Two new coordination polymers {[Zn(Hbtc)(bpyb)]•H2O}n (1) and {[Cd(Hbtc)- (bpyb)1.5]•0.5bpyb}n (2) (H3btc = 1,3,5-benzenetricarboxylic acid, bpyb = 1,4-bis(4-pyri- dyl)benzene) have been synthesized under hydrothermal conditions. The two compounds were characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. Compound 1 displays a 2-fold interpenetrating 3D supramolecular architecture through O–H•••N/O hydrogen bonds and π-π stacking interactions. Compound 2 exhibits a 2D→3D polycatenated structure, which is further stabilized by O–H•••N hydrogen bonds. The results indicate that the metal ion has significant effects on the formation and structure of the resulted coordination polymers. Furthermore, thermal stability and photoluminescent properties of 1 and 2 are also discussed in detail.
This project was supported by the National Natural Science Foundation of China (No. 21373178)
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引用本文:
王记江;曹壮;唐龙;王潇;侯向阳;鞠萍;张恩生. 金属离子调控的两个Zn (II)/Cd (II)均苯三酸配位聚合物[J]. 结构化学, 2017, 36(10): 1617-1623.
WANG Ji-Jiang;CAO Zhuang;TANG Long;WANG Xiao;HOU Xiang-Yang;JU Ping;ZHANG En-Sheng . Two Metal Ion-controlled Zn(II)/Cd(II) Coordination Polymers Based on 1,3,5-Benzenetricarboxylic Acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(10): 1617-1623.
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