Cyanide-bridged One-dimensional Heterobimetallic Complex cis-[FeII(phen)2(CN)2MnIII(salen)](PF6):Synthesis, Crystal Structure and Magnetic Properties

摘要
图/表
参考文献
相关文章 (15)

全文: PDF (646 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要

Dicyanide building block cis-Fe(phen)2(CN)2 and [MnIII(salen)](ClO4) have been used to design and synthesize a cyanide-bridged complex, resulting in a heterobimetallic one-dimensional (1D) zigzag chain complex 1, [cis-Fe(phen)2(CN)2Mn(salen)](PF6) (phen = 1,10-phenanthroline, salen = N,N΄-ethylenebis-(salicylideneaminato) dianion). Single-crystal X-ray diffraction analysis shows complex 1 crystallizes in the monoclinic P21/c space group and the asymmetric unit contains one [-NC-Fe(phen)2(-CN)-MnIII-(salen)-]+ cation and one PF6- anion. In the cationic structure of 1, each FeII(phen)2(CN)2 connects two [MnIII(salen)]+ with two cyanide groups in a cis-conformation, and in turn each [MnIII(salen)]+ unit links two FeII(phen)2(CN)2 building blocks in a trans-conformation, resulting in a 1D [-NC-FeII-CN-MnIII-]n chain. Furthermore, the electronic absorption spectra and electrochemical and magnetic properties of complex 1 have also been studied.

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	王勇
	胡建梅
	李立
	李立威

关键词 ： manganese, crystal structure, cyanide-bridged, electrochemistry, UV-vis

Abstract：将二氰基结构单元 cis-Fe(phen)2(CN)2和[MnIII(salen)](ClO4)反应，得到一个氰桥一维（1D）zigzag链异核化合物1，[cis-Fe(phen)2(CN)2Mn(salen)](PF6) （phen = 1,10-邻菲咯啉，salen = N,N’-亚乙基双（亚水杨基）阴离子）。 X-射线衍射分析表明化合物1是单斜晶系P21 /c空间群，每个不对称单元含有一个[-NC-Fe(phen)2(-CN)-MnIII-(salen)-]+ 阳离子和一个PF6-阴离子。化合物1的阳离子结构中每个 FeII(phen)2(CN)2单位通过两个氰基以顺式构象连接两个[MnIII(salen)]+ 结构单位，并且每个[MnIII(salen)]+ 单元以反式构象连接两个FeII(phen)2(CN)2 结构单元，得到一维 [-NC-FeII-CN-MnIII-]n 链。此外，我们还研究了化合物1的电子吸收光谱、电化学和磁性质。

Key words： manganese crystal structure cyanide-bridged electrochemistry UV-vis

收稿日期: 2016-05-26 出版日期: 2017-02-13

基金资助:

Supported by the Project of Hubei Provincial Department of Education (No. Q20144302 and Q20164302), the Natural Science Foundation of Hubei Province (No. 2013CFA015), the Doctoral Scientific Research Foundation of Jingchu University of Technology (No. QDB201603) and the Open Project Program of Hubei Key Laboratory of Drug Synthesis and Optimization, Jingchu University of Technology (No. OPP2016ZD02)

通讯作者: wangyong198711@yahoo.com E-mail: wangyong198711@yahoo.com

引用本文:

王勇;胡建梅;李立;李立威. Cyanide-bridged One-dimensional Heterobimetallic Complex cis-[FeII(phen)2(CN)2MnIII(salen)](PF6):Synthesis, Crystal Structure and Magnetic Properties[J]. 结构化学, 2017, 36(2): 294-302.
WANG Yong;HU Jian-Mei;LI Li;LI Li-Wei . 氰桥一维异核化合物cis-[FeII(phen)2(CN)2MnIII(salen)](PF6)的合成、晶体结构和磁性. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(2): 294-302.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2017/V36/I2/294

