Syntheses, Structures and Luminescent Properties of the Cadmium(II) Complex with 3,3΄-Thiodipropionic Acid
谷长生;郝晓敏;张竹艳;纪丽丽;李泳;宋文东
a (Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China)
b (College of Pharmacy, Harbin Medical University, Harbin 150081, China)
c (Innovation & Application Institute, Zhejiang Ocean University, Zhoushan, Zhejiang 316022, China)
a (Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China)
b (College of Pharmacy, Harbin Medical University, Harbin 150081, China)
c (Innovation & Application Institute, Zhejiang Ocean University, Zhoushan, Zhejiang 316022, China)
One new luminescent material of complex {[Cd(DPA)(H2O)2]•(H2O)2}n (1) was synthesized by evaporation methods using 3,3΄-thiodipropionic acid (DPA) and cadmium nitrate as the starting materials. Compound 1 crystallizes in the monoclinic system, space group P21/n with a = 7.5460(7), b = 13.372(3), c = 12.304(3) Å, β = 95.95(3)º, V = 1234.8(4) Å3, Dc = 1.940 g/cm3, C6H16O8SCd, Mr = 360.65, F(000) = 720, μ(MoK) = 1.960 mm-1, Z = 4, R = 0.0460 and wR = 0.1185 for 1835 observed reflections (I > 2σ(I)), and R = 0.0591, wR = 0.1245 for all data. The complex has been characterized by elemental analysis, FT-IR, TG, PXRD and X-ray single-crystal structure analysis and the fluorescence property has also been studied. As a result, complex 1 possesses a two-dimensional (2-D) structure through DPA ligands interconnecting Cd2+ ions. Complex 1 emits the intense fluorescence of 420 nm in the solid state at room temperature.
Abstract：One new luminescent material of complex {[Cd(DPA)(H2O)2]•(H2O)2}n (1) was synthesized by evaporation methods using 3,3΄-thiodipropionic acid (DPA) and cadmium nitrate as the starting materials. Compound 1 crystallizes in the monoclinic system, space group P21/n with a = 7.5460(7), b = 13.372(3), c = 12.304(3) Å, β = 95.95(3)º, V = 1234.8(4) Å3, Dc = 1.940 g/cm3, C6H16O8SCd, Mr = 360.65, F(000) = 720, μ(MoK) = 1.960 mm-1, Z = 4, R = 0.0460 and wR = 0.1185 for 1835 observed reflections (I > 2σ(I)), and R = 0.0591, wR = 0.1245 for all data. The complex has been characterized by elemental analysis, FT-IR, TG, PXRD and X-ray single-crystal structure analysis and the fluorescence property has also been studied. As a result, complex 1 possesses a two-dimensional (2-D) structure through DPA ligands interconnecting Cd2+ ions. Complex 1 emits the intense fluorescence of 420 nm in the solid state at room temperature.
基金资助:This work was supported by the National Natural Science Foundation of China (No. 51302067) and the Team of Guangdong Ocean
University (No. 1312435)
通讯作者:
gcsheng1968@126.com and swd60@163.com
E-mail: gcsheng1968@126.com and swd60@163.com
引用本文:
谷长生;郝晓敏;张竹艳;纪丽丽;李泳;宋文东. Syntheses, Structures and Luminescent Properties of the Cadmium(II) Complex with 3,3΄-Thiodipropionic Acid[J]. 结构化学, 2017, 36(3): 478-484.
GU Chang-Sheng;HAO Xiao-Min;ZHANG Zhu-Yan;JI Li-Li;LI Yong;SONG Wen-Dong. 琥珀酸和3,6-二（4-吡啶）哒嗪配体构筑的三维镉化合物的晶体结构和荧光性能. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(3): 478-484.
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