Spacer Length Effects on the Structure of Cd(II) Coordination Polymers with Flexible Bis(thiabendazolyl) Alkane and 1,2,4,5-Benzenetetracarboxylte Ligands
瞿云华;董桂英;郝少云;桓殿恒
a (School of Metallurgy, Northeastern University, Liaoning, Shenyang 110004, China)
b (College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University
of Science and Technology, Tangshan, Hebei 063009, China)
Spacer Length Effects on the Structure of Cd(II) Coordination Polymers with Flexible Bis(thiabendazolyl) Alkane and 1,2,4,5-Benzenetetracarboxylte Ligands
a (School of Metallurgy, Northeastern University, Liaoning, Shenyang 110004, China)
b (College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University
of Science and Technology, Tangshan, Hebei 063009, China)
The hydrothermal reactions of Cd(OAc)2•2H2O with 1,2,4,5-benzenetetracarboxylic acid (H4bta) and 1,4-bis(thiabendazolyl)butane (L1) or 1,6-bis(thiabendazolyl)hexane (L2) afforded two coordination polymers [Cd2(L1)(bta)•2H2O]n (1) and [Cd2(L2)2(H2bta)2]n (2). Complex 1 holds a rare 3D binodal (4,6)-connected framework with fsh topology. Complex 2 features an infinite meandering chain structure, which is further extended via O–H•••O hydrogen bonding into a 3D supramolecular network. The thermal and fluorescence proprieties of the two complexes were investigated.
The hydrothermal reactions of Cd(OAc)2•2H2O with 1,2,4,5-benzenetetracarboxylic acid (H4bta) and 1,4-bis(thiabendazolyl)butane (L1) or 1,6-bis(thiabendazolyl)hexane (L2) afforded two coordination polymers [Cd2(L1)(bta)•2H2O]n (1) and [Cd2(L2)2(H2bta)2]n (2). Complex 1 holds a rare 3D binodal (4,6)-connected framework with fsh topology. Complex 2 features an infinite meandering chain structure, which is further extended via O–H•••O hydrogen bonding into a 3D supramolecular network. The thermal and fluorescence proprieties of the two complexes were investigated.
Project supported by the Natural Science Foundation-steel and Iron Foundation of Hebei Province (B2015209299 and E2016209304)
通讯作者:
yunhuaqu@163.com
E-mail: yunhuaqu@163.com
引用本文:
瞿云华;董桂英;郝少云;桓殿恒. Spacer Length Effects on the Structure of Cd(II) Coordination Polymers with Flexible Bis(thiabendazolyl) Alkane and 1,2,4,5-Benzenetetracarboxylte Ligands[J]. 结构化学, 2017, 36(1): 153-162.
QU Yun-Hua;DONG Gui-Ying;HAO Shao-Yun;HUAN Dian-Heng. Spacer Length Effects on the Structure of Cd(II) Coordination Polymers with Flexible Bis(thiabendazolyl) Alkane and 1,2,4,5-Benzenetetracarboxylte Ligands. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(1): 153-162.
REFERENCES
(1) Zhang, T.; Lin, W. Metal-organic frameworks for artificial photosynthesis and photocatalysis. Chem. Soc. Rev. 2014, 16, 59825993.
(2) Zhang, W.; Hu, Y.; Ge, J.; Jiang, H. L.; Yu, S. H. A facile and general coating approach to moisture/water-resistant metal-organic frameworks with intact porosity. J. Am. Chem. Soc. 2014, 49, 1697816981.
(3) Schneemann, A.; Bon, V.; Schwedler, I.; Senkovska, I.; Kaskel, S.; Fischer, R. A. Flexible metal-organic frameworks. Chem. Soc. Rev. 2014, 16, 60626096.
(4) Li, J. R.; Timmons, D. J.; Zhou, H. C. Interconversion between molecular polyhedra and metal-organic frameworks. J. Am. Chem. Soc. 2009, 18, 63686369.
(5) Bisht, K. K.; Rachuri, Y.; Parmar, B.; Suresh, E. Structural and functional studies on ternary coordination polymers from 5-bromoisophthalate and imidazole based flexible linker. RSC Adv. 2014, 14, 73527360.
(6) Hao, J. M.; Zhao, Y. N.; Li, H. H.; Ming, C. L.; Cui, G. H. A series of d10 metal coordination polymers based on a flexible bis(2-methylbenzimidazole) ligand and different carboxylates: synthesis, structures, photoluminescence and catalytic properties. CrystEngComm. 2015, 11, 22792293.
(7) Wang, X. X.; Liu, Y. G.; Ge, M.; Cui, G. H. Syntheses, crystal structures and fluorescence properties of two metal-organic coordination polymers derived from rigid bis(1,2,4-triazolyl) and aromatic carboxylic acid ligands. Chin. J. Inorg. Chem. 2015, 10, 20652072.
