Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+Coordination Compound Containing Rare (H2O)22 Clusters

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摘要

A novel Dy3+ coordination compound, (H2pipz)(H3O)[Dy(pydc)3]•11H2O (1, pipz = piperazine and H2pydc = pyridine-2,6-dicarboxylic acid), has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction, elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a three- dimensional supramolecular structure via O•••H•••O hydrogen bonding interactions. Furthermore, the luminescent property of compound 1 was also investigated.

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	叶燕珠
	吴新建
	张贤金
	汪阿恋

关键词 ： Dy3+ coordination compound, crystal structure, water clusters, luminescent property

Abstract：

Key words： Dy3+ coordination compound crystal structure water clusters luminescent property

收稿日期: 2016-09-18 出版日期: 2016-12-12

基金资助:

This work was financially supported by the Foundation of Fujian Educational Committee (JA14348)

通讯作者: yanzhuye@126.com E-mail: yanzhuye@126.com

引用本文:

叶燕珠;吴新建;张贤金;汪阿恋. Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+Coordination Compound Containing Rare (H2O)22 Clusters[J]. 结构化学, 2016, 35(12): 1980-1986.
YE Yan-Zhu;WU Xin-Jian;ZHANG Xian-Jin;WANG A-Lian. Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+Coordination Compound Containing Rare (H2O)22 Clusters. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(12): 1980-1986.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I12/1980

