Syntheses and Characterizations of Cd(II) and Pr(III) Complexes Based on 5-(Tetrazol-5-yl) Isophthalic Acid

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摘要

Hydrothermal reactions of 5-(tetrazol-5-yl) isophthalic acid with cadmium nitrate/pra-seodymium nitrate led to two complexes of [Cd3(TZI)2(H2O)11]n (1) and [Pr(TZI)(H2O)5]n (2). Their structures and properties were determined by X-ray diffraction, IR spectroscopy, fluorescence spectrum, thermal gravimetric analyses and elemental analysis. Complex 1 belongs to monoclinic system, I2/c space group, with a = 12.8688(3), b = 18.0925(3), c = 14.5190(3) Å, β = 116.054(3)°, V = 3036.92(13) Å3, Z = 4; complex 2 crystallizes in triclinic, space group P , with a = 7.9690(5), b = 9.7665(8), c = 10.4353(9) Å, α = 116.709(9), β = 107.461(6), γ = 95.671(6)°, V = 665.54(9) Å3 and Z = 2. Complex 1 is a 3D planar structure. Complex 2 is a one-dimensional double chain configuration and extends into a 3D network by hydrogen bonds and π-π interactions.

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	郝雪娜
	郑宝花
	胡拖平

关键词 ： metal-organic complexes, hydrothermal synthesis, 5-(tetrazol-5-yl) isophthalic acid ligand

Abstract：

Key words： metal-organic complexes hydrothermal synthesis 5-(tetrazol-5-yl) isophthalic acid ligand

收稿日期: 2015-12-01 出版日期: 2016-08-10

基金资助:

Supported by the International Science & Technology Cooperation Program of China (No. 2011DFA51980), the International
Scientific and Technological Cooperation Projects of Shanxi Province (No. 2015081043), “131” Leading Talents Project
in Colleges and Universities, Science and Technology Innovation Project of Shanxi Province (No. 2014101002), and
Graduate Student Education Innovation Project of Shanxi Province (No. 20141101)

通讯作者: hutuoping@126.com E-mail: hutuopingsx@126.com

引用本文:

郝雪娜;郑宝花;胡拖平. Syntheses and Characterizations of Cd(II) and Pr(III) Complexes Based on 5-(Tetrazol-5-yl) Isophthalic Acid[J]. 结构化学, 2016, 35(8): 1186-1194.
HAO Xue-Na;ZHENG Bao-Hua;HU Tuo-Ping. Syntheses and Characterizations of Cd(II) and Pr(III) Complexes Based on 5-(Tetrazol-5-yl) Isophthalic Acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(8): 1186-1194.

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http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I8/1186

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