Syntheses, Crystal Structures and Luminescent Properties of Two New Zinc(II) Complexes Based on Bifunctional Ligand

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By using solvothermal method, two novel coordination polymers based on 4-(4-carboxyphen-yl)-1,2,4-triazole (Hcpt) and Zn(II) cations, [Zn(cpt)(OH)]n•nH2O (FJU-32) and [Zn(cpt)(atrz)]n (FJU-33) (Hatrz = 3-amino-1,2,4-triazolate), were synthesized and characterized by single-crystal X-ray diffraction analyses, elemental analyses, FT-IR and powder X-ray diffraction. FJU-32 crystallizes in monoclinic, space group P21/c with a = 3.7441(3), b = 23.0384(19), c = 11.8562(10) Å, = 99.069(8)º, V = 1009.91(15) Å3, Dc = 1.898 g/cm3, C9H9N3O4Zn, Mr = 288.57, F(000) = 916, (MoK) = 2.439 mm-1, Z = 4, R = 0.0600 and wR = 0.1306 for 2412 observed reflections (I > 2(I)), and R = 0.0704 and wR = 0.1349 for all data. FJU-33 crystallizes in monoclinic space group P21/c with a = 12.7483(5), b = 9.9922(3), c = 9.8403(3) Å, = 100.756(4)°, V = 1231.47(7) Å3, Dc = 1.816 g/cm3, C11H9N7O2Zn, Mr = 336.62, F(000) = 680, (CuK) = 2.957 mm-1, Z = 4, R = 0.0478 and wR = 0.1184 for 2466 observed reflections (I > 2(I)), and R = 0.0687 and wR = 0.1309 for all data. In FJU-32, Zn(II) is coordinated to three 3-OH groups forming an unprecedented 1D zigzag-like double chain, and the 1D double chains are connected to four neighbouring double chains by the cpt ligands to form an extended 3D porous coordination polymer. In FJU-33, the adjacent [Zn(atrz)] 2D layers are further connected by the cpt ligands via Zn–O coordinated bonds and neighboring interlayer hydrogen-bonding interactions to give rise to an overall 3D pillared layer structure. The neutron triazole group of the cpt ligand has weaker coordination ability than the triazolate anion of atrz ligand. Furthermore, FJU-32 and FJU-33 display high thermal stability up to 300 ℃, and the solid state fluorescence reveals that two new complexes are potential optical materials.

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	叶应祥
	郑键红
	曾燕婷
	林燕丽
	张柳钦
	王丽华
	张章静
	项生昌

关键词 ： bifunctional ligand, solvothermal synthesis, coordination polymers, photoluminescence

Abstract：

Key words： bifunctional ligand solvothermal synthesis coordination polymers photoluminescence

收稿日期: 2016-03-25 出版日期: 2016-12-12

基金资助:Financially supported by the National Natural Science Foundation of China (21207018, 21273033, 21203024 and 21573042), Fujian Science and Technology Department (2014J06003, 2014H6007 and 2016J01046) and college students' innovative training program (201510394008, 201510394055). S. X. gratefully acknowledges the supports from Recruitment Program of Global Young Experts, Program for New Century Excellent Talents in University (NCET-10-0108), and the Award ‘Minjiang Scholar Program’ in Fujian Province

通讯作者: lhwang@fjnu.edu.cn E-mail: lhwang@fjnu.edu.cn

引用本文:

叶应祥;郑键红;曾燕婷;林燕丽;张柳钦;王丽华;张章静;项生昌. Syntheses, Crystal Structures and Luminescent Properties of Two New Zinc(II) Complexes Based on Bifunctional Ligand[J]. 结构化学, 2016, 35(12): 1944-1952.
YE Ying-Xiang;ZHENG Jian-Hong;ZENG Yan-Ting;LIN Yan-Li;ZHANG Liu-Qin;WANG Li-Hua;ZHANG Zhang-Jing;XIANG Sheng-Chang. Synthesis, Crystal Structure and Luminescent Properties of Two New Zinc(II) Complexes Based on Bifunctional Ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(12): 1944-1952.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I12/1944

