Synthesis, Crystal Structure and Properties of a Zinc(Ⅱ) Complex Based on 5-(1H-Tetrazol-5-yl)isophthalic Acid Ligand
张兴晶;王璐瑶;尉兵;李梦;乔宇;车广波
a (College of Chemistry, Jilin Normal University, Siping 136000, China)
b (Key Laboratory of Preparation and Applications of Environmental Friendly Materials,Chinese Ministry of Education, Jilin Normal University, Siping 136000, China)
Synthesis, Crystal Structure and Properties of a Zinc(Ⅱ) Complex Based on 5-(1H-Tetrazol-5-yl)isophthalic Acid Ligand
a (College of Chemistry, Jilin Normal University, Siping 136000, China)
b (Key Laboratory of Preparation and Applications of Environmental Friendly Materials,Chinese Ministry of Education, Jilin Normal University, Siping 136000, China)
A novel polymeric zinc(II) complex {[Zn2(TIA)(H2O)3]•(NO3)}n (1, H3TIA = 5- (1H-tetrazol-5-yl)isophthalic acid) has been synthesized in mixed solvents under solvothermal conditions and characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction. Complex 1 crystallizes in orthorhombic, space group Cmcm with a = 10.4210(6), b = 23.3526(14), c = 6.9214(4) Å, V = 1684.37(17) Å3, Z = 4, C9H4N5O10Zn2, Mr = 472.91, Dc = 1.865 g/cm3, F(000) = 932, λ(MoKα) = 2.909 mm-1, R = 0.0423 and wR = 0.1287. The complex has good thermal stability and excellent photoluminescent property.
A novel polymeric zinc(II) complex {[Zn2(TIA)(H2O)3]•(NO3)}n (1, H3TIA = 5- (1H-tetrazol-5-yl)isophthalic acid) has been synthesized in mixed solvents under solvothermal conditions and characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction. Complex 1 crystallizes in orthorhombic, space group Cmcm with a = 10.4210(6), b = 23.3526(14), c = 6.9214(4) Å, V = 1684.37(17) Å3, Z = 4, C9H4N5O10Zn2, Mr = 472.91, Dc = 1.865 g/cm3, F(000) = 932, λ(MoKα) = 2.909 mm-1, R = 0.0423 and wR = 0.1287. The complex has good thermal stability and excellent photoluminescent property.
Supported by the National Natural Science Foundation of China (No. 21576112), the Program for New Century Excellent Talents in University (NCET-10-0176) of China and Natural Science Foundation Project of Jilin Province (No. 20130521019JH and 201215219)
张兴晶;王璐瑶;尉兵;李梦;乔宇;车广波. Synthesis, Crystal Structure and Properties of a Zinc(Ⅱ) Complex Based on 5-(1H-Tetrazol-5-yl)isophthalic Acid Ligand[J]. 结构化学, 2016, 35(8): 1213-1221.
ZHANG Xing-Jing;WANG Lu-Yao;WEI Bing;LI Meng;QIAO Yua;CHE Guang-Bo. Synthesis, Crystal Structure and Properties of a Zinc(Ⅱ) Complex Based on 5-(1H-Tetrazol-5-yl)isophthalic Acid Ligand. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(8): 1213-1221.
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2016, Vol. 35 
