Spacer Length Effects on the Structure of Cd(II) Coordination Polymers with Flexible Bis(thiabendazolyl) Alkane and 1,2,4,5-Benzenetetracarboxylte Ligands
瞿云华;董桂英;郝少云;桓殿恒
a (School of Metallurgy, Northeastern University, Liaoning, Shenyang 110004, China)
b (College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University
of Science and Technology, Tangshan, Hebei 063009, China)
Spacer Length Effects on the Structure of Cd(II) Coordination Polymers with Flexible Bis(thiabendazolyl) Alkane and 1,2,4,5-Benzenetetracarboxylte Ligands
a (School of Metallurgy, Northeastern University, Liaoning, Shenyang 110004, China)
b (College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University
of Science and Technology, Tangshan, Hebei 063009, China)
The hydrothermal reactions of Cd(OAc)2•2H2O with 1,2,4,5-benzenetetracarboxylic acid (H4bta) and 1,4-bis(thiabendazolyl)butane (L1) or 1,6-bis(thiabendazolyl)hexane (L2) afforded two coordination polymers [Cd2(L1)(bta)•2H2O]n (1) and [Cd2(L2)2(H2bta)2]n (2). Complex 1 holds a rare 3D binodal (4,6)-connected framework with fsh topology. Complex 2 features an infinite meandering chain structure, which is further extended via O–H•••O hydrogen bonding into a 3D supramolecular network. The thermal and fluorescence proprieties of the two complexes were investigated.
The hydrothermal reactions of Cd(OAc)2•2H2O with 1,2,4,5-benzenetetracarboxylic acid (H4bta) and 1,4-bis(thiabendazolyl)butane (L1) or 1,6-bis(thiabendazolyl)hexane (L2) afforded two coordination polymers [Cd2(L1)(bta)•2H2O]n (1) and [Cd2(L2)2(H2bta)2]n (2). Complex 1 holds a rare 3D binodal (4,6)-connected framework with fsh topology. Complex 2 features an infinite meandering chain structure, which is further extended via O–H•••O hydrogen bonding into a 3D supramolecular network. The thermal and fluorescence proprieties of the two complexes were investigated.
Project supported by the Natural Science Foundation-steel and Iron Foundation of Hebei Province (B2015209299 and E2016209304)
通讯作者:
yunhuaqu@163.com
E-mail: yunhuaqu@163.com
引用本文:
瞿云华;董桂英;郝少云;桓殿恒. Spacer Length Effects on the Structure of Cd(II) Coordination Polymers with Flexible Bis(thiabendazolyl) Alkane and 1,2,4,5-Benzenetetracarboxylte Ligands[J]. 结构化学, 2017, 36(1): 153-162.
QU Yun-Hua;DONG Gui-Ying;HAO Shao-Yun;HUAN Dian-Heng. Spacer Length Effects on the Structure of Cd(II) Coordination Polymers with Flexible Bis(thiabendazolyl) Alkane and 1,2,4,5-Benzenetetracarboxylte Ligands. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(1): 153-162.
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