a (State Key Laboratory of Metal Matrix Composites, School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China)
b (China Tobacco, Shanghai 200240, China)
Synthesis, Structure and Characterization of a 3D Chiral Barium Carboxylate Metal-organic Framework Based on TADDOL Ligand
a (State Key Laboratory of Metal Matrix Composites, School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China)
b (China Tobacco, Shanghai 200240, China)
A novel alkaline earth-based chiral metal-organic framework 1 {[Ba1.5L(μ- OH2)2(DMF)2(H2O)]•DMF•1.5H2O}n was synthesized from C2-symmetric TADDOL-based ligand H4L and structurally characterized by single-crystal and powder X-ray diffraction, Fourier-transform infrared spectra (FTIR), solid-state circular dichroism (CD) and thermal gravimetric analysis (TGA). 1 crystallizes in monoclinic space group C2 with a = 43.5105(12), b = 9.4781(3), c = 15.5620(4) Å, β = 99.7770(10)º, V = 6324.5(3) Å3, Z = 2, Mr = 1434.18 g/mol, Dc = 1.506 g/cm3, F(000) = 2904, GOOF = 1.026, the final R = 0.0358 and wR = 0.0952 for 21747 observed reflections with I > 2σ(I). Each Ba3 cluster in 1 is linked by eight ligands and each ligand with one coordination-free carboxyl oxygen, O(5), is coordinated to four Ba3 clusters to generate a 3D network. In addition, the photoluminescence of 1 and H4L was also investigated.
This work was supported by NSFC-21371119, 21431004, 21401128, 21522104,and 21620102001), “973” Program (Grants 2014CB932102 and 2016YFA0203400),and the Shanghai “Eastern Scholar” Program SSTC-14YF1401300
邵枫;ANEES ABBAS;李子建;刘燕;刘百战;崔勇. 一个基于TADDOL配体的三维手性钡金属羧酸框架的合成、结构与表征[J]. 结构化学, 2017, 36(11): 1871-1877.
SHAO Feng;ANEES Abbas;LI Zi-Jian;LIU Yan;LIU Bai-Zhan;CUI Yong. Synthesis, Structure and Characterization of a 3D Chiral Barium Carboxylate Metal-organic Framework Based on TADDOL Ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(11): 1871-1877.
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2017, Vol. 36 
