Syntheses and Characterizations of Two Manganese(II) Coordination Polymers Containing Three-dimensional Interpenetrating Networks Constructed by Mixed Ligands
郝少云;郝增川;刘永光;董桂英
College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science
and Technology, Tangshan, Hebei 063009, China
Syntheses and Characterizations of Two Manganese(II) Coordination Polymers Containing Three-dimensional Interpenetrating Networks Constructed by Mixed Ligands
College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science
and Technology, Tangshan, Hebei 063009, China
Two new three-dimensional coordination polymers, namely [Mn(L)(bpdc)]n (1), [Mn(L)0.5(ndc)]n (2) (L = 1,4-bis(2-methylbenzimidazole)butane, H2bpdc = 4,4΄-biphenyldicarboxy- lic acid, H2ndc = 2,6-naphthalenedicarboxylic acid) have been successfully synthesized under hydrothermal conditions. Two complexes were characterized by physico-chemical, spectroscopic methods and single-crystal X-ray diffraction. Complex 1 shows a 3D → 3D 5-fold interpenetrated network with a 4-connected uninodal dia topology. Complex 2 possesses a 3D → 3D 3-fold interpenetrating architecture with a binodal (4,5)-connected xah topology. The fluorescence and thermal properties of the title complexes were discussed.
Two new three-dimensional coordination polymers, namely [Mn(L)(bpdc)]n (1), [Mn(L)0.5(ndc)]n (2) (L = 1,4-bis(2-methylbenzimidazole)butane, H2bpdc = 4,4΄-biphenyldicarboxy- lic acid, H2ndc = 2,6-naphthalenedicarboxylic acid) have been successfully synthesized under hydrothermal conditions. Two complexes were characterized by physico-chemical, spectroscopic methods and single-crystal X-ray diffraction. Complex 1 shows a 3D → 3D 5-fold interpenetrated network with a 4-connected uninodal dia topology. Complex 2 possesses a 3D → 3D 3-fold interpenetrating architecture with a binodal (4,5)-connected xah topology. The fluorescence and thermal properties of the title complexes were discussed.
Project supported by the National Natural Science Foundation of China (No. 51474086 ) and Natural Science Foundation-Steel and Iron Foundation of Hebei Province (B2015209299)
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tsdgying@126.com
E-mail: tsdgying@126.com
引用本文:
郝少云;郝增川;刘永光;董桂英. Syntheses and Characterizations of Two Manganese(II) Coordination Polymers Containing Three-dimensional Interpenetrating Networks Constructed by Mixed Ligands[J]. 结构化学, 2017, 36(1): 118-126.
HAO Shao-Yun;HAO Zeng-Chuan;LIU Yong-Guang;DONG Gui-Ying. Syntheses and Characterizations of Two Manganese(II) Coordination Polymers Containing Three-dimensional Interpenetrating Networks Constructed by Mixed Ligands. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36(1): 118-126.
REFERENCES
(1) Liu, J.; Chen, L.; Cui, H.; Zhang, J.; Zhang, L.; Su, C. Y. Applications of metal-organic frameworks in heterogeneous supramolecular catalysis. Chem. Soc. Rev. 2014, 16, 60116061.
(2) Li, J. R.; Sculley, J.; Zhou, H. C. Metal-organic frameworks for separations. Chem. Rev. 2011, 2, 869932.
(3) Hu, J. M.; Blatov, V. A.; Yu, B.; Van Hecke, K.; Cui, G. H. An unprecedented "strongly" self-catenated MOF containing inclined catenated honeycomb-like units. Dalton Tran. 2016, 6, 24262429.
(4) Yang, J. X.; Qin, Y. Y.; Cheng, J. K.; Yao, Y. G. Tuning different kinds of entangled networks by varying N-donor ligands: from self-penetrating to multi-interpenetrating. Cryst. Growth Des. 2014, 3, 10471056.
(5) Yoon, M.; Srirambalaji, R.; Kim, K. Homochiral metal-organic frameworks for asymmetric heterogeneous catalysis. Chem. Rev. 2011, 2, 11961231.
(6) Cao, L. H.; Wei, Y. L.; Yang, Y.; Xu, H.; Zang, S. Q.; Hou, H. W.; Mak, T. C. Crystal structures and properties of Cd(II) coordination polymers supported by a new chiral aromatic polycarboxylate ligand. Cryst. Growth Des. 2014, 4, 18271838.
(7) Batten, S. R.; Robson, R. Interpenetrating nets: ordered, periodic entanglement. Angew. Chem. Int. Ed. 1998, 11, 14601494.
(8) Carlucci, L.; Ciani, G.; Proserpio, D. M. Polycatenation, polythreading and polyknotting in coordination network chemistry. Coord. Chem. Rev. 2003, 1, 247289.
(9) Baburin, I. A.; Blatov, V. A.; Carlucci, L.; Ciani, G.; Proserpio, D. M. Interpenetrated three-dimensional networks of hydrogen-bonded organic species: a systematic analysis of the cambridge structural database. Cryst. Growth Des. 2008, 2, 519539.
(10) Wu, X. R.; Yang, X.; Wei, R. J.; Li, J.; Zheng, L. S.; Tao, J. Solvent-mediated isomerization of Fe(II) complexes from a 3D 65•8 framework to a 2D 44 rhombus-grid network. Cryst. Growth Des. 2014, 10, 48914894.
(11) Wang, L.; Yan, Z. H.; Xiao, Z.; Guo, D.; Wang, W.; Yang, Y. Reactant ratio-modulated entangled Cd(II) coordination polymers based on rigid tripodal imidazole ligand and tetrabromoterephthalic acid: interpenetration, interdigitation and self-penetration. CrystEngComm. 2013, 27, 55525560.
