Structural Diversity and Luminescent Properties of Two Zinc(II) Polymers Based on Semirigid N-heterocyclic Ligand
许春莺;唐四叶;刘金强;邓东升;吉保明
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-oriented Porous Materials, Luoyang Normal University, Luoyang 471934, China
Structural Diversity and Luminescent Properties of Two Zinc(II) Polymers Based on Semirigid N-heterocyclic Ligand
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-oriented Porous Materials, Luoyang Normal University, Luoyang 471934, China
By varying the spacer angles of phenylenediacetic acid, two novel Zn(II) coor- dination polymers based on semirigid N-heterocyclic ligand 1,4-bis(2-ethylbenzimidazol- 1-ylmethyl) benzene, [Zn(beb)0.5(m-phda)]n (1) and {[Zn(beb)(p-phda)]•2H2O}n (2), were synthesized and fully structurally characterized. Polymer 1 exhibits a 2D grid-layer with a 44 topology. Polymer 2 shows a 2D layer with rare meso-helix. In addition, the thermal stability and photoluminescence properties of polymers 1 and 2 have also been investigated.
By varying the spacer angles of phenylenediacetic acid, two novel Zn(II) coor- dination polymers based on semirigid N-heterocyclic ligand 1,4-bis(2-ethylbenzimidazol- 1-ylmethyl) benzene, [Zn(beb)0.5(m-phda)]n (1) and {[Zn(beb)(p-phda)]•2H2O}n (2), were synthesized and fully structurally characterized. Polymer 1 exhibits a 2D grid-layer with a 44 topology. Polymer 2 shows a 2D layer with rare meso-helix. In addition, the thermal stability and photoluminescence properties of polymers 1 and 2 have also been investigated.
Financially supported by the National Natural Science Foundation (No. 21372112), and the Science and Technology Research Key Project of the Education Department of Henan Province (2014A150025)
许春莺;唐四叶;刘金强;邓东升;吉保明. Structural Diversity and Luminescent Properties of Two Zinc(II) Polymers Based on Semirigid N-heterocyclic Ligand[J]. 结构化学, 2017, 36(1): 127-134.
XU Chun-Ying;TANG Si-Ye;LIU Jin-Qiang;DENG Dong-Sheng;JI Bao-Ming. Structural Diversity and Luminescent Properties of Two Zinc(II) Polymers Based on Semirigid N-heterocyclic Ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(1): 127-134.
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2017, Vol. 36 