REFERENCES
(a) Zhou, H. C.; Long, J. R.; Yaghi, O. M. Introduction to metal-organic frameworks. Chem. Rev. 2012, 112, 673674; (b) Sato, H.; Kosaka, W.; Matsuda, R.; Hori, A.; Hijikata, Y.; Belosludov, R. V.; Sakaki, S.; Takata, M.; Kitagawa, S. Self-accelerating CO sorption in a soft nanoporous crystal. Science 2014, 343, 167170; (c) Férey, G.; Serre, C. Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences. Chem. Soc. Rev. 2009, 38, 13801399.
( ) El-Kaderi, H. M.; Hunt, J. R.; Mendoza-Cortés, J. L.; Côté, A. P.; Taylor, R. E.; O’Keeffe, M.; Yaghi, O. M. Designed synthesis of 3D covalent organic frameworks. Science 2007, 316, 268272.
( ) (a) O’Keeffe, M.; Yaghi, O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. Chem. Rev. 2012, 112, 675702; (b) Guillerm, V.; Kim, D.; Eubank, J. F.; Luebke, R.; Liu, X.; Adil, K.; Lah, M. S.; Eddaoudi, M. A supermolecular building approach for the design and construction of metal-organic frameworks. Chem. Soc. Rev. 2014, 43, 61416172.
( ) (a) Xiang, S. C.; Zhang, Z. J.; Zhao, C. G.; Hong, K.; Zhao, X.; Ding, D. R.; Xie, M. H.; Wu, C. D.; Das, M. C.; Gill, R.; Thomas, K. M.; Chen, B. L. Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene. Nat. Commun. 2011, 2, 204210; (b) Xiang, S. C.; He, Y. B.; Zhang, Z. J.; Wu, H.; Zhou, W.; Krishna, R.; Chen, B. L. Microporous metal-organic framework with potential for carbon dioxide capture at ambient conditions. Nat. Commun. 2012, 3, 954962; (c) Zhang, Z.; Yao, Z. Z.; Xiang, S.; Chen, B. Perspective of microporous metal-organic frameworks for CO2 capture and separation. Energy Environ. Sci. 2014, 7, 28682899; (d) Shen, Y. C.; Li, Z. Y.; Wang, L. H.; Ye, Y. X.; Liu, Q.; Ma, X. L.; Chen, Q. H.; Zhang, Z. J.; Xiang, S. C. Cobalt-citrate framework armored with graphene oxide exhibiting improved thermal stability and selectivity for biogas decarburization. J. Mater. Chem. A 2015, 3, 593599; (e) Chen, Y.; Li, Z. Y.; Liu, Q.; Shen, Y. C.; Wu, X. Z.; Xu, D. D.; Ma, X. L.; Wang, L. H.; Chen, Q. H.; Zhang, Z. J.; Xiang, S. C. Microporous metal-organic framework with lantern-like dodecanuclear metal coordination cages as nodes for selective adsorption of C2/C1 mixtures and sensing of nitrobenzen. Cryst. Growth Des. 2015, 15, 38473852; (f) Liu, L. Z.; Ye, Y. X.; Yao, Z. Z.; Zhang, L. Q.; Li, Z. Y.; Wang, L. H.; Ma, X. L.; Chen, Q. H.; Zhang, Z. J.; Xiang, S. C. A hierarchically porous metal-organic framework from semirigid ligand for gas adsorption. Chin. J. Chem. 2016, 34, 215219; (g) Yao, Z.; Zhang, Z.; Liu, L.; Li, Z.; Zhou, W.; Zhao, Y.; Han, Y.; Chen, B.; Krishna, R.; Xiang, S. Extraordinary separation of acetylene-containing mixtures with microporous metal-organic frameworks with open O donor sites and tunable robustness through control of the helical chain secondary building units. Chem.-Eur. J. 2016, 22, 56765683; (h) Song, C.; Jiao, J.; Lin, Q.; Liu, H.; He, Y. C2H2 adsorption in three isostructural metal-organic frameworks: boosting C2H2 uptake by rational arrangement of nitrogen sites. Dalton Trans. 2016, 45, 45634569.