(8) Liu, L.; Ding, J.; Li, M.; Lv, X.; Wu, J.; Hou, H.; Fan, Y. Structural variability, topological analysis and photocatalytic properties of neoteric Cd(II) coordination polymers based on semirigid bis(thiazolylbenzimidazole) and different types of carboxylic acid linkers. Dalton Transactions 2014, 33, 1279012799.
(9) Liu, L.; Ding, J.; Huang, C.; Li, M.; Hou, H.; Fan, Y. Polynuclear Cd(II) polymers: crystal structures, topologies, and the photodegradation for organic dye contaminants. Cryst. Growth Des. 2014, 6, 30353043.
(10) Wei, S. Q.; Lin, C. W.; Yin, X. H.; Huang, Y. J.; Luo, P. Q. Hydrothermal synthesis, crystal structure of four novel complexes based on thiabendazole ligand. Bull. Korean Chem. Soc. 2012, 9, 29172924.
(11) Devereux, M.; Shea, D. O.; Kellett, A.; McCann, M.; Walsh, M.; Egan, D.; Deegan, C.; Kędziora, K.; Rosair, G.; Müller-Bunz, H. Synthesis, X-ray crystal structures and biomimetic and anticancer activities of novel copper(II) benzoate complexes incorporating 2-(4΄-thiazolyl) benzimidazole (thiabendazole), 2-(2-pyridyl) benzimidazole and 1,10-phenanthroline as chelating nitrogen donor ligands. J. Inorg. Biochem. 2007, 6, 881892.
(12) Allen, F. H. The Cambridge structural database: a quarter of a million crystal structures and rising. Acta Crystallogr., Sect. B: Struct. Sci. 2002, 3, 380388.
(13) Wang, X. X.; Huang, C. M.; Dong, G. Y.; Cui, G. H. Structural modulation and properties of silver(I) coordination polymers from 2,6-naphthalenedicarboxylic acid and flexible N-donor linkers. Trans. Met. Chem. 2015, 7, 733742.
(14) Liu, X. B.; Yu, Y. M.; Ge, M.; Cui, G. H. A new two-dimensional cobalt(II) coordination polymer based on 1,4-cyclohexanedicarboxylate and flexible bis(thiabendazole) ligands. Chin J. Struct. Chem. 2015, 11, 17491755.
(15) Yang, Y. Q.; Yang, J.; Kan, W. Q.; Yang, Y.; Guo, J.; Ma, J. F. A series of 1D, 2D, and 3D coordination polymers based on flexible 3-carboxy-1-carboxymethyl-2-oxidopyridinium and different N-donor ligands-syntheses, structures, and luminescent properties. Eur. J. Inorg. Chem. 2013, 2, 280292.
(16) Liu, L.; Liu, Y.; Han, G.; Wu, D.; Hou, H.; Fan, Y. A series of 2D coordination complexes constructed from a flexible bis(methylbenzimidazole) ligand and different dicarboxylates. Inorg. Chim. Acta 2013, 2534.
(17) Fabelo, O.; Pasán, J.; Lloret, F.; Julve, M.; Ruiz-Pérez, C. Structural versatility in cobalt(II) complexes with 1,2,4,5-benzenetetracarboxylic acid (H4bta) and 4,4′-bipyridine-N,N′-dioxide (dpo). CrystEngComm. 2007, 9, 815827.
(18) Ruiz Pérez, C.; Lorenzo Luis, P.; Hernández Molina, M.; Laz, M. M.; Delgado, F. S.; Gili, P.; Julve, M. 1,2,4,5-benzenetetracarboxylic acid and 4,4′-bipyridine as ligands in designing low-dimensional coordination polymers. Eur. J. Inorg. Chem. 2004, 19, 38733879.
(19) Díaz Gallifa, P.; Fabelo, O.; Cañadillas Delgado, L.; Pasán, J.; Labrador, A.; Lloret, F.; Julve, M.; Ruiz Pérez, C. Synthesis, crystal structure and magnetic characterization of a series of Cu(II)–Ln(III) heterometallic (Ln = La, Ce, Pr, Nd and Sm) metal-organic compounds with an unusual single crystal to single crystal phase transition. Cryst. Growth Des. 2013, 11, 47354745.
(20) Cui, G. H.; He, C. H.; Jiao, C. H.; Geng, J. C.; Blatov, V. A. Two metal-organic frameworks with unique high-connected binodal network topologies: synthesis, structures, and catalytic properties. CrystEngComm. 2012, 12, 42104216.
(21) Hao, J. M.; Wang, L. N.; Van Hecke, K.; Cui, G. H. An unprecedented binodal (4,10)-connected metal-organic framework based on pentanuclear cobalt(II) clusters. Inorg. Chem. Commun. 2014, 4346.
(22) Song, J. F.; Zhou, R. S.; Xu, X. Y.; Liu, Y. B.; Wang, T. G.; Xu, J. Q. Syntheses, crystal structures and properties of two new coordination complexes containing 1,2,4,5-benzenetetracarboxylate and imidazole: [Ni2(Him)12(bta)8H2O] and [Cd2(Him)4(4-bta)]. J. Mol. Struct. 2008, 1, 3440.
