Synthesis, Structure and Characterization of a 3D Chiral Indium Carboxylate Metal-organic Framework Based on 1,1΄-Biphenol Ligand

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摘要

A novel indium-based chiral metal organic-framework 1 {In2L(μ2-O)(H2O)3}n was synthesized from C2-symmetric 1,1΄-biphenol-based ligand H4L and structurally characterized by single-crystal and powder X-ray diffraction, Fourier-transform infrared spectra (FTIR), solid-state circular dichroism (CD) and thermal gravimetric analysis (TGA). 1 crystallizes in monoclinic space group P21 with a = 10.1861(5), b = 18.5632(9), c = 16.5153(8) Å, V = 3077.1(3) Å3, Z = 2, Mr = 944.29 g/mol, Dc = 1.019 g/cm3, F(000) = 944, GOOF = 0.932, the final R = 0.0577 and wR = 0.1091 for 22090 observed reflections with I > 2σ(I). Each In2 cluster in 1 is linked by four ligands and each ligand is coordinated to four In2 clusters to generate a 3D network. Additionally, the photoluminescence of 1 and H4L were also investigated.

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	孟春龙
	李子建
	刘燕
	刘百战
	崔勇

关键词 ： 1,1?-biphenol, indium, chiral metal-organic framework, 1,1?-biphenol')" href="#">photoluminescence

1,1?-biphenol, indium, chiral metal-organic framework,

1,1?-biphenol')" href="#">photoluminescence

1,1?-biphenol, indium, chiral metal-organic framework,

')" href="#">photoluminescence

Abstract：

Key words： 1,1?-biphenol indium chiral metal-organic framework photoluminescence

收稿日期: 2017-03-09 出版日期: 2017-12-12

基金资助:

Supported by the NNSFC (No. 21371119, 21431004, 21401128, 21522104, and 21620102001), the National Key Basic Research Program
of China (Nos. 2014CB932102 and 2016YFA0203400), and the Shanghai “Eastern Scholar” Program SSTC-14YF1401300

通讯作者: yongcui@sjtu.edu.cn E-mail: yongcui@sjtu.edu.cn

引用本文:

孟春龙;李子建;刘燕;刘百战;崔勇. Synthesis, Structure and Characterization of a 3D Chiral Indium Carboxylate Metal-organic Framework Based on 1,1΄-Biphenol Ligand[J]. 结构化学, 2017, 36(12): 2081-2086.
MENG Chun-Long;LI Zi-Jian;LIU Yan;LIU Bai-Zhan;CUI Yong. Synthesis, Structure and Characterization of a 3D Chiral Indium Carboxylate Metal-organic Framework Based on 1,1΄-Biphenol Ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(12): 2081-2086.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2017/V36/I12/2081

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