Two 3D Metal-organic Frameworks with 4-Fold [2+2]-type Interpenetrated hms Nets Based on a Flexible Tricarboxylic Acid
樊义康;谢斌;谢峰;吴威平;邹立科;那仁·格日勒;魏健
a (Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, China)
b (University Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education, Zigong 643000, China)
c (College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang 641100, China)
Two 3D metal-organic frameworks with 4-fold [2+2]-type interpenetrated hms nets based on a flexible tricarboxylic acid
FAN Yi-Kang;XIE Bin;XIE Feng;WU Wei-Ping;ZOU Li-Ke;NAREN Ge-Ri-Le;WEI Jian
a (Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, China)
b (University Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education, Zigong 643000, China)
c (College of Chemistry and Chemical Engineering,Neijiang Normal University, Neijiang 641100, China)
Two 3D 4-fold interpenetrated metal-organic frameworks, [Mn(L)(bpy)]n (1) and [Cu(HL)(bpy)]n (2) (H3L = 4,4΄,4΄΄-(benzene-1,3,5-triyl-tri(methyleneoxy)) tribenzoic acid, bpy = 4,4′-bipyridine), were synthesized under hydrothermal conditions, and characterized by element analyses, IR spectra, thermogravimetric analyses, X-ray powder diffraction and magnetic property studies. The single-crystal X-ray analyses revealed that 1 and 2 are homogeneous. 1 crystallizes in monoclinic, space group Cc with a = 26.794(2), b = 11.6346(10), c = 21.4614(18) Å, β = 91.570(2), V = 6687.9(10) Å3, Z = 8, Mr = 736.59, Dc = 1.463 gcm-3, = 0.458 mm-1, Rint = 0.0524, F(000) = 3040, the final R = 0.0844 and wR = 0.2266 for 8092 observed reflections (I > 2(I)). 2 crystallizes in monoclinic, space group Cc with a = 27.609(12), b = 11.126(10), c = 21.490(9) Å, β = 92.131(2), V = 6597(5) Å3, Z = 8, Mr = 746.21, Dc = 1503 gcm-3, = 0.726 mm-1, Rint = 0.0542, F(000) = 3080, the final R =0.0681 and wR = 0.1831 for 6777 observed reflections (I > 2(I)). Two compounds are 3D [2+2]-type 4-fold interpenetrated frameworks with (63)(69.8) hms topology. The magnetic study of compound 2 shows the presence of weak antiferromagnetic interaction between the CuII ions in 2.
Two 3D 4-fold interpenetrated metal-organic frameworks, [Mn(L)(bpy)]n (1) and [Cu(HL)(bpy)]n (2) (H3L = 4,4΄,4΄΄-(benzene-1,3,5-triyl-tri(methyleneoxy)) tribenzoic acid, bpy = 4,4′-bipyridine), were synthesized under hydrothermal conditions, and characterized by element analyses, IR spectra, thermogravimetric analyses, X-ray powder diffraction and magnetic property studies. The single-crystal X-ray analyses revealed that 1 and 2 are homogeneous. 1 crystallizes in monoclinic, space group Cc with a = 26.794(2), b = 11.6346(10), c = 21.4614(18) Å, β = 91.570(2), V = 6687.9(10) Å3, Z = 8, Mr = 736.59, Dc = 1.463 gcm-3, = 0.458 mm-1, Rint = 0.0524, F(000) = 3040, the final R = 0.0844 and wR = 0.2266 for 8092 observed reflections (I > 2(I)). 2 crystallizes in monoclinic, space group Cc with a = 27.609(12), b = 11.126(10), c = 21.490(9) Å, β = 92.131(2), V = 6597(5) Å3, Z = 8, Mr = 746.21, Dc = 1503 gcm-3, = 0.726 mm-1, Rint = 0.0542, F(000) = 3080, the final R =0.0681 and wR = 0.1831 for 6777 observed reflections (I > 2(I)). Two compounds are 3D [2+2]-type 4-fold interpenetrated frameworks with (63)(69.8) hms topology. The magnetic study of compound 2 shows the presence of weak antiferromagnetic interaction between the CuII ions in 2.
Supported by the Education Committee of Sichuan Province (12ZA090, 13CZ0019 and 14ZB0220), Key Laboratory of Green Catalysis of Sichuan Institutes of High Education (LZJ14201) and Sichuan University of Science and Engineering (Y2014018)
樊义康;谢斌;谢峰;吴威平;邹立科;那仁·格日勒;魏健. Two 3D Metal-organic Frameworks with 4-Fold [2+2]-type Interpenetrated hms Nets Based on a Flexible Tricarboxylic Acid[J]. 结构化学, 2016, 35(4): 605-614.
FAN Yi-Kang;XIE Bin;XIE Feng;WU Wei-Ping;ZOU Li-Ke;NAREN Ge-Ri-Le;WEI Jian. Two 3D metal-organic frameworks with 4-fold [2+2]-type interpenetrated hms nets based on a flexible tricarboxylic acid. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35(4): 605-614.
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2016, Vol. 35 