REFERENCES
(1)Ahmad, S. The chemistry of cyano complexes of gold(I) with emphasis on the ligand scrambling reactions. Coord. Chem. Rev. 2004, 248, 231243.
(2) Atanasov, M.; Comba, P.; Hausberg, S.; Martin, B. Cyanometalate-bridged oligonuclear transition metal complexes-possibilities for a rational design of SMMs. Coord. Chem. Rev. 2009, 253, 23062314.
(3) Cernak, J.; Orendac, M.; Potocnak, I.; Chomic, J.; Orendacova, A.; Skorsepa, J.; Feher, A. Cyanocomplexes with one-dimensional structures: preparations, crystal structures and magnetic properties. Coord. Chem. Rev. 2002, 224, 5166.
(4) Li, Y. H.; He, W. R.; Ding, X. H.; Wang, S.; Cui, L. F.; Huang, W. Cyanide-bridged assemblies constructed from capped tetracyanometalate building blocks [MA(ligand)(CN)4]1-/2- (MA = Fe or Cr). Coord. Chem. Rev. 2012, 256, 27952815.
(5) Verdaguer, M.; Bleuzen, A.; Marvaud, V.; Vaissermann, J.; Seuleiman, M.; Desplanches, C.; Scuiller, A.; Train, C.; Garde, R.; Gelly, G.; Lomenech, C.; Rosenman, I.; Veillet, P.; Cartier, C.; Villain, F. Molecules to build solids: high TC molecule-based magnets by design and recent revival of cyano complexes chemistry. Coord. Chem. Rev. 1999, 190192, 10231047.
(6) Beltran, L. M. C.; Long, J. R. Directed assembly of metal-cyanide cluster magnets. Acc. Chem. Res. 2005, 38, 325334.
(7) Berlinguette, C. P.; Vaughn, D.; Canada-Vilalta, C.; Galan-Mascaros, J. R.; Dunbar, K. R. A trigonal-bipyramidal cyanide cluster with single-molecule-magnet behavior: synthesis, structure, and magnetic properties of {[MnII(tmphen)2]3[MnIII(CN)6]2}. Angew. Chem. Int. Ed. 2003, 42, 15231526.
(8) Lescouezec, R.; Vaissermann, J.; Ruiz-Perez, C.; Lloret, F.; Carrasco, R.; Julve, M.; Verdaguer, M.; Dromzee, Y.; Gatteschi, D.; Wernsdorfer, W. Cyanide-bridged iron(III)-cobalt(II) double zigzag ferromagnetic chains: two new molecular magnetic nanowires. Angew. Chem. Int. Ed. 2003, 42, 14831486.
(9) Mironov, Y. V.; Virovets, A. V.; Artemkina, S. B.; Fedorov, V. E. An unexpected layered structure in inorganic cyanide clusters: [Cu4(3-OH)4][Re4(3-Te)4(CN)12]. Angew. Chem. Int. Ed. 1998, 37, 25072509.
(10) Ni, Z. H.; Kou, H. Z.; Zhang, L. F.; Ge, C. H.; Cui, A. L.; Wang, R. J.; Li, Y. D.; Sato, O. [MnIII(salen)6][FeIII(bpmb)(CN)67H2O: a cyanide-bridged nanosized molecular wheel. Angew. Chem. Int. Ed. 2005, 44, 77427745.
(11) Lescouezec, R.; Toma, L. M.; Vaissermann, J.; Verdaguer, M.; Delgado, F. S.; Ruiz-Perez, C.; Lloret, F.; Julve, M. Design of single chain magnets through cyanide-bearing six-coordinate complexes. Coord. Chem. Rev. 2005, 249, 26912729.
(12) Wang, S.; Ding, X.; Li, Y.; Huang, W. Dicyanometalate chemistry: a type of versatile building block for the construction of cyanide-bridged molecular architectures. Coord. Chem. Rev. 2012, 256, 439464.
