Structure and Photophysical Properties of a Chiral 4-Fold Interpenetrated Zn(II) Coordination Polymer Tuned by 4,4΄-(Hexafluoroisopropylidene)bis(benzoic acid) and 1,3-Di(pyridineyl)benzene

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摘要

new three-dimensional (3D) chiral metal-organic coordination polymer, [Zn(dpb)(hfipbb)]n, was obtained under hydrothermal conditions by 1,3-di(pyridineyl)benzene (dpb) and 4,4΄-(Hexafluoroisopropylidene)bis(benzoic acid) (H2hfipbb). The as-prepared sample was characterized by single-crystal X-ray diffraction, PXRD, elemental analysis, IR spectroscopy and TGA analysis. The title coordination polymer crystallizes in orthorhombic, space group P21212, with a = 21.923(4), b = 23.594(4), c = 7.3042(13) Å, V = 3778.1(12) Å3, Dc = 1.209 g/cm3, Mr = 687.90, F(000) = 1328, μ = 0.713 mm-1 and Z = 4. The compound contains two types of helical chains [Zn(hfipbb)]n and [Zn(dpb)]n which are linked with each other to generate a 3D framework by sharing the same Zn(II) cations. It displays a 4-fold interpenetrated 3D framework. In addition, the luminescence, fluorescence lifetime and the second harmonic generation (SHG) efficiency properties in the solid state have been studied.

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	黄新华
	张雷
	周春辉

关键词 ： coordination polymer, helical chains, luminescence

Abstract：

以1,3-二吡啶基苯（dpb）和2,2-双(4-羧基苯基)六氟丙烷（H2hfipbb）和锌(Ⅱ)通过溶剂热反应合成了具有三维骨架的配位聚合物[Zn(dpb)( hfipbb)]n。对其进行了单晶衍射，粉末衍射，元素分析，红外光谱和热重分析等表征。配合物属于正交晶系，空间群为P21212，晶胞参数分别是a = 21.923(4), b = 23.594(4), c = 7.3042(13) Å, V = 3778.1(12) Å3, Dc = 1.209 g/cm3, Mr = 687.90, F(000) = 1328, μ = 0.713 mm-1, Z = 4。此配合物含有两种形式的螺旋链，分别为[Zn(hfipbb)]n和[Zn(dpb)]n，它们通过共用锌(Ⅱ)离子的方法相互连接，最终形成一个具有四重穿插结构三维骨架。此外，还研究了配合物的荧光性质和二次谐波产生效率。

Key words： coordination polymer helical chains luminescence

收稿日期: 2016-05-18 出版日期: 2017-02-13

基金资助:

This work was supported by the National Natural Science Foundation of China (No. 21501002), China Postdoctoral Science
Foundation Funded Project (2016M592031), Open Fund of State Key Laboratory of Coordination Chemistry (SKLCC1604),
and Young and Middle-aged Academic Backbone Training Project of Anhui University of Science and Technology

通讯作者: yutian1224@126.com E-mail: yutian1224@126.com

引用本文:

黄新华;张雷;周春辉. Structure and Photophysical Properties of a Chiral 4-Fold Interpenetrated Zn(II) Coordination Polymer Tuned by 4,4΄-(Hexafluoroisopropylidene)bis(benzoic acid) and 1,3-Di(pyridineyl)benzene[J]. 结构化学, 2017, 36(2): 258-265.
HUANG Xin-Hua;ZHANG Lei;ZHOU Chun-Hui. 2,2-双(4-羧基苯基)六氟丙烷和1,3-二吡啶基苯构筑的具有四重穿插结构的手性锌(Ⅱ)配合物的结构和光物理性能. CHINESE JOURNAL OF STRUCTURNAL CHEMISTRY, 2017, 36(2): 258-265.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2017/V36/I2/258

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