Catalytic Kinetic on the Thermal Decomposition of Ammonium Perchlorate with a New Energetic Complex Based on 3,5-Bis(3-pyridyl)-1H-1,2,4-triazole

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A new energetic complex, [Co(3,3΄-Hbpt)(Htm)]•H2O (1, 3,3΄-Hbpt = 3,5-bis(3- pyridyl)-1H-1,2,4-triazole and H3tm = trimesic acid), has been synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction, elementary analysis, IR spectroscopy, thermogravimetric analysis and X-ray powder diffraction. Single-crystal X-ray diffraction indicates that the complex belongs to triclinic system, space group P with a = 10.0911(1), b = 10.2573(1), c = 10.6393(1) Å, α = 103.793(2),  = 101.041(2), γ = 107.918(3)º, V = 974.9(2) Å3, Z = 2, Dc = 1.732 g•cm-3, μ = 0.941 mm-1, Mr = 508.31, F(000) = 518, the final R = 0.0523 and wR = 0.0935 with I > 2(I). In the title complex, Co(II) ions are connected by Htm2- anions generating 1D ladder-like chains which are linked by 3,3΄-Hbpt to form 1D cages. In addition, the thermal decomposition of ammonium perchlorate (AP) with complex 1 was explored by differential scanning calorimetry (DSC). AP is completely decomposed in a shorter time in the presence of complex 1, and the decomposition heat of the mixture is 2.531 kJ•g-1, signiﬁcantly higher than that of pure AP. By Kissinger's method, the ratio of Ea/ln(A) is 11.05 for the mixture, which indicates that complex 1 shows good catalytic activity toward the AP decomposition.

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	高慧
	李冰
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	毕淑娴
	田晓燕
	刘万毅

关键词 ： 3,5-bis(3-pyridyl)-1H-1,2,4-triazole, ammonium perchlorate, catalytic, thermal decomposition

Abstract： A new energetic complex, [Co(3,3΄-Hbpt)(Htm)]•H2O (1, 3,3΄-Hbpt = 3,5-bis(3- pyridyl)-1H-1,2,4-triazole and H3tm = trimesic acid), has been synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction, elementary analysis, IR spectroscopy, thermogravimetric analysis and X-ray powder diffraction. Single-crystal X-ray diffraction indicates that the complex belongs to triclinic system, space group P with a = 10.0911(1), b = 10.2573(1), c = 10.6393(1) Å, α = 103.793(2),  = 101.041(2), γ = 107.918(3)º, V = 974.9(2) Å3, Z = 2, Dc = 1.732 g•cm-3, μ = 0.941 mm-1, Mr = 508.31, F(000) = 518, the final R = 0.0523 and wR = 0.0935 with I > 2(I). In the title complex, Co(II) ions are connected by Htm2- anions generating 1D ladder-like chains which are linked by 3,3΄-Hbpt to form 1D cages. In addition, the thermal decomposition of ammonium perchlorate (AP) with complex 1 was explored by differential scanning calorimetry (DSC). AP is completely decomposed in a shorter time in the presence of complex 1, and the decomposition heat of the mixture is 2.531 kJ•g-1, signiﬁcantly higher than that of pure AP. By Kissinger's method, the ratio of Ea/ln(A) is 11.05 for the mixture, which indicates that complex 1 shows good catalytic activity toward the AP decomposition.

Key words： 3,5-bis(3-pyridyl)-1H-1,2,4-triazole ammonium perchlorate catalytic thermal decomposition

收稿日期: 2016-02-03 出版日期: 2016-12-12

基金资助:

Supported by the National Natural Science Foundation of China (No. 21263019 and 21467022)

通讯作者: nxdaxue@126.com (Li Bing) E-mail: libing@nxu.edu.cn

引用本文:

高慧;李冰;靳晓东;毕淑娴;田晓燕;刘万毅. Catalytic Kinetic on the Thermal Decomposition of Ammonium Perchlorate with a New Energetic Complex Based on 3,5-Bis(3-pyridyl)-1H-1,2,4-triazole[J]. 结构化学, 2016, 35(12): 1902-1911.
GAO Hui;LI Bing;JIN Xiao-Dong;BI Shu-Xian;TIAN Xiao-Yan;LIU Wan-Yi . Catalytic Kinetic on the Thermal Decomposition of Ammonium Perchlorate with a New Energetic Complex Based on 3,5-Bis(3-pyridyl)-1H-1,2,4-triazole. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(12): 1902-1911.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I12/1902

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