(13) Ohba, M.; Kaneko, W.; Kitagawa, S.; Maeda, T.; Mito, M. Pressure response of three-dimensional cyanide-bridged bimetallic magnets. J. Am. Chem. Soc. 2008, 130, 44754484.
(14) Shatruk, M.; Dragulescu-Andrasi, A.; Chambers, K. E.; Stoian, S. A.; Bominaar, E. L.; Achim, C.; Dunbar, K. R. Properties of Prussian blue materials manifested in molecular complexes: observation of cyanide linkage isomerism and spin-crossover behavior in pentanuclear cyanide clusters. J. Am. Chem. Soc. 2007, 129, 61046116.
(15) Rogez, G.; Marvilliers, A.; Riviere, E.; Audiere, J. P.; Lloret, F.; Varret, F.; Goujon, A.; Mendenez, N.; Girerd, J. J.; Mallah, T. A mixed-valence mixed-spin Prussian-blue-like heptanuclear complex. Angew. Chem. Int. Ed. 2000, 39, 28852887.
(16) Oshio, H.; Yamamoto, M.; Ito, T. Cyanide-bridged molecular squares with ferromagnetically coupled d, d and p spin system. Inorg. Chem. 2002, 41, 58175820.
(17) Parker, R. J.; Spiccia, L.; Moubaraki, B.; Murray, K. S.; Hockless, D. C. R.; Rae, A. D.; Willis, A. C. Structure and magnetism of heptanuclear complexes formed on encapsulation of hexacyanoferrate(II) with the Mn(II) and Ni(II) complexes of 1,4-bis(2-pyridylmethyl)-1,4,7-triazacyclo- nonane. Inorg. Chem. 2002, 41, 24892495.
(18) Bonadio, F.; Senna, M. C.; Ensling, J.; Sieber, A.; Neels, A.; Stoeckl iEvans, H.; Decurtins, S. Cyano-bridged structures based on [MnII(N3O2-Macrocycle)]2+: synthetic, structural, and magnetic Study. Inorg. Chem. 2005, 44, 969978.
(19) Nihei, M.; Ui, M.; Yokota, M.; Han, L.; Maeda, A.; Kishida, H.; Okamoto, H.; Oshio, H. Two-step spin conversion in a cyanide-bridged ferrous square. Angew. Chem. Int. Ed. 2005, 44, 64846487.
(20) Halbauer, K.; Leibeling, G.; Imhof, W. Cyanidverbrückte koordinationspolymere aus cis- oder trans-[Ru(tBuNC)4(CN)2] und MnCl2: zum Einfluß unterschiedlicher topologien auf die magnetischen eigenschaften von materialien. Z. Anorg. Allg. Chem. 2006, 632, 264268.
(21) Halbauer, K.; Spielberg, E. T.; Sterzik, A.; Plass, W.; Imhof, W. Structural and magnetic properties of one-dimensional coordination polymers {trans-[Ru(CN-tBu)4(CN)2]-FeX3}n vs. molecular squares {cis-[Ru(CN-tBu)4(CN)2]-FeX3}2 (X = NO3, Cl). Inorg. Chim. Acta 2010, 363, 10131020.
(22) Zadrozny, J. M.; Freedman, D. E.; Jenkins, D. M.; Harris, T. D.; Iavarone, A. T.; Mathoniere, C.; Clerac, R.; Long, J. R. Slow magnetic relaxation and charge-transfer in cyano-bridged coordination clusters incorporating [Re(CN)7]3-/4-. Inorg. Chem. 2010, 49, 88868896.
(23) Zhang, D.; Zhang, L.; Zhao, Z.; Ni, Z. Cyanide-bridged trinuclear and ethylenediamine-bridged one-dimensional cobalt(III)-manganese(II) complexes: synthesis, crystal structures and magnetic Properties. Bull. Korean Chem. Soc. 2011, 32, 25442548.
