A Zn(II) Coordination Polymer with 4-Connected bbf Topology: Synthesis,Crystal Structure and Luminescent Property
张鑫;覃业燕;孙明玲;姚元根
a (Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China)
b (University of Chinese Academy of Sciences, Beijing 100039, China)
A Zn(II) Coordination Polymer with 4-Connected bbf Topology: Synthesis,Crystal Structure and Luminescent Property
ZHANG Xin;QIN Ye-Yan;SUN Ming-Ling;YAO Yuan-Gen
a (Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China)
b (University of Chinese Academy of Sciences, Beijing 100039, China)
A new Zn(II) compound, namely {Zn(BTA)(pdc)0.5}n (1, HBTA = 1,2,3-benzo- triazole, H2pdc = terephthalic acid), has been hydrothermally synthesized and characterized by elemental analysis, infrared analysis, powder X-ray diffraction analysis and single-crystal X-ray structural analysis. The crystal structure is of monoclinic system, space group P21/c with a = 10.751(3), b = 9.792(3), c = 9.292(3) Å, β = 95.391(4), V = 973.9(5) Å3, C10H6N3O2Zn, Mr = 265.57, Z = 4, Dc = 1.811 g/cm3, F(000) = 532, μ = 2.506 mm-1, R = 0.0221 and wR = 0.0605 for 2075 observed reflections (I > 2(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional (3D) framework with 4-connected bbf topology. Moreover, the thermogravimetric (TG) analysis and photoluminescent property of 1 were also discussed.
A new Zn(II) compound, namely {Zn(BTA)(pdc)0.5}n (1, HBTA = 1,2,3-benzo- triazole, H2pdc = terephthalic acid), has been hydrothermally synthesized and characterized by elemental analysis, infrared analysis, powder X-ray diffraction analysis and single-crystal X-ray structural analysis. The crystal structure is of monoclinic system, space group P21/c with a = 10.751(3), b = 9.792(3), c = 9.292(3) Å, β = 95.391(4), V = 973.9(5) Å3, C10H6N3O2Zn, Mr = 265.57, Z = 4, Dc = 1.811 g/cm3, F(000) = 532, μ = 2.506 mm-1, R = 0.0221 and wR = 0.0605 for 2075 observed reflections (I > 2(I)). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional (3D) framework with 4-connected bbf topology. Moreover, the thermogravimetric (TG) analysis and photoluminescent property of 1 were also discussed.
基金资助:Supported by the 973 Program of China (2011CBA00505), the "Strategic Priority Research Program" of the Chinese Academy of Sciences (XDA07070200, XDA09030102), and the Science Foundation of the Fujian Province (2006L2005)
通讯作者:
yyg@fjirsm.ac.cn
E-mail: yyg@fjirsm.ac.cn
引用本文:
张鑫;覃业燕;孙明玲;姚元根 . A Zn(II) Coordination Polymer with 4-Connected bbf Topology: Synthesis,Crystal Structure and Luminescent Property[J]. 结构化学, 2016, 35(7): 1145-1150.
ZHANG Xin;QIN Ye-Yan;SUN Ming-Ling;YAO Yuan-Gen. A Zn(II) Coordination Polymer with 4-Connected bbf Topology: Synthesis,Crystal Structure and Luminescent Property. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(7): 1145-1150.
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