Syntheses, Crystal Structures, and Magnetic Properties of Two Manganese(II) Coordination Polymers Based on Bifunctional Pyridine-benzene Carboxylic Acids

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摘要

Two manganese(II) coordination polymers, namely, {[Mn(PIP)(BIBP)]•(BIBP)0.5}n (1) and {[Mn(PTA)(BIMBP)(H2O)]•H2O0.69}n (2) (H2PIP = 5-(4-pyridyl)-isophthalic acid, H2PTA = 6-(4-pyridyl)-terephthalic acid, BIBP = 4,4΄-bis(imidazol-1-yl)biphenyl, and BIMBP = 4,4΄-bis(imidazol-1-ylmethyl)biphenyl), have been synthesized by using the bifunctional pyrinde-benzene carboxylic acids and bis(imidazole) linkers as mixed ligands to react with MnSO4, and further characterized by elemental analysis, IR, and PXRD. Compound 1 is in the triclicnic system, space group P with a = 10.1089(8), b = 13.1927(12), c = 14.0638(12) Å, α = 69.437(2), β = 73.2890(10), γ = 78.5320(10)º, V = 1671.9(2) Å3, Z = 2, Dc = 1.449 g/cm3, F(000) = 705, μ(MoKα) = 0.453 mm-1, S = 1.053, R = 0.0491 and wR = 0.1367 for 5837 unique reflections (Rint = 0.0208) with I > 2σ(I). Compound 2 belongs to the monoclicnic system, space group C2/c with a = 15.199(3), b = 19.731(3), c = 21.537(5) Å, β = 105.228(3)º, V = 6232(2) Å3, Z = 8, Dc = 1.363 g/cm3, F(000) = 2648, μ(MoKα) = 0.475 mm-1, S = 1.048, R = 0.0489 and wR = 0.1151 for 7414 unique reflections (Rint = 0.0425) with I > 2σ(I). Structural analyses reveal that complex 1 is a 4-connected (44.62)-sql bilayer structure with binuclear [Mn2(COO)2] SBU, while complex 2 is a normally (3,5)-connected (42.67.8)(42.6)-3,5L2 monolayer. And the sheets interacted with the adjacent sheets through weak interactions, finally giving a stable three-dimensional (3D) supramolecule. Besides, the variable-temperature magnetic susceptibility measurement of complex 1 was investigated.

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	黄胜
	蒋畅
	姚枫枫
	康杰

关键词 ： coordination polymer, pyridine-benzene carboxylic acid, manganese, magnetic property, bis(imidazole) linkers

Abstract：

Key words： coordination polymer pyridine-benzene carboxylic acid manganese magnetic property bis(imidazole) linkers

收稿日期: 2016-02-22 出版日期: 2016-08-10

基金资助:

This work was supported by the NSF of Fujian Province (2015J01597), Collegiate Natural Science Fund of Fujian Province (JK2012019), and Professor Fund of Fujian Medical University (JS14008)

通讯作者: davidkj660825@163.com E-mail: davidkj660825@163.com

引用本文:

黄胜;蒋畅;姚枫枫;康杰. Syntheses, Crystal Structures, and Magnetic Properties of Two Manganese(II) Coordination Polymers Based on Bifunctional Pyridine-benzene Carboxylic Acids[J]. 结构化学, 2016, 35(8): 1260-1268.
HUANG Sheng;JIANG Chang;YAO Feng-Feng;KANG Jie. Syntheses, Crystal Structures, and Magnetic Properties of Two Manganese(II) Coordination Polymers Based on Bifunctional Pyridine-benzene Carboxylic Acids. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(8): 1260-1268.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I8/1260

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