(23) Braverman, M. A.; LaDuca, R. L. Hydrothermal synthesis of divalent metal pyromellitate/dipyridylamine complexes: from an unprecedented supramolecular three-dimensional topology to an anionic coordination polymer framework with large incipient cation-bearing voids. CrystEngComm. 2008, 1, 117124.
(24) Bronisz, R. 1,4-Di(1,2,3-triazol-1-yl)butane as building block for the preparation of the iron(II) spin-crossover 2D coordination polymer. Inorg. Chem. 2005, 13, 44634465.
(25) Sheldrick, G. M. A short history of SHELX. Acta Crystallographica. Section A, Foundations of Crystallography 2008, Pt 1, 112122.
(26) Spek, A. Single-crystal structure validation with the program PLATON. J. Appl. Crystallogr. 2003, 1, 713.
(27) Meng, W.; Xu, Z.; Ding, J.; Wu, D.; Han, X.; Hou, H.; Fan, Y. A systematic research on the synthesis, structures, and application in photocatalysis of cluster-based coordination complexes. Cryst. Growth Des. 2014, 2, 730738.
(28) Du, P.; Yang, Y.; Kang, D. W.; Yang, J.; Liu, Y. Y.; Ma, J. F. Four cluster-containing highly connected coordination networks: syntheses, structures, and properties. CrystEngComm. 2014, 28, 63726379.
(29) Cheng, H. J.; Li, H. X.; Ren, Z. G.; Lü, C. N.; Shi, J.; Lang, J. P. Substituted groups-directed assembly of Cd(II) coordination polymers based on 5-R-1,3-benzenedicarboxylate and 4,4΄-bis(1-imidazolyl)bibenzene: syntheses, structures and photoluminescent properties. CrystEngComm. 2012, 18, 60646071.
(30) Ming, C. L.; Zhang, H.; Li, G. Y.; Cui, G. H. Assembly and catalytic properties of a 3D (4, 6)-connected cobalt-organic framework with fsh topology. Notes 2014, 2, 651.
(31) Guo, F.; Wang, F.; Yang, H.; Zhang, X.; Zhang, J. Tuning structural topologies of three photoluminescent metal-organic frameworks via isomeric biphenyldicarboxylates. Inorg. Chem. 2012, 18, 96779682.
(32) Abu Youssef, M. A.; Mautner, F. A.; Alshima’a, A. M.; Öhrström, L. Synthesis, structure, network and thermal analysis of four 5-(pyrazinyl)tetrazolato copper(II) and cobalt(II) complexes. Polyhedron 2007, 7, 15311540.
(33) Platero-Prats, A. E.; Iglesias, M.; Snejko, N.; Monge, Á.; Gutiérrez-Puebla, E. From coordinatively weak ability of constituents to very stable alkaline-earth sulfonate metal-organic frameworks. Cryst. Growth Des. 2011, 5, 17501758.
(34) Yang, G. P.; Hou, L.; Wang, Y. Y.; Zhang, Y. N.; Shi, Q. Z.; Batten, S. R. Two unprecedented three-dimensional Pb(II) polymorphs and structural diversities built on a kinked flexible dicarboxylate building block. Cryst. Growth Des. 2011, 4, 936940.
(35) Duan, J.; Higuchi, M.; Zou, C.; Jin, W.; Kitagawa, S. Two solvent-dependent porous coordination polymers with -OH decorated ligands: unusual non-crystallographic net and fsh topology. CrystEngComm. 2015, 30, 56095613.
(36) Banerjee, S.; Ghosh, A.; Wu, B.; Lassahn, P. G.; Janiak, C. Polymethylene spacer regulated structural divergence in cadmium complexes: unusual trigonal prismatic and severely distorted octahedral coordination. Polyhedron 2005, 5, 593599.
(37) Zhang, M. D.; Qin, L.; Yang, H. T.; Li, Y. Z.; Guo, Z. J.; Zheng, H. G. Series of metal-organic frameworks including novel architectural features based on a star-like tri(4-pyridylphenyl)amine ligand. Cryst. Growth Des. 2013, 5, 19611969.
(38) Zhai, Q. G.; Gao, X.; Li, S. N.; Jiang, Y. C.; Hu, M. C. Solvothermal synthesis, crystal structures and photoluminescence properties of the novel Cd/X/, -bis(benzotriazole)alkane hybrid family (X = Cl, Br and I). CrystEngComm. 2011, 5, 16021616.
(39) Liu, H. Y.; Wu, H.; Ma, J. F.; Liu, Y. Y.; Liu, B.; Yang, J. Syntheses, structures, and photoluminescence of zinc(II) coordination polymers based on carboxylates and flexible bis[(pyridyl)-benzimidazole] ligands. Cryst. Growth Des. 2010, 11, 47954805.
(40) Guo, Y.; Feng, X.; Han, T.; Wang, S.; Lin, Z.; Dong, Y.; Wang, B. Tuning the luminescence of metal-organic frameworks for detection of energetic heterocyclic compounds. J. Am. Chem. Soc. 2014, 44, 1548515488.
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