(24) Zhang, D. P.; Wang, P. Hydrogen-bond directed 2D cyanide-bridged coordination polymer assembled from a new pentacyanidecobalt(III) building block and a bicompartimental Schiff-base manganese(III) compound: synthesis, structures and magnetic properties. Inorg. Chem. Commun. 2012, 26, 7781.
(25) Xu, Y.; Shen, X.; Zhou, H.; Shu, H.; Li, W.; Yuan, A. Synthesis, crystal structure and magnetic properties of a cyanide-bridged FeIII-MnIII bimetallic chain based on [Fe(bipy)(CN)4]- building block. J. Mol. Struct. 2009, 921, 341345.
(26) Pzychodzen, P.; Lewinski, K.; Balanda, M.; Pelka, R.; Rams, M.; Wasiutynski, T.; Guyard-Duhayon, C.; Sieklucka, B. Crystal structures and magnetic properties of two low-dimensional materials constructed from [MnIII(salen)H2O]+ and [M(CN)8]3-/4- (M = Mo or W) precursors. Inorg. Chem. 2004, 43, 29672974.
(27) Ko, H. H.; Lim, J. H.; Yoo, H. S.; Kang, J. S.; Kim, H. C.; Koh, E. K.; Hong, C. S. Two WV-MnIII bimetallic assemblies built by octacyanotungstate(v) and MnIII Schiff bases: molecular structures and a spin-flop transition. Dalton Trans. 2007, 20702076.
(28) Miyasaka, H.; Takahashi, H.; Madanbashi, T.; Sugiura, K. I.; Clérac, R.; Nojiri, H. Cyano-bridged MnIII3MIII (MIII = Fe, Cr) complexes: synthesis, structure, and magnetic properties. Inorg. Chem. 2005, 44, 59695971.
(29) Ma, X.; Lin, C. S.; Hu, S. M.; Tan, C. H.; Wen, Y. H.; Sheng, T. L.; Wu, X. T. Influence of central metalloligand geometry on electronic communication between metals: syntheses, crystal structures, MMCT properties of isomeric cyanido-bridged Fe2Ru complexes, and TDDFT calculations. Chem.-Eur. J. 2014, 20, 70257036.
(30) Ma, X.; Hu, S. M.; Tan, C. H.; Wen, Y. H.; Zhu, Q. L.; Shen, C. J.; Sheng, T. L.; Wu, X. T. A cyanide-bridged trinuclear Fe(II)-Ru(II)-Fe(II) complex with three stable states: synthesis, crystal structures, electronic couplings and magnetic properties. Dalton Trans. 2012, 41, 1216312169.
(31) Ma, X.; Hu, S. M.; Tan, C. H.; Zhang, Y. F.; Zhang, X. D.; Sheng, T. L.; Wu, X. T. From antiferromagnetic to ferromagnetic interaction in cyanido-bridged Fe(III)–Ru(II)–Fe(III) complexes by change of the central diamagnetic cyanido-metal geometry. Inorg. Chem. 2013, 52, 1134311350.
(32) Wang, Y.; Ma, X.; Hu, S. M.; Wen, Y. H.; Xue, Z. Z.; Zhu, X. Q.; Zhang, X. D.; Sheng, T. L.; Wu, X. T. Syntheses, crystal structures, MMCT and magnetic properties of four one-dimensional cyanide-bridged complexes comprised of MII-CN-FeIII (M = Fe, Ru, Os). Dalton Trans. 2014, 43, 1745317462.
(33) Wang, Y.; Lin, C.; Ma, X.; Xue, Z.; Zhu, X.; Cao, W.; Hu, S.; Sheng, T.; Wu, X. Influence of the central diamagnetic cyanidometal on the distant magnetic interaction in cyanide-bridged Fe(iii)-M(ii)-Fe(iii) complexes. Dalton Trans. 2015, 44, 74377448.
(34) Wang, Y.; Ma, X.; Hu, S. M.; Xue, Z. Z.; Wen, Y. H.; Sheng, T. L.; Wu, X. T. Syntheses, crystal structures, spectroscopy, electrochemical and magnetic properties of four cyanido-bridged MII–MnIII (M = Fe, Ru, Os) complexes. J. Coord. Chem. 2015, 68, 5570.