( ) (a) Ramaswamy, P.; Wong, N. E.; Shimizu, G. K. H. MOFs as proton conductors-challenges and opportunities. Chem. Soc. Rev. 2014, 43, 59135932; (b) Xu, G.; Otsubo, K.; Yamada, T.; Sakaida, S.; Kitagawa, H. Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm. J. Am. Chem. Soc. 2013, 135, 74387441; (c) Ye, Y.; Zhang, L.; Peng, Q.; Wang, G. E.; Shen, Y.; Li, Z.; Wang, L.; Ma, X.; Chen, Q. H.; Zhang, Z.; Xiang, S. High anhydrous proton conductivity of imidazole-loaded mesoporous polyimides over a wide range from subzero to moderate temperature. J. Am. Chem. Soc. 2015, 137, 913918; (d) Su, X.; Yao, Z.; Ye, Y.; Zeng, H.; Xu, G.; Wu, L.; Ma, X.; Chen, Q. H.; Wang, L.; Zhang, Z.; Xiang, S. 40-Fold enhanced intrinsic proton conductivity in coordination polymers with the same proton-conducting pathway by tuning metal cation nodes. Inorg. Chem. 2016, 55, 983986; (e) Ye, Y.; Wu, X.; Yao, Z.; Wu, L.; Cai, Z.; Wang, L.; Ma, X.; Chen, Q. H.; Zhang, Z.; Xiang, S. Metal-organic frameworks with large breathing effect to host hydroxyl compounds for high anhydrous proton conductivity over a wide temperature range from subzero to 125 ℃. J. Mater. Chem. A 2016, 4, 40624070.
( ) Liu, J.; Chen, L.; Cui, H.; Zhang, J.; Zhang, L.; Su, C. Y. Applications of metal-organic frameworks in heterogeneous supramolecular catalysis. Chem. Soc. Rev. 2014, 43, 60116061.
( ) He, Y.; Li, B.; O'Keeffe, M.; Chen, B. Multifunctional metal-organic frameworks constructed from meta-benzenedicarboxylate units. Chem. Soc. Rev. 2014, 43, 56185656.
( ) (a) Xue, D. X.; Cairns, A. J.; Belmabkhout, Y.; Wojtas, L.; Liu, Y.; Alkordi, M. H.; Eddaoudi, M. Tunable rare-earth fcu-MOFs: a platform for systematic enhancement of CO2 adsorption energetics and uptake. J. Am. Chem. Soc. 2013, 135, 76607667; (b) He, C. T.; Tian, J. Y.; Liu, S. Y.; Ouyang, G.; Zhang, J. P.; Chen, X. M. A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic compounds. Chem. Sci. 2013, 4, 351356.
( ) (a) Savard, D.; Lin, P. H.; Burchell, T. J.; Korobkov, I.; Wernsdorfer, W.; Clérac, R.; Murugesu, M. Two-dimensional networks of lanthanide cubane-shaped dumbbells. Inorg. Chem. 2009, 48, 1174811754; (b) Aharen, T.; Habib, F.; Korobkov, I.; Burchell, T. J.; Guillet-Nicolas, R.; Kleiz, F.; Murugesu, M. Novel Co-based metal-organic frameworks and their magnetic properties using asymmetrically binding 4-(4΄-carboxyphenyl)-1,2,4-triazole. Dalton Trans. 2013, 42, 77957802; (c) Holmberg, R. J.; Kay, M.; Korobkov, I.; Kadantsev, E.; Boyd, P. G.; Aharen, T.; Desgreniers, S.; Woo, T. K.; Murugesu, M. An unprecedented CoII cuboctahedron as the secondary building unit in a Co-based metal-organic framework. Chem. Commun. 2014, 50, 53335335.
( ) (a) Ye, Y. X.; Xiong, S. S.; Wu, X. N.; Zhang, L. Q.; Li, Z. Y.; Wang, L. H.; Ma, X. L.; Chen, Q. H.; Zhang, Z. J.; Xiang, S. C. Microporous metal-organic framework stabilized by balanced multiple host-counter anion hydrogen-bonding interactions for high-density CO2 capture at ambient conditions. Inorg. Chem. 2016, 55, 292299; (b) Chen, D. M.; Ma, J. G.; Cheng, P. Solvent-induced secondary building unit (SBU) variations in a series of Cu(II) metal-organic frameworks derived from a bifunctional ligand. Dalton Trans. 2015, 44, 89268931; (c) Chen, D. M.; Zhang, X. P.; Shi, W.; Cheng, P. Microporous metal-organic framework based on a bifunctional linker for selective sorption of CO2 over N2 and CH4. Inorg. Chem. 2015, 54, 55125518; (d) Chen, D. M.; Tian, J. Y.; Fang, S. M.; Liu, C. S. Two isomeric Zn(II)-based metal-organic frameworks constructed from a bifunctional triazolate-carboxylate tecton exhibiting distinct gas sorption behaviors. CrystEngComm. 2016, 18, 25792584.
( ) (a) Song, J. F.; Zhou, R. S.; Zhang, J.; Xu, C. Y.; Li, Y. B.; Wang, B. B. Three new cpt-metal complexes displaying 0D, 1D, and 3D topology structures. Z. Anorg. Allg. Chem. 2011, 637, 589595; (b) Wang, L.; Ye, Y.; Zhang, L.; Chen, Q.; Ma, X.; Zhang, Z.; Xiang, S. A 3D-diamond-like metal-organic framework: crystal structure, nonlinear optical effect and high thermal stability. Inorg. Chem. Commun. 2015, 60, 1922; (c) Yang, L. B.; Wang, H. C.; Fang, X. D.; Chen, S. J.; Xu, Q. Q.; Zhu, A. X.; Yang, Z. A series of Zn(II) and Cd(II) coordination compounds based on 4-(4H-1,2,4-triazol-4-yl) benzoic acid: synthesis, structure and photoluminescence properties. CrystEngComm. 2016, 18, 130142.
