Topology and Photoluminescence Property of a Neodymium-carboxylate Coordination Polymer Based on aTripodal Flexible Ligand

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摘要

A new metal-organic coordination polymer {[Nd(tci)(H2O)2]•2H2O}n (1) has been synthesized based on the flexible tricarboxylate ligand tris(2-carboxyethyl)isocyanuric acid (H3tci) and structurally characterized by single-crystal X-ray diffraction analyses, elemental analysis, infrared spectra (IR), powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA). Complex 1 crystallizes in triclinic, space group P with a = 9.1648(11), b = 9.3326(12), c = 12.440(2) Å, C12H20N3O13Nd, Mr = 558.55, V = 886.9(2) Å3, Z = 2, Dc = 2.092 g•cm-3, μ = 3.006 mm-1, F(000) = 554, 2.56<θ<25.00°, λ(MoKα) = 0.71073 Å, T = 293(2) K, the final R = 0.0662 and wR = 0.2071. X-ray diffraction analysis reveals that complex 1 is a two-dimensional layer, which is further assembled into a three-dimensional supramolecular architecture through hydrogen bonding interactions. The structure of complex 1 can be simplified as a rare 2-periodic uninodal {48•62} topology and a non-interpenetrating kgd topology. Furthermore, the thermal stability and photoluminescence property of 1 were investigated.

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	崔培培
	符爱云
	王鹏

关键词 ： tripodal flexible ligand, topology, conformation, photoluminescence property

Abstract：

Key words： tripodal flexible ligand topology conformation photoluminescence property

收稿日期: 2015-12-16 出版日期: 2016-09-13

基金资助:

Supported by the NSFC (No. 21171031)

通讯作者: 1cuipeipei1@163.com E-mail: 1cuipeipei1@163.com

引用本文:

崔培培;符爱云;王鹏. Topology and Photoluminescence Property of a Neodymium-carboxylate Coordination Polymer Based on aTripodal Flexible Ligand[J]. 结构化学, 2016, 35(9): 1391-1398.
CUI Pei-Pei;FU Ai-Yun;WANG Peng. Topology and Photoluminescence Property of a Neodymium-carboxylate Coordination Polymer Based on aTripodal Flexible Ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(9): 1391-1398.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I9/1391

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