(35) Wang, Y.; Ma, X.; Hu, S. M.; Wang, Y. L.; Tan, C. H.; Wen, Y. H.; Zhang, X. D.; Sheng, T. L.; Wu, X. T. Syntheses, crystal structures and magnetic properties of two cyanide-bridged molecular squares MII2–CoII2 (M = Ru, Os) based on the diamagnetic cyanidometal M(dppm)2(CN)2. Polyhedron 2014, 83, 137142.
(36) Wang, Y.; Song, J. S.; Ma, X.; Xue, Z. Z.; Hu, S. M.; Fu, R. B.; Li, C. S.; Sheng, T. L.; Wu, X. T. Synthesis, crystal structure and MMCT of new cyanide-bridged complexes cis-MII(dppm)2(CN)2(FeIIIX3)2 (M = Ru, Os). RSC Adv. 2015, 5, 33993407.
(37) Schilt, A. A. Mixed ligand complexes of iron(II) and (III) with cyanide and aromatic di-imines. J. Am. Chem. Soc. 1960, 82, 30003005.
(38) Schilt, A. A.; Russo, P. A.; Wold, A. Dicyanobis(1,10-phenanthroline) iron(II) and dicyanobis (2,2′-bipyridine) iron(II). Inorg. Synth. 1970, 247251.
(39) Ni, Z. H.; Zheng, L.; Zhang, L. F.; Cui, A. L.; Ni, W. W.; Zhao, C. C.; Kou, H. Z. Cyanido-bridged dimetallic complexes derived from manganese(III) Schiff bases and pentacyanidonitrosylchromate(I): synthesis, crystal structure and magnetic properties. Eur. J. Inorg. Chem. 2007, 12401250.
(40) Shyu, H.; Wei, H.; Wang, Y. Structure and magnetic properties of dinuclear [MnIII(salen)(H2O)]2(ClO4)2 and polynuclear [MnIII(salen)(NO3)]n. Inorg. Chim. Acta 1999, 290, 813.
(41) Li, H.; Zhong, Z. J.; Duan, C.; You, X.; Mak, T. C. W.; Wu, B. Synthesis and crystal structure of a manganese(III) complex with the tetradentate schiff base N,N'-ethylenebis(salicylideneiminato). J. Coord. Chem. 1997, 41, 183189.
(42) Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. Sect. A 2008, 64, 112122.
(43) Sheldrick, G. M. SHELXS-2013, Program for X-ray Crystal Structure Refinement. University of Göttingen, Germany 2013.
(44) Shriver, D. F.; Posner, J. Bridge addition compounds. III. The Influence of boron-containing Lewis acids on electronic spectra, vibrational spectra, and oxidation potentials of some iron-cyanide Complexes. J. Am. Chem. Soc. 1966, 88, 16721677.
(45) Anderson, K. M.; Orpen, A. G. On the relative magnitudes of cis and trans influences in metal complexes. Chem. Commun. 2001, 26822683.
(46) Hunter, C. A.; Sanders, J. K. M. The nature of π-π interactions. J. Am. Chem. Soc. 1990, 112, 55255534.
(47) Główka, M. L.; Martynowski, D.; Kozłowska, K. Stacking of six-membered aromatic rings in crystals. J. Mol. Struct. 1999, 474, 8189.
(48) Hamer, N. K.; Orgel, L. E. Structure and spectra of [(phenanthroline)2Fe(CNMe)2]2+ and [(phenanthroline)2Fe(CN)2H2]2+. Nature 1961, 190, 439440.
(49) Kessissoglou, D. P.; Li, X. H.; Butler, W. M.; Pecoraro, V. L. Mononuclear manganese(IV) complexes of hydroxyl-rich Schiff-base ligands. Inorg. Chem. 1987, 26, 24872492.