( ) (a) Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2012, 112, 10011033; (b) Huang, C.; Ji, F.; Liu, L.; Li, N.; Li, H.; Wu, J.; Hou, H.; Fan, Y. Seven dicarboxylate-based coordination polymers with structural varieties and different solvent resistance properties derived from the introduction of small organic linkers. CrystEngComm. 2014, 16, 26152625.
( ) Dolomanov, A. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 2009, 42, 339341.
( ) Palatinus, L.; Chapuis, G. SUPERFLIP-a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions. J. Appl. Crystallogr. 2007, 40, 786790.
( ) Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. Sect. A: Found. Crystallogr. 2008, A64, 112122.
( ) (a) Ling, Y.; Yang, F.; Deng, M.; Chen, Z.; Liu, X.; Weng, L.; Zhou, Y. Novel iso-reticular Zn(ii) metal-organic frameworks constructed by trinuclear-triangular and paddle-wheel units: synthesis, structure and gas adsorption. Dalton Trans. 2012, 41, 40074011; (b) Su, Z.; Bai, Z. S.; Fan, J.; Xu, J.; Sun, W. Y. Synthesis and characterization of 3d-3d homo- and heterometallic coordination polymers with mixed ligands. Cryst. Growth Des. 2009, 9, 51905196.
( ) Delgado-Friedrichs, O.; O’Keeffe, M. Identification of and symmetry computation for crystal nets. Acta Crystallogr. 2003, A59, 351360.
( ) Jiang, Z. Q.; Jiang, G. Y.; Wang, F.; Zhao, Z.; Zhang, J. Controlling state of breathing of two isoreticular microporous metal-organic frameworks with triazole homologues. Chem.-Eur. J. 2012, 18, 1052510529.
( ) Blatov, V. A.; Shevchenko, A. P.; Proserpio, D. M. Applied topological analysis of crystal structures with the program package ToposPro. Cryst. Growth Des. 2014, 14, 35763586.
( ) Song, Z.; Gao, H.; Li, G.; Yu, Y.; Shi, Z.; Feng, S. Influence of noncovalent intermolecular interactions on crystal packing: syntheses and crystal structures of three layered Zn(II)/1,2,4-triazole/carboxylate coordination polymers. CrystEngComm. 2009, 11, 15791584.
( ) (a) Jia, L. N.; Hou, L.; Wei, L.; Jing, X. J.; Liu, B.; Wang, Y. Y.; Shi, Q. Z. Five sra topological Ln(III)-MOFs based on novel metal-carboxylate/Cl chain: structure, near-infrared luminescence and magnetic properties. Cryst. Growth Des. 2013, 13, 15701576; (b) Huang, S. Y.; Li, J. Q.; Wu, X. L.; Zhang, X. M.; Luo, M. B.; Luo, F. A new acrylamide MOF with sra net showing an uncommon eight-fold interpenetration. Inorg. Chem. Commun. 2014, 44, 2931.
( ) Gao, J.; Wang, N.; Xiong, X.; Chen, C.; Xie, W.; Ran, X.; Long, Y.; Yue, S.; Liu, Y. Syntheses, structures, and photoluminescent properties of a series of zinc(II)-3-amino-1,2,4-triazolate coordination polymers constructed by varying carboxylate anions. CrystEngComm. 2013, 15, 32613270.
( ) (a) He, K. H.; Li, Y. W.; Chen, Y. Q.; Song, W. C.; Bu, X. H. Employing zinc clusters as SBUs to construct (3,8) and (3,14)-connected coordination networks: structures, topologies, and luminescence. Cryst. Growth Des. 2012, 12, 27302735; (b) Li, L. J.; Qin, C.; Wang, X. L.; Shao, K. Z.; Su, Z. M.; Liu, P. J. Synthesis and characterization of two self-catenated networks and one case of pcu topology based on the mixed ligands. CrystEngComm. 2012, 14, 42054209.
( ) Cui, Y.; Yue, Y.; Qian, G.; Chen, B. L. Luminescent functional metal-organic frameworks. Chem. Rev. 2012, 112, 11261162.