Abstract:A novel complex, [Zn(L)]2•H2O (1, H2L = 4-aminophthalic acid), has been hydro- thermally prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and PXRD. Complex 1 crystallizes in monoclinic, space group C2/c with a = 12.4267(6), b = 7.7482(3), c = 18.6983(8) Å, β = 110.437(3)º, V = 1687.04(13) Å3, Z = 4, C16H12N2O9Zn2, Mr = 507.06, Dc = 1.996 g/cm3, μ = 2.903 mm-1, S = 0.989, F(000) = 1016, the final R = 0.0304 and wR = 0.0720 for 12618 observed reflections (I > 2σ(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional (3D) framework with 4-connected umc topology. Moreover, the thermogravimetric (TG) analysis and photoluminescent property of 1 were also discussed.
This work was supported by the National Natural Science Foundation of China (Nos. 21171040 and 21302019), excellent organic teaching and research project (No. 2013JCJS01) and National Undergraduates Innovation Project (201510371010)
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引用本文:
张自由;肖丽;陈水生;乔瑞;杨松. 一个新颖4-结点umc拓扑Zn(II)配合物的合成、结构和荧光性能研究[J]. 结构化学, 2017, 36(5): 819-824.
ZHANG Zi-You;XIAO Li;CHEN Shui-Sheng;QIAO Rui;YANG Song. A Novel Zn(II) Complex with 4-Connected umc Topology: Synthesis, Crystal Structure and Luminescent Property. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(5): 819-824.
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