Structures and Photoluminescent Properties of Two Complexes Based on Dipyrido[3,2-a:2΄,3΄-c]phenazine and 2,4΄-Biphenyldicarboxylic Acid

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摘要

Two new complexes [Cd(2,4΄-bpdc)(DPPZ)]2n•nH2O (1) and [Zn(2,4΄-Hbpdc)2(DPPZ)]•H2O (DPPZ = dipyrido[3,2-a:2΄,3΄-c]phenazine, 2,4΄-H2bpdc = 2,4΄-biphenyldicarboxylic acid) have been hydrothermally synthesized. The structure of complex 1 was determined by single-crystal X-ray diffraction diffraction and further characterized by elemental analysis, IR spectrum, powder X-ray diffraction (XRD) and single-crystal X-ray diffraction. Complex 1 has 1D chains, which are further connected by π-π stacking interactions of neighbouring chains, generating a steady 3D supramolecular structure. Complex 2 shows the isolated mononuclear units, which are further extended to a 2D supramolecular layered structure through π-π stacking interactions and hydrogen bonds. Furthermore, complexes 1 and 2 exhibit green photoluminescent properties at room temperature.

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	姜大雨
	王博
	冯博
	李秀颖
	乔宇
	徐占林
	车广波

关键词 ： Cd(II) complex, Zn(II) complex, 2,4?-biphenyldicarboxylic acid, dipyrido[3,2-a:2?,3?- c]phenazine, photoluminescent property

Abstract：

Key words： Cd(II) complex Zn(II) complex 2,4?-biphenyldicarboxylic acid dipyrido[3,2-a:2?,3?- c]phenazine photoluminescent property

收稿日期: 2015-11-03 出版日期: 2016-07-12

基金资助:

Supported by the Program for NNSFC (21407064, 21576112), NSF of Jilin Province (20130521019JH),and the Science and Technology Development Plan of Siping City (2014052, 2015049)

通讯作者: xzl@jlnu.edu.cn E-mail: guangboche@jlnu.edu.cn

引用本文:

姜大雨;王博;冯博;李秀颖;乔宇;徐占林;车广波. Structures and Photoluminescent Properties of Two Complexes Based on Dipyrido[3,2-a:2΄,3΄-c]phenazine and 2,4΄-Biphenyldicarboxylic Acid[J]. 结构化学, 2016, 35(7): 1107-1114.
JIANG Da-Yu;WANG Bo;FENG Bo;LI Xiu-Ying;QIAO Yu;XU Zhan-Lin;CHE Guang-Bo. Structures and Photoluminescent Properties of Two Complexes Based on Dipyrido[3,2-a:2΄,3΄-c]phenazine and 2,4΄-Biphenyldicarboxylic Acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(7): 1107-1114.

链接本文:

http://manu30.magtech.com.cn/jghx/CN/ 或 http://manu30.magtech.com.cn/jghx/CN/Y2016/V35/I7/1107

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