(12) Lin, H. Y.; Luan, J.; Wang, X. L.; Zhang, J. W.; Liu, G. C.; Tian, A. X. Construction and properties of cobalt(II)/copper(II) coordination polymers based on N-donor ligands and polycarboxylates mixed ligands. RSC Adv. 2014, 107, 6243062445.
(13) Zhang, H. M.; Yang, J.; Liu, Y. Y.; Kang, D. W.; Ma, J. F. A family of coordination polymers assembled with a flexible hexacarboxylate ligand and auxiliary N-donor ligands: syntheses, structures, and physical properties. CrystEngComm. 2015, 16, 31813196.
(14) Cui, G. H.; He, C. H.; Jiao, C. H.; Geng, J. C.; Blatov, V. A. Two metal-organic frameworks with unique high-connected binodal network topologies: synthesis, structures, and catalytic properties. CrystEngComm. 2012, 12, 42104216.
(15) Hao, J. M.; Zhao, Y. N.; Li, H. H.; Ming, C. L.; Cui, G. H. A series of d10 metal coordination polymers based on a flexible bis(2-methylbenzimidazole) ligand and different carboxylates: synthesis, structures, photoluminescence and catalytic properties. CrystEngComm. 2015, 11, 22792293.
(16) Yang, R.; Liu, Y. G.; Van Hecke, K.; Cui, G. H. Synthesis and characterization of two cobalt(II) coordination polymers based on 5-tert-butyl isophthalic acid and bis(benzimidazole) ligands. Tran. Met. Chem. 2015, 3, 333340.
(17) Wang, X. X.; Liu, Y. G.; Van Hecke, K.; Goltsev, A.; Cui, G. H. Three silver(I) coordination polymers constructed from flexible bis(benzimidazole) and carboxylates ligands. Z. Anorg. Allg. Chem. 2015, 5, 903910.
(18) Wang, X. X.; Liu, Y. G.; Ge, M.; Cui, G. H. Syntheses, crystal structures and fluorescence properties of two metal-organic coordination polymers derived from rigid bis(1,2,4-triazolyl) and aromatic carboxylic acid ligands. Chin. J. Inorg. Chem. 2015, 10, 20652072.
(19) Huan, D. H.; Yu, Y. M.; Wang, S. C.; Dong, G. Y. Syntheses, structures, and catalytic properties of two 2D manganese(II) coordination polymers containing flexible bis(benzimidazole) ligands. Z. Anorg. Allg. Chem. 2015, 11, 18991905.
(20) Yang, J.; Ma, J. F.; Liu, Y. Y.; Ma, J. C.; Jia, H. Q.; Hu, N. H. Two new Cu(II) coordination polymers: studies of topological networks and water clusters. Eur. J. Inorg. Chem. 2006, 6, 12081215.
(21) Sheldrick, G. M. SADABS 2.05, Area-detector Absorption Correction. University of Göttingen, Germany 1996.
(22) Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structure. University of Göttingen, Göttingen, Germany 1997.
(23) Yang, Y. Q.; Yang, J.; Kan, W. Q.; Yang, Y.; Guo, J.; Ma, J. F. A series of 1D, 2D, and 3D coordination polymers based on flexible 3-carboxy-1-carboxymethyl-2-oxidopyridinium and different N-donor ligands-syntheses, structures, and luminescent properties. Eur. J. Inorg. Chem. 2013, 2, 280292.
(24) Blatov, V. Nanocluster analysis of intermetallic structures with the program package TOPOS. Struct. Chem. 2012, 4, 955963.
(25) Blatov, V.; Carlucci, L.; Ciani, G.; Proserpio, D. M. J. Solid State Chem. 2005, 2452.
(26) Blatov, V.; Carlucci, L.; Ciani, G.; Proserpio, D. Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database. CrystEngComm. 2004, 65, 377395.
(27) Li, J. R.; Zhou, H. C. Metal-organic hendecahedra assembled from dinuclear paddlewheel nodes and mixtures of ditopic linkers with 120 and 90 bend angles. Angew. Chem. Int. Ed. 2009, 45, 84658468.
(28) Spek, A. L. PLATON, A Multipurpose Crystallographic Tool. Utrecht University, Utrecht, The Netherlands 2001.
(29) Singh, D. P.; Allam, B. K.; Singh, K. N.; Singh, V. P. A binuclear Mn(II) complex as an efficient catalyst for transamidation of carboxamides with amines. RSC Adv. 2014, 3, 11551158.
(30) Wang, D. E.; Deng, K. J.; Lv, K. L.; Wang, C. G.; Wen, L. L.; Li, D. F. Structures, photoluminescence and photocatalytic properties of three new metal-organic frameworks based on non-rigid long bridges. CrystEngComm. 2009, 7, 14421450.
(31) Gu, X.; Xue, D. Selected controlled synthesis of three-dimensional 4d-4f heterometallic coordination frameworks by lanthanide carboxylate subunits and silver centers. Cryst. Growth Des. 2006, 11, 25512557.
(32) Deacon, G.; Phillips, R. Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination. Coord. Chem. Rev. 1980, 3, 227250.
(33) Bai, H. Y.; Yang, J.; Liu, B.; Ma, J. F.; Kan, W. Q.; Liu, Y. Y.; Liu, Y. Y. Syntheses, structures, and photoluminescence of five silver(I) coordination polymers based on tetrakis(imidazol-1-ylmethyl)methane. CrystEngComm. 2011, 19, 58775884.
(34) Liu, G. C.; Huang, J. J.; Zhang, J. W.; Wang, X. L.; Lin, H. Y. Effect of organic bicarboxylates on the structures of cobalt(II) coordination polymers derived from a semi-rigid bis(benzimidazole) derivative. Trans. Met. Chem. 2013, 4, 359365.
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