Interpenetration of Three 2D In-MOFs with (6, 3) Topology: Syntheses, Structures and Fluorescent Properties

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摘要

Three indium metal-organic frameworks (In-MOFs), [In(BTB)(2,2΄-bipy)]•NMP (1), [In(BTB)(2,2΄-bipy)]•NMP•2H2O (2), and [In(BTB)(NMP)]•0.5NMP (3), have been constructed by the solvothermal reaction of In(NO3)3•5H2O and 1,3,5-benzenetribenzoic acid (H3BTB) in similar reaction conditions, and characterized by single-crystal X-ray crystallography, power X-ray diffraction (PXRD), infrared spectroscopy (IR), elemental analysis (EA) and thermogravimetry analysis (TGA). Complex 1 bears a two-dimensional (2D) layered structure of 6,3-connected hcb net topology, and complexes 2 and 3 have 2-fold interpenetrating structures based on 6,3-connected layer, which display the same net topologies with the C3-symmetric H3BTB ligands as 3-connected linkers and the In(III) ions as 6-connected nodes. Moreover, the fluorescent properties of 1～3 have also been studied.

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	王荣明
	张明会
	王文
	徐玉文
	王志英
	戴昉纳
	张亮亮
	孙道峰

关键词 ： indium complex, interpenetration, metal-organic frameworks

Abstract：Three indium metal-organic frameworks (In-MOFs), [In(BTB)(2,2΄-bipy)]•NMP (1), [In(BTB)(2,2΄-bipy)]•NMP•2H2O (2), and [In(BTB)(NMP)]•0.5NMP (3), have been constructed by the solvothermal reaction of In(NO3)3•5H2O and 1,3,5-benzenetribenzoic acid (H3BTB) in similar reaction conditions, and characterized by single-crystal X-ray crystallography, power X-ray diffraction (PXRD), infrared spectroscopy (IR), elemental analysis (EA) and thermogravimetry analysis (TGA). Complex 1 bears a two-dimensional (2D) layered structure of 6,3-connected hcb net topology, and complexes 2 and 3 have 2-fold interpenetrating structures based on 6,3-connected layer, which display the same net topologies with the C3-symmetric H3BTB ligands as 3-connected linkers and the In(III) ions as 6-connected nodes. Moreover, the fluorescent properties of 1～3 have also been studied.

Key words： indium complex interpenetration metal-organic frameworks

收稿日期: 2016-01-25 出版日期: 2016-11-10

基金资助:

Supported by the National Natural Science Foundation of China (No. 21371179, 21201179), the Fundamental Research Funds for the
Central Universities (14CX02213A, 16CX05015A) and the Foundation of State Key Laboratory of Structural Chemistry (20150026, 20160006)

通讯作者: rmwang@upc.edu.cn E-mail: rmwang@upc.edu.cn

引用本文:

王荣明;张明会;王文;徐玉文;王志英;戴昉纳;张亮亮;孙道峰. Interpenetration of Three 2D In-MOFs with (6, 3) Topology: Syntheses, Structures and Fluorescent Properties[J]. 结构化学, 2016, 35(11): 1714-1722.
WANG Rong-Ming;ZHANG Ming-Hui;WANG Wen;XU Yu-Wen;WANG Zhi-Ying;DAI Fang-Na;ZHANG Liang-Liang;SUN Dao-Feng. Interpenetration of Three 2D In-MOFs with (6, 3) Topology: Syntheses, Structures and Fluorescent Properties. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(11): 1714-1722.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I11/1714

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