beijing Institute of Petrochemical Technology,Beijing 102617, China)
b (College of Materials Science and Engineering,Beijing University of Chemical Technology, Beijing 100029, China)
By using solvothermal method, two new Zn(Ⅱ) coordination polymers based on 2,5- furandicarboxylic acid (H2FDA) ligand, [Zn(FDA)(CH3OH)]n (1) and [Zn2(FDA)2(CH3CH2OH)2]n (2), were synthesized and structurally characterized by single-crystal X-ray diffraction as well as elemental analysis and IR. Complexes 1 and 2 are isostructural coordination polymers with two-dimensional sheet structures bridged by the protonated carboxylates ligands. The 2D network can be rationalized as a 3-c net with Schläfli symbol is 82•10. Although 1 and 2 are isostructural, the photoluminescent intensity of 2 is almost twice that of 1 due to the difference of coordinated solvents.
By using solvothermal method, two new Zn(Ⅱ) coordination polymers based on 2,5- furandicarboxylic acid (H2FDA) ligand, [Zn(FDA)(CH3OH)]n (1) and [Zn2(FDA)2(CH3CH2OH)2]n (2), were synthesized and structurally characterized by single-crystal X-ray diffraction as well as elemental analysis and IR. Complexes 1 and 2 are isostructural coordination polymers with two-dimensional sheet structures bridged by the protonated carboxylates ligands. The 2D network can be rationalized as a 3-c net with Schläfli symbol is 82•10. Although 1 and 2 are isostructural, the photoluminescent intensity of 2 is almost twice that of 1 due to the difference of coordinated solvents.
This project was supported by the Training Program Foundation for Excellent Talents by Beijing Municipal Committee of CPC Organization Department (2015000020124G063)
通讯作者:
wangh@bipt.edu.cn
E-mail: wangh@bipt.edu.cn
引用本文:
赵帅;郝学敏;刘家麟;王浩;伍一波;郭文莉. Tuning the Photoluminescence of Zn(Ⅱ) Coordination Polymers by Changing the Coordinated Solvent[J]. 结构化学, 2018, 37(1): 145-151.
ZHAO Shuai;HAO Xue-Min;LIU Jia-Lin;WANG Hao;WU Yi-Bo;GUO Wen-Li. Tuning the Photoluminescence of Zn(Ⅱ) Coordination Polymers by Changing the Coordinated Solvent. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37(1): 145-151.
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2018, Vol. 37 
