Syntheses and Characterizations of Two Manganese(II) Coordination Polymers Containing Three-dimensional Interpenetrating Networks Constructed by Mixed Ligands
郝少云;郝增川;刘永光;董桂英
College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science
and Technology, Tangshan, Hebei 063009, China
Syntheses and Characterizations of Two Manganese(II) Coordination Polymers Containing Three-dimensional Interpenetrating Networks Constructed by Mixed Ligands
College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science
and Technology, Tangshan, Hebei 063009, China
Two new three-dimensional coordination polymers, namely [Mn(L)(bpdc)]n (1), [Mn(L)0.5(ndc)]n (2) (L = 1,4-bis(2-methylbenzimidazole)butane, H2bpdc = 4,4΄-biphenyldicarboxy- lic acid, H2ndc = 2,6-naphthalenedicarboxylic acid) have been successfully synthesized under hydrothermal conditions. Two complexes were characterized by physico-chemical, spectroscopic methods and single-crystal X-ray diffraction. Complex 1 shows a 3D → 3D 5-fold interpenetrated network with a 4-connected uninodal dia topology. Complex 2 possesses a 3D → 3D 3-fold interpenetrating architecture with a binodal (4,5)-connected xah topology. The fluorescence and thermal properties of the title complexes were discussed.
Two new three-dimensional coordination polymers, namely [Mn(L)(bpdc)]n (1), [Mn(L)0.5(ndc)]n (2) (L = 1,4-bis(2-methylbenzimidazole)butane, H2bpdc = 4,4΄-biphenyldicarboxy- lic acid, H2ndc = 2,6-naphthalenedicarboxylic acid) have been successfully synthesized under hydrothermal conditions. Two complexes were characterized by physico-chemical, spectroscopic methods and single-crystal X-ray diffraction. Complex 1 shows a 3D → 3D 5-fold interpenetrated network with a 4-connected uninodal dia topology. Complex 2 possesses a 3D → 3D 3-fold interpenetrating architecture with a binodal (4,5)-connected xah topology. The fluorescence and thermal properties of the title complexes were discussed.
Project supported by the National Natural Science Foundation of China (No. 51474086 ) and Natural Science Foundation-Steel and Iron Foundation of Hebei Province (B2015209299)
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E-mail: tsdgying@126.com
引用本文:
郝少云;郝增川;刘永光;董桂英. Syntheses and Characterizations of Two Manganese(II) Coordination Polymers Containing Three-dimensional Interpenetrating Networks Constructed by Mixed Ligands[J]. 结构化学, 2017, 36(1): 118-126.
HAO Shao-Yun;HAO Zeng-Chuan;LIU Yong-Guang;DONG Gui-Ying. Syntheses and Characterizations of Two Manganese(II) Coordination Polymers Containing Three-dimensional Interpenetrating Networks Constructed by Mixed Ligands. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(1): 118-126.
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