REFERENCES
(1)Gu, J. Z.; Wu, J.; Lv, D. Y.; Tang, Y.; Zhu, K.; Wu, J. Lanthanide coordination polymers based on 5-(2΄-carboxylphenyl) nicotinate: syntheses, structure diversity, dehydration/hydration, luminescence and magnetic properties. Dalton Trans. 2013, 42, 4822–4830.
(2) Zhang, F. M.; Yan, P. F.; Zou, X. Y.; Zhang, J. W.; Hou, G. F.; Li, G. M. Novel 3D alkali-lanthanide heterometal-organic frameworks with pyrazine-2,3,5,6-tetracarboxylic acid: synthesis, structure, and magnetism. Cryst. Growth Des. 2014, 14, 2014–2021.
(3) Wei, X. H.; Yang, L. Y.; Liao, S. Y.; Zhang, M.; Tian, J. L.; Du, P. Y.; Gu, W.; Liu, X. A series of rare earth complexes with novel non-interpenetrating 3D
networks: synthesis, structures, magnetic and optical properties. Dalton Trans. 2014, 43, 5793–5800.
(4) Feng, X.; Ling, X. L.; Liu, L.; Song, H. L.; Wang, L. Y.; Ng, S. W.; Su, B. Y. A series of 3D lanthanide frameworks constructed from aromatic multi-carboxylate ligand: structural diversity, luminescence and magnetic properties. Dalton Trans. 2013, 42, 10292–10303.
(5) Vilela, S. M. F.; Firmino, A. D. G.; Mendes, R. F.; Fernandes, J. A.; Ananias, D.; Valente, A. A.; Ott, H.; Carlos, L. D.; Rocha, J.; Tome, J. P. C.; Paz, F. A. A. Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties. Chem. Commun. 2013, 49, 6400–6402.
(6) Feng, W.; Zhang, Y.; Lü, X.; Hui, Y.; Shi, G.; Zou, D.; Song, J.; Fan, D.; Wong, W. K.; Richard, A. J. Near-infrared (NIR) luminescent homoleptic lanthanide salen complexes Ln4(Salen)4 (Ln = Nd, Yb or Er). CrystEngComm. 2012, 14, 3456–3463.
(7) Xu, J.; Su, W. P.; Hong, M. C. A series of lanthanide secondary building units based metal-organic frameworks constructed by organic
pyridine-2,6-dicarboxylate and inorganic sulfate. Cryst. Growth Des. 2011, 11, 337–346.
(8) Ye, Y. Z.; Wu, X. J.; Wang, A. L. Synthesis, structure and property of a novel coordination polymer [Tb(C7H3NO4)(C6H4NO2)(H2O)]. Chin. J. Struct. Chem. 2014, 33, 1860–1864.
(9) Yang, L. R.; Song, S.; Shao, C. Y.; Zhang, W.; Zhang, H. M.; Bu, Z. W.; Ren, T. G. Synthesis, structure and luminescent properties of 3D lanthanide (La(III), Ce(III)) coordination polymers possessing 1D nanosized cavities based on pyridine-2,6-dicarboxylic acid. Synth. Met. 2011, 161, 1500–1508.
(10) (a) Li, M.; Feng, R.; Huang, Q. Z.; Feng, Y. Q.; Shi, H. Z. Synthesis, crystal structure and luminescent property of a novel lanthanide coordination polymer containing (H2O)20 clusters. Inorg. Chem. Commun. 2014, 50, 8–12.
(b) Aghabozorg, H.; Motieiyan, E.; Salimi, A. R.; Mirzaei, M.; Manteghi, F.; Shokrollahi, A.; Derki, S.; Ghadermazi, M.; Sheshmani, S.; Eshtiagh-Hosseini, H. Piperazinediium, Zr(IV) and Ce(IV) pyridine-2,6-dicarboxylates: syntheses, characterizations, crystal structures, ab initio HF, DFT calculations and solution studies. Polyhedron 2010, 29, 1453–1464.
(c) Dalai, S.; Rana, A.; Chowdhuri, D. S.; Bera, M.; Zangrando, E. Cubane-like water clusters in a 3D supramolecular network of zinc with pyridine-2,6-dicarboxylic acid and 5-aminotetrazole. Inorg. Chim. Acta 2010, 363, 1052–1055.
(d) Deng, D. S.; Liu, P.; Fu, W. J.; Li, L.; Yang, F. X.; Ji, B. M. Metal-organic open frameworks with one-dimension channels assembled with pyridine 2,6-dicarboxylic acid and N-containing auxiliary ligands: syntheses, crystal structures, and physical characterization. Inorg. Chim. Acta 2010, 363, 891–898.
(11) Zhu, T. Y.; Ikarashi, K.; Ishigaki, T.; Uematsu, K.; Toda, K.; Okawa, H.; Sato, M. Structure and luminescence of sodium and lanthanide(III) coordination polymers with pyridine-2,6-dicarboxylic acid. Inorg. Chim. Acta 2009, 362, 3407–3414.
(12) Deng, D. S.; Liu, P.; Fu, W. J.; Li, L.; Yang, F. X.; Ji, B. M. Metal-organic open frameworks with one-dimension channels assembled with pyridine 2,6-dicarboxylic acid and N-containing auxiliary ligands: syntheses, crystal structures, and physical characterization. Inorg. Chim. Acta 2010, 363, 891–898.
(13) Dalai, S.; Rana, A.; Chowdhuri, D. S.; Bera, M.; Zangrando, E. Cubane-like water clusters in a 3D supramolecular network of zinc with pyridine-2,6-dicarboxylic acid and 5-aminotetrazole. Inorg. Chim. Acta 2010, 363, 1052–1055.
(14) Zeng, X. Z.; Zhang, A. Y.; He, C.; Li, Y. W. Synthesis, structure and thermal properties of two cerium(Ⅳ) complexes with 2,6-pyridinedicarboxylic acid. Chin. J. Inorg. Chem. 2013, 29, 1557–1562.
(15) Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of Göttingen, Göttingen (Germany) 1997.
(16) Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures. University of Göttingen, Göttingen (Germany) 1997.
(17) Biswas, S.; Jena, H. S.; Goswami, S.; Sanda, S.; Konar, S. Synthesis and characterization of two lanthanide (Gd3+and Dy3+)-based three-dimensional metal organic frameworks with squashed metallomacrocycle type building blocks and their magnetic, sorption, and fluorescence properties study. Cryst. Growth Des. 2014, 14, 1287–1295.
(18) Ghosh, S. K. Structure of a discrete hexadecameric water cluster in a metal-organic framework structure. Inorg. Chem. 2004, 43, 6687–6889.
(19) Mao, P. D.; Yan, L. L.; Wu, W. N.; Liu, M. Q.; Zhou, L. H.; Fu, S. L. Lanthanide (La, Tb, Dy) complexes with quinolinyloxy acetamide ligand: crystal structures and fluorescence properties. Chin. J. Inorg. Chem. 2016, 32, 1095–1100.
(20) Li, H. H.; Li, H.; Niu, Z.; Wang, Y. P. Structural diversity of two novel Dy(III) metal-organic frameworks based on binuclear nodes with furan-2,5-dicarboxylic acid: crystal structures and luminescent properties. Inorg. Chem. Commun. 2015, 55, 103–107.
(21) Yang, R.; He, S. Y.; Wu, W. T.; Wen, Z. Y.; Shi, Q. Z.; Wang, D. Q. Crystal structure, fluorescence characterization of dysprosium(III) multicomponent complex with acylhydrazone and 1,10-phenanthroline. Acta Chimica Sinica 2004, 62, 2040–2044.